全文获取类型
收费全文 | 2800篇 |
免费 | 531篇 |
国内免费 | 958篇 |
专业分类
化学 | 2045篇 |
晶体学 | 89篇 |
力学 | 221篇 |
综合类 | 98篇 |
数学 | 450篇 |
物理学 | 1386篇 |
出版年
2024年 | 3篇 |
2023年 | 23篇 |
2022年 | 87篇 |
2021年 | 87篇 |
2020年 | 89篇 |
2019年 | 93篇 |
2018年 | 95篇 |
2017年 | 135篇 |
2016年 | 90篇 |
2015年 | 138篇 |
2014年 | 219篇 |
2013年 | 236篇 |
2012年 | 214篇 |
2011年 | 243篇 |
2010年 | 240篇 |
2009年 | 252篇 |
2008年 | 284篇 |
2007年 | 254篇 |
2006年 | 276篇 |
2005年 | 230篇 |
2004年 | 165篇 |
2003年 | 105篇 |
2002年 | 101篇 |
2001年 | 111篇 |
2000年 | 147篇 |
1999年 | 74篇 |
1998年 | 32篇 |
1997年 | 26篇 |
1996年 | 12篇 |
1995年 | 9篇 |
1994年 | 18篇 |
1993年 | 16篇 |
1992年 | 32篇 |
1991年 | 21篇 |
1990年 | 21篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 11篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1966年 | 4篇 |
1965年 | 2篇 |
1964年 | 4篇 |
1960年 | 2篇 |
排序方式: 共有4289条查询结果,搜索用时 15 毫秒
991.
992.
TANG Zhu-Rui HUANG Cai-Hong TAN Wen-Bing HE Xiao-Song ZHANG Hui LI Dan XI Bei-Dou 《分析化学》2018,46(3):422-430
Dissolved organic matter (DOM) is the most active fraction of compost organic matter. The presence of the redox-active functional groups in DOM allows it to act an electron shuttle to promote the electron transfer between microorganisms and terminal electron acceptors. In this study, the electron transfer capacities (ETCs) of compost DOM samples at eight different composting stages were determined by electrochemical method. 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and Diquat dibro-mide monohydrate (DQ) were used to measured electron donating capacity (EDC) and electron accepting capacity (EAC) at working voltage 0.61 V/–0.49 V, respectively. The evolution characteristics of the chemical structures and components were analyzed by combining the three-dimensional fluorescence spectra, Fourier transform infrared (FTIR) spectra and elemental analysis. The results showed that the EDC of DOM increased from 16.850 μmol e? (g C)?1 to 22.077 μmol e? (g C)?1, The EAC decreased from 1.866 μmol e? (g C)?1 to 1.779 μmol e? (g C)?1. The results of three-dimensional fluorescence spectroscopy showed that the relative contents of humic-like and protein-like components gradually increased and decreased, respectively, during the composting process. The humuc-like components were the main contributor for the ETC of DOM. FTIR spectra showed that there was no significant change in the hydroxyl and carboxyl group contents of DOM during composting, suggesting no contribution of these function groups to the ETC of DOM. The elemental analysis showed that the content of oxygen in the DOM increased during the composting process, while the sulfur-containing group might be dominated contributor for its ETC. 相似文献
993.
������������������ ������ ����̷ ������ ������ ������Ӣ�� 《核聚变与等离子体物理》2020,39(4):331-337
The brazing process of chlorofluorocarbon/oxygen-free-copper (CFC/OFC) composite mockup and CuCrZr at 710~750°C by vacuum brazing and with STEMET-1101 amorphous filler is studied. Firstly, the microstructure and melt behaviors of the filler are characterized by means of XRD and differential scanning calorimetry and then the organism form, elemental distributions, phase structures, and mechanical property in the bonding seams are studied by using optical microscopy, electron probe microanalysis and tensile tests. The thermal fatigue property of CFC/OFC/CuCrZr brazing mockup is measured with the high heat flux facility. The results show that the bonding seam consists of Ni(Cr, Cu)2P particles, Cu(Ni)3P phase and Cu matrix in brazing temperature of 710~750°C, which is smooth and crack-free. Especially, a continued intermetallic phase network in the bonding seam is depressed in the case of 750°C/15min treatment. The welding strength of the OFC/CuCrZr is higher than tensile strength of OFC. The bonding strength of CuCrZr/CuCrZr joint is 210MPa and fracture is partly ductile. The CFC/Cu/CuCrZr mockup prepared in the case of 750°C/15min treatment can tolerate 7MW·m-2 high heat flux under 1000 cycles. 相似文献
994.
以硫脲为原料,通过简单绿色的球磨法提高原位硫掺杂g-C3N4的光催化活性。利用X射线衍射、扫描电子显微镜、元素分析、X射线光电子能谱、紫外-可见漫反射光谱及光致发光光谱等测试方法对其结构和光学特性进行表征。以亚甲基蓝为目标污染物,评价了在不同物料溶剂比下球磨的硫掺杂g-C3N4的可见光催化性能。结果表明,湿式球磨后的硫掺杂g-C3N4光催化剂比表面积增大,反应活性位点的数量增加,带隙宽度也适当增大,氧化还原能力增强。另外,湿式球磨后样品的表面缺陷减少,聚合度增加,促进了光生电子-空穴的有效分离和转移,从而降低其复合率,协同提高了硫掺杂g-C3N4的可见光催化性能。湿式球磨后的样品在可见光照射下对亚甲基蓝的降解速率分别比未球磨的样品和干式球磨后的样品提高了1.5和3.6倍。 相似文献
995.
A crucial element in the reverse engineering process is to obtain 3D data of the part or its CAD model. A new method is presented in this paper, which combines layer-by-layer cutting and scanning on each cross-section of a part with a milling machine and an image scanner respectively. The method can capture the internal and external profile informations of a complex-shaped part at the same precision simultaneously. When data files of 2D edges are imported into the 3D CAD/CAM package, the 3D data or 3D CAD model is acquired. According to the customers' requirements, the system can reach the highest accuracy of 5.4 μm, and a resolution of 2.7 μm in obtaining the 2D edges. The product is completely made now, on which experiments are conducted, which demonstrate the higher accuracy and efficiency. 相似文献
996.
Using variational methods and Morse theory, we obtain some existence results of multiple solutions for certain semilinear problems associated with general Dirichlet forms. 相似文献
997.
998.
3×n阶网络等效电阻的另一个普适规律 总被引:7,自引:1,他引:6
再次研究了3×n阶电阻网络的等效电阻,通过网络分析构建差分方程组模型,应用矩阵变换方法巧解差分方程组,给出了3×n阶电阻网络等效电阻的另外一个优美、简洁的普适规律,同时给出了无穷3×n阶电阻网络的等效电阻,并在最后对特殊情形的相关结果进行了比较与验证. 相似文献
999.
Shu-hong CHEN & Zhong TAN School of Mathematical Science Xiamen University Xiamen China 《中国科学A辑(英文版)》2007,50(1):105-115
In this paper, we are concerned with the partial regularity for the weak solutions of energy minimizing p-harmonic maps under the controllable growth condition. We get the interior partial regularity by the p-harmonic approximation method together with the technique used to get the decay estimation on some Degenerate elliptic equations and the obstacle problem by Tan and Yan. In particular, we directly get the optimal regularity. 相似文献
1000.
The thermodynamic properties of LiBC are investigated by using the full-potential linearized muffin-tin orbital method (FP-LMTO) within the frame of density functional theory (DFT) and using the quasi-harmonic Debye model. The dependencies of the normalized lattice parameters a/a0 and c/c0, the ratio (c/a)/2, the normalized primitive volume V/V0 on pressure and temperature are successfully obtained. It is found that the interlayer covalent interactions (Li-B bonds or Li-C bonds) are more sensitive to temperature and pressure than intralayer ones (B-C bonds), as gives rise to the extreme lattice anisotropy in the bulk hcp LiBC. 相似文献