干涉光谱仪动镜倾斜误差容限分析

本文从调制度和相位误差角度,系统分析了双光束干涉光谱仪中,当光束孔径为圆形和矩形时,动镜运动过程中发生倾斜的影响,讨论了动镜倾斜容限以及减小动镜倾斜误差的方法.     

光谱估计方法FAT的强度修正及品质因子

对作者早先提出的光谱估算方法ＦＡＴ作进一步探讨，提出利用退卷积技术实现光谱线型优化从而修正估计谱相对强度的方法，同时还提出了反映线型优化度及估计谱可靠性的品质因子的概念。     

Study on the interactions between anti-tumor metal complexes and mononucleotides using trans-[en_2Os(η~2-H_2)(CF_3SO_3)](CF_3SO_3) as a ~1H NMR probe in a competitive mode

Trans-[en_2Os(η~2-H_2)]2 , the structure of which is shown in Scheme l, as described in an earlier paper[l] shows promise of being a useful and versatile probe for research on biomolecules. It has been shown to bind to a variety of biomolecules such as n…     

傅里叶变换光谱仪中的主要技术环节

本文总结了在研制傅里叶交换光谱仪(FTS)或成象傅里叶变换光谱仪(IFTS)时应当考虑的主要技术环节,包括仪器函数、光谱分辨率、扩展光源、动镜运动误差、噪音等效功率、信噪比等,并给出相应计算公式.     

Lipophilicity measurement of drugs by reversed phase HPLC over Wide pH range using an alkaline-resistant silica-based stationary phase, XBridge Shield RP(18)

We propose a reversed phase HPLC (RP-HPLC) with an alkaline-resistant silica-based stationary phase, XBridge Shield RP(18), for the determination of the lipophilicity of drugs with diverse chemical nature ranging from acidic to basic. A set of 40 model compounds with well-defined solvatochromic parameters was selected to allow a broad distribution of structural properties. The chromatographic results showed that the lipophilicity index log k(w) obtained with XBridge Shield RP(18) was well correlated with experimental log P(oct) values (r(2)=0.96). Linear solvation free-energy relationship (LSER) analyses revealed that the retention mechanism of the stationary phase and 1-octanol/water partitioning were controlled by almost the same balance of intermolecular forces (hydrophobicity as expressed by the van der Waals volume V(w), H-bond acceptor basicity beta, and dipolarity/polarizability pi*). The results showed that XBridge Shield RP(18) phase overcomes the shortcomings of the silica-based stationary phases, the application of which to lipophilicity measurements had been limited to neutral and acidic compounds.     

离子色谱-紫外检测法测定饲料中的胍基乙酸

通过对色谱柱、流动相洗脱、样品前处理等条件进行优化,建立了一种检测饲料中胍基乙酸含量的离子色谱法。在甲磺酸线性梯度洗脱条件下,样品经Dionex IonPacTMCS16阳离子交换柱分离,用紫外检测器于200 nm波长处进行检测。在0.5~200 mg/L范围内,中胍基乙酸色谱峰面积与质量浓度呈良好的线性关系(相关系数r2=0.999 9)。配合饲料和浓缩饲料中胍基乙酸的检出限为4.5 mg/kg、定量限为15 mg/kg,复合预混合饲料中胍基乙酸的检出限为9.0 mg/kg、定量限为30 mg/kg。该方法对添加量在15 mg/kg~60 g/kg范围内的禽用配合饲料、猪用配合饲料、浓缩饲料、复合预混合饲料中胍基乙酸的回收率均大于94%。该方法性能指标可满足饲料中胍基乙酸含量的检测需求。     

连续函数的概念和性质剖析及其拓展教学研究

比较深入的剖析了连续函数的概念,对连续函数的三种常见定义方式进行了分析,以连续性的判断为例,分析了数学思维的特点,介绍了一个一般文献中不常见的重要结论,讨论了连续函数概念在理论、应用和数学概念进一步发展的拓展.     

In-column “click” preparation of hydrophobic organic monolithic stationary phases for protein separation

Two types of macroporous organic polymer monoliths based on glycidyl methacrylate (GMA), 4-vinylbenzyl chloride (VBC) and divinylbenzene (DVB) were prepared inside stainless-steel tubes. Azide functionalities were firstly introduced on the surfaces of poly(GMA-co-DVB) and poly(VBC-co-DVB) monoliths to provide reactive sites for click chemistry. With the application of copper(I)-catalyzed (3 + 2) azide-alkyne cycloaddition, an in-column click-modification approach for covalent attachment of long alkyl chains onto polymer monoliths was developed. The column morphology and surface chemistry of the fabricated monolithic columns were characterized by the scanning electron microscopy, mercury intrusion porosimeter, Fourier transform infrared spectroscopy, and elemental analyses, respectively. The chromatographic performances of the “clicked” stationary phases were demonstrated with the high separation efficiency for a variety of proteins within 4 min.     

干涉光谱数据处理技术研究进展

干涉光谱成像技术是一类同时具有成像、光谱测量功能的新型信息获取技术,由于干涉光谱成像仪获取的数据是目标的干涉数据,是一种中间数据,不能为用户直接所用,必须通过数据处理技术进行处理才能得到高质量的光谱数据,最终为用户所用.文章将干涉光谱数据处理技术分为通用型和专用型两大类,首先介绍了通用型干涉光谱数据处理技术的发展历程,然后针对干涉光谱成像技术的分类,介绍了不同类型干涉光谱数据的提取方式,对近些年来国内外专用型干涉光谱数据处理技术的发展进行了分析介绍.最后,对干涉光谱数据处理技术的发展趋势进行了展望.     

基于光谱分类的端元提取算法研究

目前成熟的端元提取算法是基于单形体几何学的像元纯度指数(PPO)算法,N-FINDR,VCA等算法.这些算法从图像所有像元中提取纯光谱,具有提取速度慢、精度不高的缺点;部分算法需要进行光谱降维,不利于小目标信息的提取.该文提出先利用基于空间特征的光谱分类算法进行分类,将格个图像划分成空间相邻、光谱相似的若干类,每一类的...