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排序方式: 共有832条查询结果,搜索用时 62 毫秒
91.
N. Kent Dalley Jerald S. Bradshaw Xiaolan Kou Reed M. Izatt Krzysztof E. Krakowiak 《Journal of heterocyclic chemistry》1995,32(4):1201-1204
The solid state structure of the Na[2.2.2]C1 · 3H2O complex has the sodium ion displaced towards one of the cryptand nitrogens and the chloride and water molecules associated by hydrogen bonds to form a pseudo cube with two chloride ions at opposite corners of the cube and water oxygens at the other six corners. 相似文献
92.
Huakuan Lin Shourong Zhu Appolin Bave Kondiano Xuncheng Su Fuping Kou Yunti Chen 《Polyhedron》1998,17(25-26)
The kinetics of the acid dissociation of copper(II) complexes of novel C-functionalized macrocyclic dioxotetraamines has been studied by means of a stopped-flow spectrophotometer. The acid dissociation rate follows the law Vd = CcomkK1K2H 2/(1+K1H+K1K2H 2). From the experimental facts we have obtained, the dissociation kinetics are interpreted by a mechanism involving the negatively charged carbonyl oxygen of the complex being rapidly protonated in a pre-equilibrium step, the rate-determining step being intramolecular hydrogen (enolic tautomer) migration (to imine nitrogen). The dissociation rate reached a plateau in the strongly acidic solution. By means of temperature coefficient method, ΔH φ, ΔS φ of the pre-equilibrium step and ΔH ≠, ΔS≠ of the rate-determining step were obtained. The results of 13-membered macrocyclic dioxotetraamines have been discussed. The influence of the substituents to the acid dissociation rates has also been discussed. The Bronsted type linear free energy relationships do also exist in these C-functionalized dioxotetraamine copper(II) complexes. 相似文献
93.
KouZhejun ChengJiangang YaoZhenhan WangFujun 《Acta Mechanica Solida Sinica》2003,16(3):205-209
A smooth C1 interpolation for two-dimensional contact problems using paxametric curve technique was developed and implemented. The parametric curve can ensure C1 continuity of the contact surfaces and provide a unique surface normal vector. Some numerical examples were used to illustrate the advantages of the newly developed representation of contact surface. The results reveal a significant improvement in the prediction of contact stresses and contactarea. The predicted contact stresses are less sensitive to the mismatch in meshes of the different contacting bodies. 相似文献
94.
Separation and determination of 10-hydroxy-2-decenoic acid in royal jelly by capillary electrophoresis 总被引:1,自引:0,他引:1
Summary The application of capillary electrophoresis (CE) to the separation and determination of the active ingredient, 10-hydroxy-2-decenoic
acid, in royal jelly with direct on-column UV detection at 214 nm is described. Using a cathodic injection and anodic detection
scheme, 10-hydroxy-2-decenoic acid (10-HDA) was separated and detected in less than 10 min in a fused silica capillary column
with a phosphate buffer at pH 7.3 with an applied voltage of 20 KV followed by direct UV detection. The use of cetyltrimethylammonium
bromide (CTAB) as electroosmotic flow modifier allows the rapid separation of 10-HDA from other constituents in royal jelly
by reversing the direction of electroosmotic flow. The influence of organic solvents in the electrolyte on separation selectivity
is also discussed. 相似文献
95.
A system for transformation and regeneration of Lycium barbarum L. , an important Chinese medical plant, has been established. Young stem segments from Lycium barbarum L. were infected with Agrobacterium tumefaciens C58cl(pGV3850: :ineo1130), and the transformed calli selected from the callus induction medium containing 50 fig/ml kanamycin could regenerate buds on differentiation medium containing 25 μg/ml kanamycin. 30% of the regenerated buds were normal in morphology. The normal buds could develop into whole plantlets after they were transferred to the rooting medium to induce roots. Nopa-line detection, NPT-Ⅱ enzyme activity assay and Southern blotting hybridization indicated that the foreign genes had been integrated into the genome of Lycium barbarum L. and expressed in the plant. In the processes of experiments, it was found that (i) after the pre-processes, the explants which formed callus quickly were easy to transform ; (Ⅱ) the rate of normal regenerated plants from transgenic calli was hig 相似文献
96.
Wang Q.S. Kou C.S. McDermott D.B. Lin A.T. Chu K.R. Luhmann N.C. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1992,20(3):163-169
For pt.I, see ibid., vol.20, no.3, p.155-162 (1992). Based on an analytical study of the stability problems of gyrotron traveling wave amplifiers (gyro-TWTs), an extremely high power second-harmonic gyro-TWT has been designed, evaluated and optimized with a self-consistent nonlinear numerical simulation code. The design, which is based on the magnetron-injection-gun (MIG)-type beam, is presented. Using a 100 kV, 25 A MIG beam with α=1 and an axial velocity spread of 5%, nonlinear self-consistent analysis of a three-stage second-harmonic gyro-TWT amplifier predicts a peak output power of 533 kW, peak efficiency of 21.3% and a 7.4% saturated bandwidth, which verifies the theoretical predictions that a stable harmonic gyro-TWT can generate power levels an order of magnitude higher than those possible from a fundamental gyro-TWT. It is shown that the positioning of the electron beam is very important. A multistage structure is used to recover the loss in gain resulting from shortening the interaction sections to ensure stability 相似文献
97.
Nakata K Sakamoto M Taguchi S Yoshida N Shimazu K 《Journal of colloid and interface science》2005,288(2):634-637
The water-insoluble poly-beta-cyclodextrin (poly-CD)/Nafion composite film was easily prepared by casting a mixed solution of poly-CD and Nafion onto substrate plates. FT-IR measurements showed that the 50/50 wt% poly-CD/Nafion composite film remained stable on the glass and quartz substrates after immersion in water for more than 3 h, while a pure poly-CD film was almost completely dissolved by immersion within 1 h. The film stability was also evaluated from the amount of p-nitrophenol (p-NP) inclusion in the film, which was determined from the decrease in UV-vis absorbance of the p-NP solution into which the film was immersed. The composition dependence of the inclusion amount showed that the film was stable up to 50 wt% CD, but became less stable with further increase in the CD concentration in the film. From the isotherms for the inclusion of p-NP and 1-naphthoate (1-Naph) into the film, the inclusion (stability) constants were determined to be 3.7x10(3) M(-1) and 1.9x10(2) M(-1), respectively. These results show that the selective inclusion of CD is retained after preparation of the composite film. 相似文献
98.
99.
相干性对X光全息图分辨率的影响 总被引:4,自引:4,他引:0
分析计算了X光束的相干性对X光全息图分辨率的影响,结论是X光无透镜傅里叶变换全息术所要求的相干长度和分辨率与样品尺雨戌二次线型关系;X光同轴全息术所要求的相干长度和分辨率的平方以及样品到全息图的距离成正比。 相似文献
100.
在电子扩散微分方程的基础上,研究了染料敏化太阳电池光生电流和光生电压随光照强度不同的变化关系.提出敏化太阳电池串联阻抗功率损耗模型,理论模拟了大面积电池(有效面积>1 cm2)光电转换效率随多孔薄膜有效面积宽度变化的曲线、透明导电基底膜与银栅极的比接触电阻以及在不同入射光强下银栅极体电阻对大面积染料敏化太阳电池光伏性能的影响.结果表明透明导电基底膜的方块电阻和银栅极体电阻对大面积染料敏化太阳电池的性能有很大影响,而这种影响随光强的减弱逐渐减小.
关键词:
染料敏化
太阳电池
串联阻抗
光电转换效率 相似文献