青藏高原龙胆属中10种野生药材的4种主要活性成分的测定分析

建立反相高效液相色谱法同时测定青藏高原龙胆属中10种常用野生药材的獐牙菜苦苷、龙胆苦苷、獐芽菜苷、异荭草苷的含量.方法:采用反相高效液相色谱法.乙腈-水(0.1%的H3PO4)为流动相,梯度洗脱,洗脱条件为0.01 min→20.00 min→20.01 min→40.00 min→40.01 min→50.00 min,乙腈:12%→12%→15%→33%→100%→100%,体积流量1.0 mL/min,检测波长为240 nm,柱温25 ℃.4种成分均达到基线分离,线性良好.     

端面抽运激光晶体热形变及温度场分布研究

用有限元方法研究了端面抽运Nd∶YAG激光器中激光晶体的温度和端面热形变分布规律.研究表明,激光晶体的端面热形变分为端面伸长形变和鼓出形变两种,晶体的热形变透镜效应是由鼓出形变引起的.在端面抽运的Nd∶YAG晶体中采用第三类热传导边界条件,实验测量了晶体的端面伸长和端面鼓出形变,结果与理论分析相一致.     

油膜支承转子系统动静件碰摩特征分析

以支承在油膜轴承上的Jeffcott转子为对象，分析了油膜力对碰摩转子动力学行为的影响。通过与刚支情形对比，发现油膜力是耦合作用于碰摩转子系统，有时能够抑制振动，有时却加剧振动。因此实际转子碰摩故障诊断过程中，必须在充分考虑支承情况的基础上建立合理的非线性动力学模型，才能为实际转子系统的碰摩故障分析提供必要的理论依据。     

手性助剂法不对称合成γ-不饱和氨基酸

采用2-N-(N'-苄基脯氨酰)-氨基二苯甲酮-镍(Ⅱ)-甘氨酸复合物与2-N-(N'-苄基脯氨酰)-氨基二苯甲酮-镍(Ⅱ)-丙基酸复合物为手性助剂,与3-烯丙基溴进行取代反应,制备了2种手性非蛋白不饱和氨基酸.反应过程操作简便,复合物产率达90%～93%,2-氨基-4-烯-戊酸和2-甲基-2-氨基-4-烯-戊酸的总收率分别为75%和80%. 手性助剂回收率达90%. 中间产物及γ-不饱和氨基酸经1H NMR和质谱测试技术的确证.     

考虑径向内间隙的滚动轴承平衡转子系统的非线性动力稳定性

研究滚动轴承平衡转子系统在不同轴承内间隙量,不同转速下系统的稳定性及其分岔特性和混沌．考虑Hertz接触力、 滚动体通过振动和轴承径向内间隙等非线性因素建立数学模型,根据Floquet理论分析不同间隙量下滚动轴承转子系统的周期解稳定性, 找到了3种导致周期解失稳的方式:倍周期分岔失稳、拟周期分岔失稳和边界激变导致混沌失稳．通过对各间隙量下转子系统拓扑特性变化和失稳区域的研究,表明滚动轴承间隙量是影响转子系统动力稳定性的一个重要因素．     

Quantum secure direct communication with Greenberger-Horne-Zeilinger-type state （GHZ state） over noisy channels

We propose a quantum error-rejection scheme for direct communication with three-qubit quantum codes based on the direct communication of secret messages without any secret key shared in advance. Given the symmetric and independent errors of the transmitted qubits, our scheme can tolerate a bit of error rate up to 33.1%, thus the protocol is deterministically secure against any eavesdropping attack even in a noisy channel.     

一种基于共保护策略合成谷胱甘肽的新方法

报道了一种采用谷氨酸席夫碱Ni(II)配合物共保护L-谷氨酸α-氨基和α-羧基合成谷胱甘肽(γ-L-谷氨酰-L-半胱氨酰-甘氨酸)的新方法. 首先由手性助剂——2-[N-(N’-苄基-脯氨酰)氨基]二苯甲酮(1)、六水合氯化镍和L-谷氨酸反应, 得到谷氨酸席夫碱Ni(II)配合物2, 产率为98%; 进而采用二异丙基碳二亚胺(DIC)/1-羟基-苯并三氮唑(HOBt)复合缩合剂法与S-苄基-L-半胱氨酸反应, 得到S-苄基-γ-L-谷氨酰-L-半胱氨酸席夫碱Ni(II)配合物3, 产率为90%; 接着同样采用DIC/HOBt复合缩合剂法与甘氨酸反应, 得到S-苄基-γ-L-谷氨酰-L-半胱氨酰-甘氨酸席夫碱Ni(II)配合物4, 产率为95%; 然后稀酸水解配合物4, 得到S-苄基-γ-L-谷氨酰-L-半胱氨酰-甘氨酸(5), 产率为70%; 最后采用甲酸铵催化转移氢化脱除S-苄基, 得到谷胱甘肽(6), 产率为87%. 中间产物和终产物的结构经由旋光, 1H NMR, 13C NMR和HRMS表征.     

Stability and bifurcation of unbalance rotor/labyrinth seal system

The influence of labyrinth seal on the stability of unbalanced rotor system was presented . Under the periodic excitation of rotor unbalance , the whirling vibration of rotor is synchronous if the rotation speed is below stability threshold, whereas the vibration becomes severe and asynchronous which is defined as unstable if the rotation speed exceeds threshold . The. Muszynska model of seal force and shooting method were used to investigate synchronous solution of the dynamic equation of rotor system. Then , based on Floquet theory the stability of synchronous solution and unstable dynamic characteristic of system were analyzed.     

精细积分法在迷宫密封转子系统非线性动力学特性计算中的应用

基于Muszynska密封力模型,建立了迷宫密封转子系统的非线性动力学模型,将精细积分法推广应用于非线性情况,计算了迷宫密封不平衡转子系统的动力学特性,依据Floquet理论讨论其分岔特性。研究表明：在2^N类算法计算指数矩阵基础上提出的精细积分法和传统的数值计算方法相比,其精度高,在分析中通过取不同步长计算对比,表明该方法在某些情况下可以采取较大时间步长,有效提高了计算速度。     

NONLINEAR STABILITY OF BALANCED ROTOR DUE TO EFFECT OF BALL BEARING INTERNAL CLEARANCE

Stability and dynamic characteristics of a ball bearing-rotor system are investigated under the effect of the clearance in the ball bearing. Different clearance values are assumed to calculate the nonlinear stability of periodic solution with the aid of the Floquet theory. Bifurcation and chaos behavior are analyzed with variation of the clearance and rotational speed. It is found that there are three routes to unstable periodic solution. The period-doubling bifurcation and the secondary Hopf bifurcation are two usual routes to instability. The third route is the boundary crisis, a chaotic attractor occurs suddenly as the speed passes through its critical value. At last, the instable ranges for different internal clearance values are described. It is useful to investigate the stability property of ball bearing rotor system.