三波长-分光光度法测定大叶落地生根中总黄酮的含量

以木犀草素-7-O-β-D-葡萄糖苷为对照品、AlCl3作为显色剂,建立了三波长分光光度法测定大叶落地生根中总黄酮含量的方法。结果显示,总黄酮在0~0.01g/L范围内呈良好的线性关系,相关系数r=0.9999,平均回收率为101.4%,RSD=3.7%(n=4)。该方法可校正混浊背景倾斜度的影响,消除重叠吸收曲线的干扰,适用于植物中总黄酮的测定。     

MgB_2和Mg_(0.93)Li_(0.07)B_2的电阻率与霍尔效应研究

测量了MgB2 和Mg0 .93Li0 .0 7B2 的电阻率 ρ(T)与霍尔系数RH(T)的温度依赖关系 .电阻率的测量结果表明 ,MgB2 和Mg0 .93Li0 .0 7B2 的正常态电阻率与温度有平方的依赖关系 .MgB2 和Mg0 .93Li0 .0 7B2 的超导转变温度几乎相同 .霍尔系数的测量结果表明 ,MgB2 和Mg0 .93Li0 .0 7B2 的载流子类型为空穴型 ,二者的霍尔系数都随温度升高而减小 ,且Mg0 .93Li0 .0 7B2 的霍尔系数比MgB2 略有减小 ,这可能与Li掺杂引入空穴有关 .二者的霍尔角都与温度平方呈线性关系 .     

Detection of alkanolamines in liquid cement grinding aids by HPLC coupled with evaporative light scattering detector

Triethanolamine (TEA), triisopropanolamine (TIPA), diethanol isopropanolamine (DEIPA) are necessary cement additives, and knowing their contents is needed for quality control and also to understand final properties of the cement. Whether it is the production of grinding aids, technical research and development or application research all involve the detection of grinding aids. This work developed a simple analytical technique for the simultaneous analysis of these alkanolamines in liquid cement grinding aids using high-performance liquid chromatography (HPLC) combined with evaporative light scattering detection (ELSD). HPLC was conducted by an XBridge C18 column (with dimensions 4.6 × 250 mm and 5 µm particles) using methanol and 0.1% trichloroacetic acid as mobile elution phases. The ELSD sprayer and drift tube temperatures were 60 ºC and 90 ºC, respectively. HPLC-ELSD developed in this work demonstrated 1) high sensitivity with limits of detection for the three analytes are 0.15, 0.54, 1.04 µg/mL; 2) good linearity with correlation coefficients equal to 0.997–0.999 over the tested concentration range; 3) excellent repeatability with intra- and interday coefficient of variation (CV) below 2.71% and 4, satisfactory accuracy with recovery in the 95.5%–100.8% range. This novel method is a powerful, time- and costeffective tool for alkanolamine analyses and quality control.     

固体热容激光器与热稳态固体激光器温度场和应力场的比较研究

 建立了3维温度场及应力场模型，并采用有限元分析方法对Nd:YAG作为激活介质的固体热容激光器与热稳态固体激光器进行了对比研究。激光二极管阵列距离晶体3.5 mm，阵列功率2×4.2 kW，bar间隔0.4 mm，每bar发光面积为1 μm×5 mm，频率100 Hz，脉宽100 μs，Nd:YAG晶体初始温度20 ℃，冷却水温20 ℃。计算结果表明：热容模式激光介质的表面温度高于中心温度，稳态模式刚好相反, 稳态模式温差极值（19.8 ℃）是热容模式(6.4 ℃)的3.1倍,温度梯度极值(11.9 ℃/mm)是热容模式(2.46 ℃/mm)的4.8倍，热流密度极值(0.136 W/mm²)是热容模式(0.021 W/mm²))的6.4倍；稳态模式激光介质的表面出现张应力，中心出现压应力，热容模式则刚好相反，稳态模式压应力极值(18.27 MPa)是热容模式(12.1 MPa)的1.5倍，张应力极值(38.39 MPa)是热容模式(10.3 MPa)的3.9倍。由于晶体可以承受的压应力的破坏阈值远高于张应力，所以热容模式的固体激光器比稳态模式的固体激光器可以工作在更高的泵浦功率水平上。     

Cu-Ni-Al尖晶石催化甲醇重整制氢:Al含量的影响

采用固相球磨法制备了Al含量不等的Cu-Ni-Al三元尖晶石固溶体催化剂，通过BET、XRD、H₂-TPR、XPS表征和催化性能评价，研究了Al含量对Cu-Ni-Al尖晶石的物化性质和甲醇制氢缓释催化性能的影响。结果表明，恒定Cu：Ni（molar ratio）=0.95：0.05，增加Al含量时（Al=2、3、4），所得催化剂的比表面积和孔体积都明显增大，且尖晶石晶胞常数和晶粒尺寸均减小，催化剂也变得难以还原。进一步研究发现，随着Al含量增加，尖晶石Ni²⁺含量略微增加，但尖晶石Cu²⁺含量大幅降低，因此，尖晶石结构中Cu²⁺和Ni²⁺的总量降低，表明Ni²⁺的存在抑制了Cu²⁺进入尖晶石结构。表面分析结果证实，Al含量增加导致催化剂表面由富Cu转变为富Al，表层尖晶石Cu²⁺含量降低，但仍高于体相含量。评价结果显示，随着Al含量增加，反应初始活性增大，CO选择性降低，但Al过量太多时催化稳定性降低，综合来说，Al=3的催化剂表现出较好的催化性能。结果表明，对于Cu-Ni-Al尖晶石缓释催化剂，存在最佳Al含量，对催化稳定性起到关键作用。     

基于模糊相似比较的模具报价方法的研究

为克服模具报价工作对报价人员经验的依赖性,简化报价操作,在分析了报价系统的要求和传统的模具报价进程的基础上,提出了利用模糊数学来提取模具报价领域中专家的经验,模拟专家行为,根据预测技术理论,得出模具价格的模糊相似比较法构想.在此基础上,推导其公式.以冲裁模为研究对象,阐述了工件特征集合构成、模糊相似关系和权值、贴近度计算等关键问题.从理论上为模具报价这一实际问题的解决提供了基本原则和方法.     

非奇异H-矩阵的实用新判定

本文给出了几个关于非奇异H-矩阵新的实用性判定条件,改进了近期的相关结果,并用数值例子说明了文中结果判定范围的更广泛性.     

Study on two-cell stimulated Brillouin scattering system with mixture medium

In this paper,a method of choosing mixture medium in two-cell stimulated Brillouinscattering(SBS)system to improve the system performance is proposed.The Brillouin frequency shift(BFS)of mixture medium varies with the mixing ratio andthus the difference of the BFS between the two cells can be eliminated.The two-cellSBS system with acetone(C3H6O)in its generator cell and mixture liquid ofCCl4/C2Cl4 in its amplifier cell is investigated.The C3H6O has a high optical breakdown threshold and the mixture liquid of CCl4/C2Cl4 has a small absorption coeffi-cient and the same BFS as that of C3H6O when the volume fraction of CCl4 is 4%.Compared with two-cell SBS system with the same liquid(C2Cl4)or different liquid(C3H6O and C2Cl4)in generator and amplifier cell,the SBS system with mixture liq-uid(CCl4/C2Cl4)in amplifier cell and C3H6O in generator cell improves thepower-load,energy reflectivity(ER),phase conjugation(PC)fidelity and ER stabil-ity.     

采用激光诱导击穿光谱技术探测等离子体温度

阐述了激光诱导击穿技术的基本原理，研究了激光诱导击穿光谱技术在探测等离子体温度方面的应用，并进行了实验研究。在等离子体达到局部热平衡时，通过探测Cu的等离子体特征谱线相对强度的方法，达到用激光诱导击穿光谱技术探测等离子体温度的目的。实验结果表明，该方法方便、快捷，具有一定的实际应用价值。     

Simulation of general three-body interactions in a nuclear magnetic resonance ensemble quantum computer

Three-body interaction plays an important role in many-body physics, and quantum computer is efficient in simulating many-body interactions. We have experimentally demonstrated the general three-body interactions in a three-qubit nuclear magnetic resonance ensemble quantum computer. Using a nuclear magnetic resonance computer we implemented general forms of three-body interactions including σ _x ¹ σ _z ² σ _x ³ and σ _x ¹ σ _z ² σ _y ³ The results show good agreement between theory and experiment. We have also given a concise and practical formula for a general n-body interaction in terms of one-and two-body interactions. Supported by the National Natural Science Foundation of China (Grant Nos. 10374010 and 10325521) and the National Basic Research Program of China (Grant No. 2006CB921106)