Impact of photodepletion to amplified spontaneous emission of proton-transfer dyes in polymeric matrices

A six level rate equation system was used to investigate the impact of photodepletion to amplified spontaneous emission (ASE) of intramolecular proton-transfer (IPT) dyes incorporated into polymeric hosts. The model includes the most important transitions for the normal and tautomer form of the molecule as well as intersystem crossing and triplet–triplet transitions. The experimentally observed pulse shape as well as photodepletion phenomena, i.e. a first order exponential decay of the ASE intensity and a shortening in ASE pulse width, have been simulated successfully. Additionally, the model was used to propose an explanation of the unexpected high photodepletion of proton-transfer dyes in solids. The results show that the emission cross section and reabsorption cross section of the tautomer form of the molecule are the most important parameter not only for efficiency but also for photodepletion. The model was tested by comparison with experimental results of 2-(2’-hydroxyphenyl)benzimidazole in polymethylmethacrylate (PMMA), polystyrene (PS) and a 1:1 alternating copolymer matrix PS-co-PMMA. PACS 78.45.th; 42.55.Mv; 42.70.Jk     

Eine neue volumetrische Methode zur Bestimmung der salpetrigen S?ure

Ohne Zusammenfassung     

Stability of Crystalline Ion Beams

Hyperfine Interactions - In this paper, the conditions for which three-dimensional crystalline ion beams were attained in the rf quadrupole storage ring PALLAS at a velocity of around 2800 m/s are...     

Stratifiable Families of Extremals and Sufficient Conditions for Optimality in Optimal Control Problems

It is shown that, if a parametrized fämily of extremals F can be stratified in a way compatible with the flow map generated by F, then those trajectories of the family which realize the minimal values of the cost in F are indeed optimal in comparison with all trajectories which lie in the region R covered by the trajectories of F. It is not assumed that F is a field covering the state space injectively. As illustration, an optimal synthesis is constructed for a system where the flow of extremals exhibits a simple cusp singularity.     

Allocating energy in a first-to-n match

This paper models a decision where a player must allocate limitedenergy over a contest of uncertain length. The motivating exampleis a squash match where one of the players is not as fit asthe other. Should a player's energy be concentrated in the earlygames of the match? Should it be spread evenly over all possiblegames? Or should it be conserved for the end of the match? Wemodel this as a decision problem where, in each game, the decision-makermust determine how much energy to expend. We assume that thereare only a small number of discrete energy choices for eachgame and that the more energy the decision-maker expends, themore likely he is to win that game. We solve for the optimaldecision with dynamic programming. With only two possible energychoices for each game, we show that it does not matter how energyis expended. In the case where there are three or more energychoices, we show how to take advantage of the structure of theproblem to determine the optimal sequence of decisions. As forpractical advice, the model suggests that when the decision-makerfalls behind in a match, he ought to switch to a more conservativeapproach by dividing his remaining energy evenly among all thepossible remaining games. Received 14 May 2003. Revised 5 January 2004.     

A study on anisotropy of L2 to L3 Coster-Kronig transition (f23) for Th and U elements

The Coster-Kronig transition, f₂₃, was determined using differential fluorescence cross sections of L_l X-ray for Th and U. The targets were irradiated an Am-241 radioisotope at the different incident angle. The L_l X-rays were counted with a Si (Li) detector at the different scattering angle varying from 60° to 90° at 10° intervals. For each angle, the Coster-Kronig transition probability, f₂₃, was found. An obtained Coster-Kronig transition probability value was fitted versus emission angle. According to present results we can say that the Coster-Kronig transition probability, f₂₃, shows isotropic distribution.     

Time-resolved imaging of latent fingerprints with nanosecond resolution

Imaging of latent fingerprints using time-resolved (TR) method offers a broader platform to eliminate the unwanted background emission. In this paper, a novel TR imaging technique is demonstrated and implemented, which facilitates the detection of latent fingerprints with nanosecond resolution. Simulated experiments were carried out with two overlapping fingerprints treated with two fluorescent powders having different lifetimes in nanosecond range. The dependence of the fluorescence emission intensity in nanosecond resolution of TR imaging is also revealed.     

Elemental composition of nanoclusters formed by pulsed irradiation with low-energy ions during Ge/Si epitaxy

Multilayer silicon structures with built-in layers of Ge nanoclusters were studied experimentally by Raman light scattering. The built-in layers were formed by the pulsed action of a low-energy beam of intrinsic ions during molecular-beam epitaxy. It is found that the ion-stimulated nucleation and the subsequent growth make it possible to obtain Ge nanoclusters almost free of Si.     

Mössbauer Study of Ceramic Finds from the Galería de las Ofrendas, Chavín de Huántar

Ceramic finds from the Galería de las Ofrendas at Chavín de Huántar and surface finds from the settlement of Chavín were characterised by combining the results of archaeological typology with archaeometric studies using neutron activation analysis, Mössbauer spectroscopy, X-ray diffraction and thin-section microscopy. Sherds from the pyramid Tello are included in the study as representative of local material. The analyses show that the vessels were made from different raw materials and that different firing procedures were used in their production. Sherds of certain styles largely exhibit similar types of Mössbauer patterns and in many instances also have similar element compositions. This supports the archaeological notion that the vessels were brought to Chavín from the provinces, perhaps on the occasion of a festivity.     

4英寸热氧化硅衬底上磁性隧道结的微制备

就如何在4英寸热氧化硅衬底上沉积高质量的磁性隧道结纳米多层薄膜材料和如何利用光刻方法微加工制备均匀性较好的磁性隧道结方面做了初步研究，并对磁性隧 道结的磁电性质及其工作特性进行了初步测量和讨论.利用现有的光刻设备和工艺条 件在4英寸热氧化硅衬底上直接制备出的磁性隧道结，其结电阻与面积的积 矢的绝对误差在10% 以内，隧穿磁电阻的绝对误差在7% 以内，样品的磁性隧道结性质具有较好的均匀性和一致性，可以满足研制磁随机存储器存储单元演示器件的基本要求. 关键词： 磁性隧道结 隧穿磁电阻 磁随机存储器 4英寸热氧化硅衬底