Fluorescence and HPLC Detection of Hydroxyl Radical by a Rhodamine-Nitroxide Probe and its Application in Cell Imaging

A rhodamine nitroxide probe was designed to detect the hydroxyl radical (·OH), which presented high selectivity for ·OH over other reactive oxygen species (ROS) and linear fluorescence response to ·OH produced by Fenton reaction. The product was detected by HPLC-MS, indicating that the main product of the reaction was O-methylhydroxylamine and the product peak areas measured by HPLC-UV/vis and HPLC-FLD both enhanced proportionally with the increase of ·OH concentration. The application of the probe in biological system was explored to trace the production of ·OH in cells under oxidative stress condition induced by rotenone which can inhibit the mitochondria respiratory chain complex I and we found that appropriate rotenone may induce the normal human liver cells (L02) and human hepatoma cells (HepG2) to produce ·OH at different degrees.     

Enhanced photoluminescence of CdSe quantum dots by the coupling of Ag nanocube and Ag film

The coupling of local surface plasmon(LSP) of nanoparticle and surface plasmon(SP) mode produced by metal film can lead to the enhanced electromagnetic field, which has an important application in enhancing the fluorescence of quantum dots(QDs). Herein, the Ag nanocube and Ag film are used to enhance the fluorescence of CdSe QDs. The enhancement is found to relate to the sizes of the Ag nanocube and the thickness of the Ag film. Moreover, we also present the fluorescence enhancement caused by only SP. The result shows that the coupling between metal nanoparticles and metal film can realize larger field enhancement. Numerical simulation verifies that a nanocube can localize a strong electric field around its corner. All the results indicate that the fluorescence of QDs can be efficiently improved by optimizing the parameters of Ag film and Ag cubes.     

Laser-induced damage of the optical films prepared by electron beam evaporation and ion beam sputtering in vacuum

The laser-induced damage characteristics and adsorption effects of organic contamination molecules of two high reflectors (HR) prepared by electron beam evaporation (EB) and ion beam sputtering (IBS) method at 1064 nm is investigated in vacuum. It is found that EB films show the performance degradation of laser induced damages in vacuum while for IBS film, seems to have no this effect, in comparison with air environment. In addition, EB coatings also have the strong affinity with organic contamination molecules, in contrast of IBS films. The results reveal that ion beam sputtering (IBS) method seem to be one of the favorite film deposition techniques of the optical films used in vacuum and space environments.     

MnO2/graphite electrodeposited under supergravity field for supercapacitors and its electrochemical properties

MnO₂/graphite electrode material is successfully synthesized by electrodeposition under supergravity field from manganese acetate and graphite suspending solution. X-ray diffraction and field emission scanning electron microscopy show that the obtained composite is γ-MnO₂/graphite. The process of depositing the MnO₂/graphite was shown by the schematic illustration. Galvanostatic charge/discharge and cyclic voltammograms tests are applied to investigate electrochemical performances of the composite electrodes prepared under supergravity fields. MnO₂/graphite synthesized under supergravity field exhibits good discharge capacitance and the specific capacitance is 367.77 F g^?1 at current density of 0.5 A g^?1. It is found that supergravity field has effects on the electrochemical performances of MnO₂/graphite material.     

全景视觉系统发展与应用

全景视觉系统具有视场范围大的特点,并且系统结构种类繁多,各有特色,已广泛应用在机器人导航、空间探测、视频监控、虚拟现实、环境感知技术等民用或军用领域;全景视觉系统由全景视觉光学成像系统、图像传感器、图像处理系统和输出图像显示等组成;文章主要从全景视觉成像角度对全景视觉系统进行分类,并详细介绍了每一类的全景成像原理、发展现状和应用情况,最后对每种类型全景视觉系统的优缺点给予分析总结。     

一种新型的渐变脊径向波导空间功率合成器设计

给出了一种新型的波导渐变脊的设计方法及其在波导空间功率合成器中的应用,该设计方法采用新型复合函数渐变曲线代替了传统的单一指数函数或三角函数渐变曲线,通过优化渐变脊的结构可以达到对频带内引起的谐振进行抑制的目的,并能降低功率合成器中的通路损耗;将该新型波导渐变脊结构用于30~40 GHz的波导空间功率合成器,经测试得到,由渐变脊组成的合成器部分在整个频段内插入损耗不足0.8 dB,整个无源合成器结构的输入端口驻波小于1.35,满足了合成器的使用要求。     

基于符号函数的注入反馈式蔡氏电路同步控制

蔡氏电路的状态变量不易引出,一般的同步控制方法难以硬件电路实现.针对此类含有电感、电容储能元件的混沌电路,提出一种注入反馈式混沌同步电路设计方法,通过引出状态变量,并在状态变量微分量未知的情况下对系统实施混沌控制.利用该方法,对运动行为不同的两个蔡氏系统,实现了基于符号函数的非线性投影同步控制研究,电路实验结果验证了该方法的可行性和有效性.     

一种有场旋转和集中功能的新型多功能电磁器件的设计与研究

基于变换光学理论设计了一种新型的多功能电磁器件—旋转集中器.它以特殊的方式引导电磁波使其传播方向在器件核心区发生指定角度的旋转,并同时实现电磁场能量向该核心区的集中.针对提出的三种等效的旋转集中器结构,分别推导了相应的本构参数表达式,并利用有限元软件对三种结构分别进行了全波仿真.仿真结果验证了本构参数表达式的正确性.这三种不同的结构中,前两种结构由三层介质构成,后一种简化为两层介质.对于给定的任意旋转角度和能量集中率,三种结构可以使电磁场发生等效的传播方向旋转和能量集中两种效果.这些结果有助于对旋转器和集中器机理的进一步理解,并为复合功能器件的设计奠定了更充分的理论基础.本文提出的旋转集中器在设计高效率接收天线和特殊电路封装互联器件等方面都有潜在的应用前景.     

基于Cu/SiO_x/Al结构的阻变存储器多值特性及机理的研究

采用氧化硅材料构建了Cu/SiOx/Al的三明治结构阻变存储器件.用半导体参数分析仪对其阻变特性进行测量,结果表明其具有明显的阻变特性,并且通过调节限制电流,得到了四个稳定的阻态,各相邻阻态的电阻比大于10,并且具有良好的数据保持能力.在不同温度条件下对各个阻态进行电学测试及拟合,明确了不同阻态的电子传输机理不尽相同:阻态1和阻态2为欧姆传导机制,阻态3为P-F(Pool-Frenkel)发射机制,阻态4为肖特基发射机制.根据电子传输机制,建立了铜细丝导电模型并对Cu/SiOx/Al阻变存储器件各个阻态的电致阻变机制进行解释.     

超宽带TEM喇叭天线优化设计与实验

针对用于成像雷达系统的超宽带TEM喇叭天线进行了优化设计,兼顾辐射性能、馈入反射和小尺寸条件,采用平滑渐变结构和加载技术代替原设计,增加了低频电流的回流通道,从而改善了天线的低频特性,增强了其定向辐射能力。在理论分析的基础上对其进行了仿真,并按照仿真结果实际制作了一副天线,对天线进行了测试。仿真与实测结果表明:在电压驻波系数小于2时,该天线具有11∶1的阻抗带宽,较强的辐射能力和良好的定性辐射特性,能够满足雷达系统的需求。