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111.
112.
探索了辛可宁季铵盐的通用合成方法, 确定辛可宁与取代苄溴在四氢呋喃中回流为最优反应途径, 合成了11个羟基保留的辛可宁季铵盐, 收率57%~88%, 并合成了4种羟基保护季铵盐, 羟基成醚过程在生成季铵盐前后均可进行, 总收率62%~71%; 羟基酯化只能在生成季铵盐之后进行, 总收率78%. 本文共合成了15个季铵盐(Cn-1~Cn-15), 其中5个为新化合物, 另有4个的合成方法未见文献报道. 选用该类季铵盐催化剂催化二苯亚甲基甘氨酸叔丁酯的不对称苄基化反应, 结果发现, 催化剂苄基具有4-Br取代或羟基成醚均有助于提高反应产物的对映选择性. Cn-9可得到最优的反应结果, 产率93%, e.e.值91%. 相似文献
113.
使用反馈式微机控制双注仪,在晶体生长不同时期,依次加入不同量碘盐和一定量甲酸盐,制得了两个系列的溴碘化银乳剂:一系列为碘含量分别为乳剂颗粒总银量的0、2×10-2、3×10-2、4×10-2和5×10-2I-mol/Ag mol的溴碘化银颗粒乳剂;另一系列为碘含量与上述系列乳剂相同,并掺杂有1×10-4mol/Ag mol甲酸根的溴碘化银颗粒乳剂.对其感光性能的测试结果表明,经过化学敏化和光谱增感后,甲酸根掺杂的溴碘化银乳剂较未掺杂甲酸根的乳剂,感光度显著提高,在一定量的I-掺杂范围内(0-4×10-2I-mol/Ag mol),灰雾没有明显增加. 相似文献
114.
在螺桨盘转子系统的颤振涡动研究中,系统的安装刚度对转子的颤振涡动失稳有着重要的作用.对于飞机发动机,实际安装情况十分复杂,发动机短舱.安装节、机翼等对螺桨盘转子的运动均有影响.所以,在颤振涡动研究中,必须考虑轴头的动刚度.轴头的动刚度是通过动柔度转换而来的,而在动柔度的实验测量中必须解决几个技术问题,首先是提高信噪比.其次是消除工艺夹具带来的附加质量和附加转动惯量的影响,从而提高动刚度系数的测量精度.本文通过对模型转子以及某实际桨轴发动机转子轴头动刚度系数的测量及处理,阐述轴头动刚度矩阵的测量方法,以及有关技术问题的处理过程. 相似文献
115.
This paper studies the evolutionary prisoner's dilemma game on a highly clustered community network in which the clustering
coefficient and the community size can be tuned. It finds that the clustering coefficient in such a degree-homogeneous network inhibits the emergence of cooperation for the entire range of the payoff parameter. Moreover, it finds that the community size can also have a marked influence on the evolution of cooperation, with a larger community size leading to not only a lower cooperation level but also a smaller threshold of the payoff parameter above which cooperators become extinct. 相似文献
116.
Long-range surface plasmon polaritons with subwavelength mode expansion in an asymmetrical system 下载免费PDF全文
Long-range surface plasmon polariton (LRSPP) modes in an
asymmetrical system, in which the thin metal film is sandwiched
between a semi-infinite substrate and a high permittivity polymer
film with a finite thickness, are theoretically calculated and
analyzed. Due to the high permittivity of the polymer film, at
proper polymer film thicknesses, the index-matching condition of the
dielectrics at both sides of the metal can be satisfied for
supporting LRSPP modes, and the electromagnetic field above the
metal can be localized well. It is found that these LRSPP modes have
both long propagation lengths and subwavelength mode expansion above
the metal at the optimal polymer film thicknesses. Furthermore, the
requirements on the refractive index and the thickness of the
polymer film to support LRSPP modes at the optimal thicknesses are
found to be not critical. 相似文献
117.
Global adaptive synchronization of chaotic systems with uncertain parameters 总被引:3,自引:0,他引:3 下载免费PDF全文
We propose a novel adaptive synchronization method for a class of nonlinear chaotic systems with uncertain parameters.Using the chaos control method,we derive a synchronizer,which can make the states of the driven system globally track the states of the drive system asymptotically.The advantage of our method is that our problem sctting is more general than those that already exist,and the synchronizer is simply constructed by an analytic formula,without knowledge in advance of the unknown bounds of the uncertain parameters.A computer simulation example is given to validate the proposed approach. 相似文献
118.
Global synchronization of Chua's chaotic delay network by using linear matrix inequality 总被引:3,自引:0,他引:3 下载免费PDF全文
Global synchronization of Chua‘s chaotic dynamical networks with coupling delays is investigated in this paper.Unlike other approaches, where only local results were obtained, the network is found to be not linearized in this paper.Insteat, the global synchronization is obtained by using the linear matrix inequality theory. Moreover, some quite simple linear-state-error feedback controllers for global synchronization are derived, which can be easily constructed based on the minimum eigenvalue of the coupling matrix. A simulation of Chua‘s chaotic network with global coupling delays in nodes is finally given, which is used to verify the theoretical results of the proposed global synchron izationscheme. 相似文献
119.
120.
马凯 叶沿林 林承键 陈家豪 王东玺 韩家兴 贾会明 杨磊 阳黎升 胡梓瑶 陈莹 蒲伟良 李根 谭智威 黄大湖 骆天鹏 钟善豪 楼建玲 杨晓菲 李智焕 李奇特 许金艳 杨再宏 魏康 《中国物理C(英文版)》2023,(11):54-60
A 6Li(16O,19Ne*)3 H multi-nucleon transfer-reaction experiment was performed to populate the highly excited states in 19Ne.The subsequent decay particles,4He or protons from the 19Ne resonant states,were detected in coincidence with the recoil 3H.The excitation-energy spectra of 19Ne were reconstructed using the detected proton or 4He and the deduced 18F or 15O data... 相似文献