大面积染料敏化太阳电池的串联阻抗特性研究

在电子扩散微分方程的基础上，研究了染料敏化太阳电池光生电流和光生电压随光照强度不同的变化关系.提出敏化太阳电池串联阻抗功率损耗模型，理论模拟了大面积电池（有效面积>1 cm²）光电转换效率随多孔薄膜有效面积宽度变化的曲线、透明导电基底膜与银栅极的比接触电阻以及在不同入射光强下银栅极体电阻对大面积染料敏化太阳电池光伏性能的影响.结果表明透明导电基底膜的方块电阻和银栅极体电阻对大面积染料敏化太阳电池的性能有很大影响，而这种影响随光强的减弱逐渐减小. 关键词： 染料敏化 太阳电池 串联阻抗 光电转换效率

Model for series resistance photovoltaic performance of large-scale dye-sensitized solar cells

The dependence of photocurrent and photovoltage of dye-sensitized solar cell on the incident light intensity were investigated based on the electron continuity diffusion equation. For the first time a model was presented for power loss of series resistance in dye-sensitized solar cell, and were simulated the influence of the active-area width of nanoporous film, the effect of special contact resistance on the photo-electric conversion efficiency, as well as the silver impedance in lager-scale solar cells with active area greater than 1 cm² under different illuminations. It was found that the efficiency strongly depends on the width of active area and the silver impedance under strong illumination, nevertheless, this dependence is not obvious under poor illumination.