Tunable ultra-wideband terahertz filter based on three-dimensional arrays of H-shaped plasmonic crystalsTunable ultra-wideband terahertz filter based on three-dimensional arrays of H-shaped plasmonic crystalsTunable ultra-wideband terahertz filter based on three-dimensional arrays of H-shaped plasmonic crystals

A face-to-face system of double-layer three-dimensional arrays of H-shaped plasmonic crystals is proposed, and its transmission and filtering properties are investigated in the terahertz regime. Simulation results show that our design has excellent filtering properties. It has an ultra-wide bandgap and passband with steep band-edges, and the transmittance of the passband and the forbidden band are very close to I and 0, respectively. As the distance between the two face-to-face plates increases, the resonance frequency exhibits a gradual blueshift from 0.88 THz to 1.30 THz. Therefore, we can dynamically control the bandwidths of bandgap and passband by adding a piezoelectric ceramic plate between the two crystal plates. Furthermore, the dispersion relations of modes and electric field distributions are presented to analyze the generation mechanisms of bandgaps and to explain the location of bandgaps and the frequency shift phenomenon. Due to the fact that our design can provide many resonant modes, the bandwidth of the bandgaps can be greatly broadened. This paper can serve as a valuable reference for the design of terahertz functional devices and three-dimensional terahertz metamaterials.     

ASE-GC-MS法同时测定农用地土壤中的多环芳烃、多氯联苯和有机氯农药

建立同时检测农用地土壤中15种多环芳烃、7种多氯联苯和8种有机氯农药的方法,对样品前处理流程及仪器工作参数进行优化。样品经正己烷–二氯甲烷(1∶1)加速溶剂萃取,以硅酸镁小柱净化,二氯甲烷–正己烷(1∶4)洗脱,用气相色谱–质谱法同时测定。各目标化合物在质量浓度在5.0～500μg/L范围内相对响应因子的相对标准偏差均小于9.3%;平均加标回收率为60.3%～105.6%,相对标准偏差为1.7%～12.8%(n=6),方法检出限为0.12～0.40μg/kg。该方法快速、稳健,净化效果好,能满足农用地土壤中30种持久性有机污染物的检测要求。     

坡莫合金磁阻传感器的特性研究和应用

介绍了坡莫合金型磁阻传感器的结构与工作原理，研究了该传感器的特性，并用它测量了地磁场的主要参量。设计了一个消除此类磁阻传感器受强磁场干扰的电路，有利于坡莫合金集成磁阻器件的推广应用。     

Tunable ultra-wideband terahertz filter based on three-dimensional arrays of H-shaped plasmonic crystals

A face-to-face system of double-layer three-dimensional arrays of H-shaped plasmonic crystals is proposed, and its transmission and filtering properties are investigated in the terahertz regime. Simulation results show that our design has excellent filtering properties. It has an ultra-wide bandgap and passband with steep band-edges, and the transmittance of the passband and the forbidden band are very close to 1 and 0, respectively. As the distance between the two face-to-face plates increases, the resonance frequency exhibits a gradual blueshift from 0.88 THz to 1.30 THz. Therefore, we can dynamically control the bandwidths of bandgap and passband by adding a piezoelectric ceramic plate between the two crystal plates. Furthermore, the dispersion relations of modes and electric field distributions are presented to analyze the generation mechanisms of bandgaps and to explain the location of bandgaps and the frequency shift phenomenon. Due to the fact that our design can provide many resonant modes, the bandwidth of the bandgaps can be greatly broadened. This paper can serve as a valuable reference for the design of terahertz functional devices and three-dimensional terahertz metamaterials.     

高架桥混凝土多室箱梁水压爆破破碎机理数值模拟

高架桥钢筋混凝土箱梁属于薄壁空腔结构,钢筋含量高,难以进行钻孔爆破破碎。以武汉沌阳高架桥爆破拆除工程为背景,提出了采用水压爆破破碎多室钢筋混凝土箱梁的方案,并采用动力有限元数值模拟方法模拟了全封闭多室箱梁结构的水压爆破破坏过程,研究了炸药在水中爆炸后诱发的冲击波和爆生气体对下箱梁结构的双重作用过程;在对数值模拟与实际爆破效果分析基础上,探讨了箱梁水压爆破方案的药包布置方式、爆破参数和起爆顺序等。     

爆破扰动下邻近层状围岩隧道的稳定性与振速阈值

爆炸荷载下邻近既有层状围岩隧道的迎爆侧易发生开裂、破坏,确保既有隧道围岩在爆破扰动下的安全是隧道近接施工中的关键问题。基于弹性力学和结构力学原理,建立了既有层状围岩隧道迎爆侧最危险点的简化力学模型,得到了最危险点的应力计算表达式,分析了隧道半径与岩层厚度的比值、岩层的倾角、岩层所对应的圆心角和隧道埋深等因素对既有隧道围岩稳定性的影响规律,并依据岩体最大拉应力判据确定了既有层状隧道围岩稳定的质点临界振动速度,结合地震波传播时的衰减规律,可以得出爆破施工时的最大单响药量,从而为隧道近接爆破动力扰动施工提供理论依据。     

独立组分分析在红外光谱分析中的应用

针对红外光谱的黑色体系分析,提出了一种基于独立组分分析(ICA)的红外光谱定性分析方法.其主要优点在于可从混合光谱中分离出独立组分的光谱,且这种分离是盲源分离,混合物的组分预先是未知的.对ICA在正己醇、丙酮和正丁醇的混合中红外光谱分离中的应用进行了研究,验证了体系的独立性,并对ICA算法做了一定的改进,讨论了各种预处理方法对其分离结果的误差.     

PVT法同质外延制备大尺寸Al极性氮化铝晶体生长工艺及其表征分析研究

本文基于自主设计的氮化铝生长炉,开展了四组不同工艺条件下Al极性面氮化铝籽晶同质外延生长氮化铝单晶的生长特征及其结晶质量表征研究。研究发现:不同工艺条件下生长的晶体的拉曼图谱E₂(high)特征峰峰位表明,晶体内部均存在较小的拉应力;在坩埚顶部在相对较高温度2 210 ℃、坩埚底部与顶部温差42 ℃的低过饱和度生长条件下,晶体表面光滑,呈现阶梯流生长形貌,并具有典型的氮化铝单晶生长习性面,晶体初始扩张角大于40°,高分辨率X射线衍射(HRXRD)测得0002、1012反射摇摆曲线及拉曼光谱检测结果表明,该条件下生长的氮化铝晶体结晶质量优异,并可实现快速扩径。基于该生长条件,通过外延生长后成功获得尺寸ϕ45~47 mm的氮化铝单晶锭,相关表征结果表明生长的氮化铝晶体具有优越的结晶性能。     

CTAB对氯硅烷残液水解制备二氧化硅的影响

以十六烷基三甲基溴化铵(CTAB)为表面活性剂,氯硅烷残液为硅源,在水溶液中水解制备了较高比表面积多孔二氧化硅粉体。研究了在水解体系中引入表面活性剂CTAB对二氧化硅粉体比表面积、孔径和孔容的影响。控制CTAB加入量和溶液的酸碱度,可以提高二氧化硅粉体的比表面积、孔径和孔容。二氧化硅粉体比表面积在100～750 m~2·g~(-1)之间。     

爆破开挖振动下既有大型储油罐的动力响应

针对既有大型储油罐近区基础爆破开挖中的安全问题,采用ANSYS/LS-DYNA的隐式-显式顺序求解方法,结合流固耦合算法,研究了爆破振动下大型储油罐的动力响应规律。分析了罐壁不同位置的质点振速,由于质点振速分布情况较为复杂,不宜用局部质点振速判断罐壁危险点;总结了罐壁上应力的分布规律,结果显示爆破振动对储油罐的影响主要集中在迎爆侧下部,且在罐壁迎爆侧高度为3 m左右的位置最易发生象足屈曲;分析了不同频率爆破振动作用下满载储罐罐壁的质点振速,结果表明在爆破振动主频范围内,载荷频率远大于储罐固有频率条件下,罐壁上质点振速随着爆破振动频率的降低呈减小趋势;建立了储油罐罐壁质点振速与罐内液面高度的关系,结果表明降低液面高度可以有效提高储油罐的爆破振动安全阈值,爆破施工中邻近储罐储液高度不宜高于10 m。