膨胀腔类超材料的传递损失研究*

声学超材料及结构已被广泛研究,其超结构通常利用3D打印技术实现,当结构刚度较小或者面积较大时,由声固耦合所导致的声学效果与设计不符的情况广泛存在。本文针对含有膨胀腔类的超材料,研究了声固耦合对其声学性能的影响,采用有限元计算结合阻抗管实验的方法,得到其传递损失,分析了声固耦合现象对传递损失的影响。结果表明：薄壁膨胀腔结构的作用频率范围与只考虑声学理论计算的设计不符,声固耦合现象对传递损失产生显著影响;采用增加膨胀腔壁厚、减少膨胀腔内径或选择金属材料的方式,都可以使得声固耦合现象对传递损失的影响减小;仿真结果与实验结果基本吻合。该研究结果说明：对于膨胀腔类超材料,当刚度较小或者面积较大时,对其进行声固耦合分析是完全必要的。     

中立型二阶非线性微分方程振动性的判据

Abstract. In this paper ,the oscillation criteria for the solutions of the nonlinear differential e-quations of neutral type of the forms:     

分压与限流线路特性分析

在电学实验的创新设计类问题中,常常涉及到滑线变阻器的分压线路和限流线路。本文对滑线变阻器的分压线路和限流线路的特性作一较系统的分析,对涉及到此类问题的实际工作具有指导意义。     

大学物理实验选修课的探讨

本文介绍了开设大学物理实验选修课的内容、时间安排及具体实施方案,对开好该课程具有一定的参考价值。     

A rapid in vitro assay of cobalamin in human urine and medical tablets using ICP-MS

A rapid and simple as well as sensitive inductively coupled plasma mass spectrometry (ICP-MS) method for the determination of cobalamin is described. Cobalamin in human urine and medicine tablet solutions was converted on-line into free cobalt ions in acid medium, the cobalt ions were then detected by ICP-MS. Cobalamin was determined by measuring the increase of integral counts per second intensity, which was linear over the cobalamin concentration range of 1.0 × 10⁻¹⁰ g mL⁻¹ to 8.0 × 10⁻⁵ g mL⁻¹, and the limit of detection was 0.05 ng mL⁻¹ (3σ). At the pump rate of 30 rotations per minute, one analysis cycle of cobalamin, including sampling and washing, could be accomplished in 0.5 min with the relative standard deviations of less than 5 %. The proposed procedure was applied successfully in monitoring cobalamin in human urine without any pretreatment process and in rapid determination of cobalamin in multivitamin tablets.     

Uniform AMoO4:Ln (A=Sr, Ba; Ln=Eu, Tb) submicron particles: Solvothermal synthesis and luminescent properties

Rare-earth ions (Eu³⁺, Tb³⁺) doped AMoO₄ (A=Sr, Ba) particles with uniform morphologies were successfully prepared through a facile solvothermal process using ethylene glycol (EG) as protecting agent. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), photoluminescence (PL) spectra and the kinetic decays were performed to characterize these samples. The XRD results reveal that all the doped samples are of high purity and crystallinity and assigned to the tetragonal scheelite-type structure of the AMoO₄ phase. It has been shown that the as-synthesized SrMoO₄:Ln and BaMoO₄:Ln samples show respective uniform peanut-like and oval morphologies with narrow size distribution. The possible growth process of the AMoO₄:Ln has been investigated in detail. The EG/H₂O volume ratio, reaction temperature and time have obvious effect on the morphologies and sizes of the as-synthesized products. Upon excitation by ultraviolet radiation, the AMoO₄:Eu³⁺ phosphors show the characteristic ⁵D₀–⁷F_1–4 emission lines of Eu³⁺, while the AMoO₄:Tb³⁺ phosphors exhibit the characteristic ⁵D₄–⁷F_3–6 emission lines of Tb³⁺. These phosphors exhibit potential applications in the fields of fluorescent lamps and light emitting diodes (LEDs).     

Synthesis and characterization of Eu-doped hydroxyapatite through a microwave assisted microemulsion process

Europium doped hydroxyapatite (Eu:HAp) nanosized particles with multiform morphologies have been successfully prepared via a simple microemulsion-mediated process assisted with microwave heating. The physicochemical properties of the samples were well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), photoluminescence (PL) spectra, and the kinetic decays, respectively. The results reveal that the obtained Eu:HAp particles are well assigned to the hexagonal lattice structure of the hydroxyapatite phase. Additionally, it is found that samples exhibit uniform morphologies which can be controlled by altering the pH values. Furthermore, the samples show the characteristic ⁵D₀–⁷F_1–4 emission lines of Eu³⁺ excited by UV radiation.     

Computational study on the reaction mechanism of hydrosilylation of carbonyls catalyzed by high-valent rhenium(V)-di-oxo complexes

Density functional theory (DFT) calculations have been performed to elucidate the reaction mechanism of hydrosilylation of carbonyl compounds catalyzed by high-valent rhenium(V)-di-oxo complexes ReO2I(PR3)2 (R = Me, Ph). The calculations suggest that the most favorable mechanism involves the rate-determining dissociative [2 + 2] addition of the Si-H bond across a Re=O bond to form a Re(V) hydrido siloxy intermediate; this is followed by carbonyl coordination, reduction of the carbonyl, rearrangement, and final intramolecular nucleophilic attack from the alkoxy group to the silyl center (dissociative retro-[2 + 2] addition). It was also found that the additional oxo ligand in the ReO2I(PR3)2 complexes promotes the [2 + 2] addition across the rhenium-oxo bond both kinetically and thermodynamically, as compared to the neutral rhenium(V)-mono-oxo complex ReOCl3(PMe3)2. The effect of different silanes on the [2 + 2] addition barriers is also studied.     

Spatially regularized and locality-constrained linear coding for human action recognition

To reduce quantization error, preserve the manifold of local features, distinguish the ambiguous features, and model the spatial configuration of features for Bag-of-Features (BoF) model-based human action recognition, a novel feature coding method called spatially regularized and locality-constrained linear coding (SLLC) is proposed. The spatial regularization and locality constraint are involved in the feature coding phase to model the spatial configuration of features and preserve their nonlinear manifold. The action recognition experimental results on benchmark datasets show that SLLC achieves better performance than the state-of-the-art feature coding methods such as soft vector quantization, sparse coding, and locality-constrained linear coding.