全文获取类型
收费全文 | 867篇 |
免费 | 170篇 |
国内免费 | 260篇 |
专业分类
化学 | 594篇 |
晶体学 | 32篇 |
力学 | 63篇 |
综合类 | 30篇 |
数学 | 123篇 |
物理学 | 455篇 |
出版年
2023年 | 8篇 |
2022年 | 21篇 |
2021年 | 24篇 |
2020年 | 36篇 |
2019年 | 29篇 |
2018年 | 30篇 |
2017年 | 37篇 |
2016年 | 22篇 |
2015年 | 50篇 |
2014年 | 65篇 |
2013年 | 72篇 |
2012年 | 57篇 |
2011年 | 63篇 |
2010年 | 63篇 |
2009年 | 81篇 |
2008年 | 75篇 |
2007年 | 75篇 |
2006年 | 74篇 |
2005年 | 71篇 |
2004年 | 47篇 |
2003年 | 29篇 |
2002年 | 30篇 |
2001年 | 47篇 |
2000年 | 41篇 |
1999年 | 20篇 |
1998年 | 15篇 |
1997年 | 7篇 |
1996年 | 13篇 |
1995年 | 9篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1989年 | 6篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有1297条查询结果,搜索用时 15 毫秒
11.
采用纳米化学技术制备了新型的纳米复合固体超强酸催化剂SO42-/ZrO2-Fe2O3,并用XRD、TEM进行了表征.结果表明:所研制的SO42-/ZrO2-Fe2O3催化剂为晶态纳米粒子,平均粒径为30 nm,分散性较好;当活化温度为580℃,反应温度为75℃,n(硝酸)/n(苯)=2,m(苯)/m(催化剂)=20,催化反应时间5 h时,硝基苯收率可达89.6%. 相似文献
12.
The polymerization mechanism is described by the conductance changewith the time during the polymerization. The mechanism can be explained by the equi-librium feature (i.e. main ion-pairs) between the free ions and the ion-pairs dissociated bythe organic salt (-) Sp~/(*~+) (+) CSA~(*~-) (An asterisk represents the chirality) and the schemeof the polymerization process is described mainly by the charge transfer complexes havingchiral induction power. 相似文献
13.
14.
15.
The methanolysis of poly(triphenylmethyl methacrylate) (PTrMA) and its copoly-mers P(TrMA-co-MMA), P(TrMA-b-MMA) has been studied in the presence of anhydrousmethanol at 40℃ by electroconductometric method. It has been found that the methanoly-sis stability can be obviously improved for the copolymer, especially, the radom copolymer,P(TrMA-co-MMA). 相似文献
16.
17.
XI Jingyu QIU Xinping ZHU Wentao & CHEN Liquan Department of Chemistry Tsinghua University Beijing China 《中国科学B辑(英文版)》2005,48(6)
All solid-state lithium polymer batteries may be one of the best choices for the future electrochemical power source, characterized by high energy densities, good cyclability, reliability and safety[1,2]. Owing to its potential capability to replace the t… 相似文献
18.
The effect of polystyrene sulfonic acid (PSSA) macromolecules on the polymerization of acrylamide (AM) has been studied. It was found that the rates of polymerization of AM were greatly increased in the presence of PSSA in the polymerization system.The maximum value of the rate of polymerization of AM was obtained when the ratio of [—SO_3H]: [AM] reached 3:1. When the insoluble crosslinked PSSA was used instead of the soluble one, this effect decreased considerably. The interaction between molecules of PSSA and AM was determined by infrared spectroscopy, elementary analysis and X-ray photoelectron spectroscopy. The combination form, —SO_3-NH_3~ CO—, formed between sulfonic group and amide group was found to be existed since the infrared absorption band of —NH_2 shifted from 3400cm~(-1) to 3150 cm~(-1), the binding energy of electron N_(18) changed from 399.7 eV to 401.3 eV, and the atomic ratio of N to S of the products was similar to the ratio of reagents. Based on these experimental results, the mechanism of AM polymerization in the presence of PSSA is proposed. The initial step is the combination of AM with sulfonic group to form —CONH_3~ , then followed by polymerization on the PSSA macromolecule. The role of PSSA on the polymerization of AM is discussed. 相似文献
19.
The organic nanoparticles of a blue-light-emitting molecule, 1,3-diphenyl-5-(9-anthryl)-2-pyrazuline, were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morphologies, spherical, doughnut-shaped and cubic, could be observed on the silicon substrate forthe nanoparfides by the volume-controlled addition of acetonitrile. The evolution of particle morphology as a function of acetonitrile addition was attributed to the variation of the growth habits of the particles in the different environment. The nanoparticles exhibit the novel photoluminescence spectra as compared to those of monomer and the bulk crystals. 相似文献
20.