改进最小费用流相位解包裹算法

在不同解包裹算法中,最小费用流(MCF)解包裹法可以限制残差点误差远程扩散,并将误差优先限制在低相干区域,有利于保证高相干区域解包裹结果不受干扰,精度较高,但残差点数量较多时计算效率很低。为缩短解包裹时间,提出一种残差点预处理方法。该方法将残差点视作正负电荷,通过电场力,引导距离较近的异号残差点互相抵消,大幅减少残差点数量,从而提高解包裹计算效率。仿真数据和实验数据表明,残差点预处理对MCF解包裹精度影响很小,在残差点数量超过3000时可以大幅提高解包裹计算效率。     

Tribological Behaviors of Fluorinated Polyimides at Different Temperatures

4,4′-(hexafluoroisopropylidene) diphthalic anhydride (6FDA)-based copolyimides were synthesized and the tribological properties of the copolyimides with different heat histories were studied at different temperatures. Fluoride-containing polyimide (PI) showed better thermal stability, decreased friction coefficients, and postponed the consequence of friction variation, which depended on temperature, than nonfluorinated PI. Thermal treatments seemed to increase the friction coefficients of copolyimides, and reduced the tensile strengths of the materials. The effects of applied load (P) and sliding speed (V) on tribological behaviors of thermally treated copolyimides were also examined and the variations of friction coefficient depending on PV values were investigated for clear understanding of its relationship between PV value and friction coefficient with different thermal treating time. Distortions of net structures of the chains and molecular motion contributed to variations of tribological properties of thermal treated copolyimides.     

Rhodium(III)-catalyzed intermolecular direct amination of aromatic C-H bonds with N-chloroamines

A Rh(III)-catalyzed direct aromatic C-H amination is achieved using N-chloroamines as a reagent. Furthermore, we also developed a one-pot amination protocol involving in situ chlorination of the secondary amines. The catalytic amination operates at mild conditions with excellent functional group tolerance and regioselectivity.     

Highly efficient synthesis of a class of novel chiral-bridged atropisomeric monophosphine ligands via simple desymmetrization and their applications in asymmetric Suzuki-Miyaura coupling reaction

A series of novel chiral-bridged atropisomeric monophosphine ligands were synthesized via convenient and simple pathways. The prepared ligands, especially for ligand 7d, were found to be highly effective in the Pd-catalyzed Suzuki-Miyaura coupling reaction. The steric hindrance and electronic effect of substrates on the reactivity and enantioselectivity were explored preliminarily.     

Enhanced luminescence from Si quantum dots/SiO2 multilayers by hydrogen annealing

Si quantum dots/SiO₂ multilayers were prepared by annealing a-Si:H/SiO₂ stacked structures at 1100 °C . Photo- and electro-luminescence band around 750 nm can be observed from Si QDs/SiO₂ multilayers due to the recombination of electron-hole pairs in Si QDs/SiO₂ interfaces. The electro-luminescence intensity was obviously enhanced after post hydrogen annealing at 400 °C. Electron spin resonance measurements were used to characterize the change of the defect states after hydrogen annealing. It is found that there exists a-centers (g value = 2.006), which is related to the Si dangling bonds in Si QDs in our samples. Hydrogen annealing can significantly reduce non-luminescent a-centers and enhance the electro-luminescence intensity consequently.     

无线/水声通信浮标技术研究及其实现

本文研究并设计实现了一种用于浅海水声信道多速率通信的无线/水声通信(racom)浮标,介绍了其水声通信和无线通信技术方案和工程设计与实现。本文设计的浮标综合了水声通信、DSP信号处理和无线电通信等技术,也可以用作水声通信/传感网络中的无线/水声通信(racom)网关节点。海上试验验证了本浮标总体设计方案的可行性。海上试验中,浮标无线通信距离达到15.2 km,误码率不大于10 6;除2 kbps速率外,浮标各种速率的水声通信数据传输误码率都小于1%,最大通信作用距离达到9.6 km;同时,试验也验证了浮标与水下运动平台之间的通信功能。     

遗传算法在炸药爆轰参数计算中的应用

为解决爆轰参数计算中自变量取值范围要求严格以及收敛性差等问题,在最小自由能法的基础上,引入遗传算法建立了炸药爆轰参数的计算方法,并利用典型单质炸药和混合炸药的实验结果对计算结果进行了验证。结果表明:采用该方法计算得到的单质和混合炸药的爆速、爆压与实验测试结果基本一致,误差在5%以内,满足炸药性能预估的要求;该方法人工干预弱,只需一次性确定少数主要组分物质的量的变化范围,可适应于多配方优化计算。     

热处理温度对化学镀磁性ICF玻璃靶丸特性的影响

 在300,700和1 000 ℃温度下,对化学镀Ni-P合金涂层后的磁性ICF玻璃靶丸进行热处理,通过X射线衍射仪（XRD）、扫描电子显微镜（SEM）和振动样品磁强计（VSM）对热处理后化学镀ICF玻璃靶丸的结构、形貌和磁性能进行了表征。结果表明：化学镀ICF玻璃靶丸经过热处理后,Ni-P涂层晶化为晶态合金层,涂层的组成颗粒直径和磁性能随着热处理温度的升高而不断增加,可望用于磁悬浮实验研究。     

Curing theory of A f -A g type free radical polymerization (II)

By means of the polymer statistical thrury. the A _f -A _g type nonlinear free radical polymerization is investigated to give the number of effective elastic chains, the number of effective elastic mers and the average length for the elastic chains. The corresponding quantities for the dangling chains, the number of effective cross-linkage and the mod-ulus are also obtained. Furthrrmore, the nurnber- and weight-fractions of elastic chains are deduced. Project supported by the National Natural Science Foundation of China (Grant No. 29673018), the Ph. D. funds of the State Education Commission of China.     

条形靶激光等离子体复合特性的理论研究

报导一个条形靶激光等离子体的计算程序JLULP1,并首次用此程序研究了条形Si靶激光等离子体的空间和时间分布特性及其与靶形状之间的关系.结果表明,条形靶产生的激光等离子体比圆柱形靶产生的激光等离子体更有利于三体复合.