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991.
A variety of novel N-t-butyl-N'-aminocarbonyl-N-(substituted)benzoylhydrazines containing a -aminoalkylphosphonate groups were synthesized by the addition of N-t-butyl-N-(substituted)benzoylhydrazines to a -isocyanatoalkylphosphonates, which were synthesized by the reaction of a -aminoalkylphosphonates with triphosgene in good yields. The structures of products including by-products were confirmed by 1H NMR, 31P NMR, IR, mass spectroscopy, and elemental analysis. 相似文献
992.
Rui Duarte Xavier Carton Xavier Capet Laurent Chérubin 《Regular and Chaotic Dynamics》2011,16(6):577-601
This paper addresses the instability of a two-layer coastal current in a quasigeostrophic model; the potential vorticity (PV) structure of this current consists in two uniform cores, located at different depths, with finite width and horizontally shifted. This shift allows both barotropic and baroclinic instability for this current. The PV cores can be like-signed or opposite-signed, leading to their vertical alignment or to their hetonic coupling. These two aspects are novel compared to previous studies. For narrow vorticity cores, short waves dominate, associated with barotropic instability; for wider cores, longer waves are more unstable and are associated with baroclinic processes. Numerical experiments were performed on the f-plane with a finite-difference model. When both cores have like-signed PV, trapped instability develops during the nonlinear evolution: vertical alignment of the structures is observed. For narrow cores, short wave breaking occurs close to the coast; for wider cores, substantial turbulence results from the entrainment of ambient fluid into the coastal jet. When the two cores have opposite-signed PV, the nonlinear regimes range from short wave breaking to the ejection of dipoles or tripoles, via a regime of dipole oscillation near the wall. The Fourier analysis of the perturbed flow is appropriate to distinguish the regimes of short wave breaking, of dipole formation, and of turbulence, but not the differences between regimes involving only vortex pairs. To explain more precisely the regimes where two vortices (and their wall images) interact, a point vortex model is appropriate. 相似文献
993.
994.
Rui Wang Chao Zhang Weizhi Wang Tianxi Liu 《Journal of polymer science. Part A, Polymer chemistry》2010,48(21):4867-4874
Novel nanoparticles based on conjugated polymer with good fluorescent properties were synthesized by Suzuki coupling reaction using certain surfactants as one kind of special emulsion polymerization. The luminescent properties of the prepared nanoparticles could be controlled by selecting different monomers. Without using substances comprising any heavy metal element, these fluorescent nanoparticles show very good biocompatibility with cells, thus showing potential applications in cell biolabeling, drug delivery tracing, organic light‐emitting diodes, flat displays, and other areas. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
995.
Wei Li YANG Jun TIAN Qiang ZHANG Shu Lin PENG Li Sheng DING* Chengdu Institute of Biology Chinese Academy of Sciences Chengdu School of Pharmacy West China University of Medical Sciences Chengdu 《中国化学快报》2001,(2)
There are only three species in the genus Diuranthera (Liliaceae), which is endemic in the southwest of China1. Four steroidal saponins, diuranthosides A-C and chloromalo-side A were isolated from the fresh roots of D. major. This paper deals with the structure elucidation of two new steroidal saponins, diuranthosides D and E, which were isolated from the methanolic extract of whole plant of D. inarticulata Wang et K. Y. Lang.Diuranthoside D (1), [(]-38 (c 0.08, pyridine), afforded galac… 相似文献
996.
Influence of the KTP crystal boundary temperature on conversion efficiency in high power green laser
Degang Xu Jianquan Yao Baigang Zhang Shiyong Zhao Rui Zhou Xin Ding Wuqi Wen Peng Wang 《中国光学快报(英文版)》2005,3(2)
The influence of the KTiOPO4 (KTP) crystal boundary temperature on conversion efficiency in high power green laser has been studied theoretically and experimentally. Temperature distribution inside the KTP crystal has been analyzed by solving the thermal conductivity equation. From the temperature distribution inside the KTP crystal, we have calculated the optimal phase-matching angles of the type-Ⅱ KTP crystal as a function of temperature. The second-harmonic conversion efficiency as a function of temperature has also been calculated. In the experiment, two KTP crystals with different phase-matching angles were used in the intrcavity-frequency-doubled resonator. When the boundary temperature of KTP-A (φ = 23.6°,θ = 90° under the condition of 27 ℃ temperature) was setting at 4 ℃, a maximum green light power of 104 W was generated at repetition rate of 20.7 kHz and pulse width of 132 nm with pumping current of laser diode of 18.3 A, leading to 10.2% optical-to-optical conversion efficiency. When KTP-B crystal (φ = 24.68°, θ = 90° under the condition of 80 ℃ temperature) was employed, an average output power of 110 W at 532 nm has been achieved with values of 11.5% and 2% for the optical-to-optical efficiency and the instability, respectively. The optimal boundary temperature of this KTP crystal has been found to be 48.8 ℃. 相似文献
997.
We prove two results about the problem of finding the Helly number for line transversals to a family of parallel triangles in the plane: (1) If each three triangles of a family of parallel right triangles are intersected by an ascending (or a descending) line, then there is an ascending (or a descending) line that intersects all 相似文献
998.
999.
1000.
一种超高耐久混凝土——梯度结构混凝土 总被引:2,自引:1,他引:1
分析超高耐久混凝土的研究现状,提出了一种高耐久、低成本的超高耐久混凝土--梯度结构混凝土(Gradient Structural Concrete,简称GSC),采用电量法和氯离子扩散系数法来评价梯度结构混凝土的抗氯离子渗透性能,最后进行梯度结构混凝土的寿命预测与成本分析.结果表明,高性能混凝土(High Performance Concrete,简称HPC)、无细观界面过渡区水泥基复合材料(Meso-interfacial transition zone-free cement-based materials,简称 MIF)和梯度结构混凝土MIF-HPC的6 h导电量和氯离子扩散系数的排列顺序均为:HPC>MIF-HPC>MIF,其抗氯离子渗透性能排列顺序为:MIF>MIF-HPC>HPC.梯度结构混凝土的成本会有所增加,但由于其氯离子渗透性能大幅降低,其使用寿命得到大幅延长,使得其年损耗费用大幅下降. 相似文献