Novel Cross‐Linked Conducting Polythiophene with Yellow‐Green‐Light‐Emitting Properties and Good Thermal Stability

A novel conjugated polythiophene derivative with polymethacrylate attaching to the polymer backbone via an alkyl spacer was successfully synthesized. A methacrylate‐substituted thiophene monomer, 3‐(hexyl methacrylate)thiophene was prepared and polymerized by free radical polymerization, followed by an electrochemical polymerization. The resulting polymer as a yellow‐green‐light emitter, has potential applications in photoelectronics area.     

Matlab在二元共聚物组成曲线绘制中的应用

通过Matlab GUI工具开发出一款专供反复使用且操作简单的绘制共聚物组成曲线的图形用户程序.其开发过程包括图形用户界面的构思、控件的绘制与调整、图形对象属性的设置、M文件的编写和程序调试与运行.该图形用户程序可实现绘图、参数显示、坐标捕捉和曲线风格设置等功能.它的使用在高分子化学教学中收到了良好的效果,通过随机输入...     

A glucose biosensor based on chitosan-Prussian blue-multiwall carbon nanotubes-hollow PtCo nanochains formed by one-step electrodeposition

In this paper, a simple one-step electrodeposition method is described to fabricate chitosan-Prussian blue-multiwall carbon nanotubes-hollow PtCo nanochains (CS-PB-MWNTs-H-PtCo) film onto the gold electrode surface, then glucose oxidase (GOD) and Nafion were modified onto the film subsequently to fabricate a glucose biosensor. The morphologies and electrochemistry of the composite were investigated by using Fourier transform infrared (FTIR) spectrometry, scanning electron microscopy (SEM) and electrochemical techniques including cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), respectively. The performances of the biosensor have been investigated by chronoamperometry method under the optimized conditions. This biosensor showed a linear response to glucose range from 1.5 μM to 1.12 mM with a detection limit of 0.47 μM (S/N=3), a high sensitivity of 23.4 μA mM(-1) cm(-2), and a fast response time. The apparent Michaelis-Menten constant (K(M)(app)) was 1.89 mM. In addition, the biosensor also exhibited strong anti-interference ability, excellent stability and good reproducibility.     

N-（5-氯-2-羟基苄基）氨基酸衍生物及其金属配合物的合成、表征及抑菌活性

以N-（5-氯-2-羟基苄基）氨基酸及其酯为配体,在室温下以水和甲醇为溶剂,采用分步法,以1∶1的摩尔比将配体与金属离子在弱碱性条件下混合,合成了20种未见报道的N-(5-氯-2-羟基苄基)氨基酸类金属配合物。 用核磁、红外和紫外光谱技术对其结构进行了表征。 证明在配合物中配体N-(5-氯-2-羟基苄基)氨基酸的羟基、胺基和羧基均参与了配位。 抑菌测试表明,N-(5-氯-2-羟基苄基)氨基酸类金属配合物的抑菌活性普遍高于其配体,尤其对白色念珠菌的抑菌效果更为明显,均高达100%。 对N-（5-氯-2-羟基苄基）席夫碱氨基酸酯的合成方法进行了优化,得到了较佳的合成工艺条件。     

Catalytic combustion of soot particulates over La_(2-x)K_xNiMnO_6 catalysts

Nanosized La2-xKxNiMnO6 catalysts with ABO3 type perovskite-like structure were prepared by auto-combustion method using citric acid as a ligand to control particle size and morphology.The structures and properties of these perovskite-like oxides were investigated by X-ray powder diffraction(XRD)and temperature-programmed reduction(TPR).The catalytic activities for soot combustion were evaluated by temperature- programmed oxidation(TPO)with pure O2 and O2/NOx as oxidant,respectively.In the La2-xKxNiMnO6 catalysts,the partial substitution of K at A-site leads to an increase of the concentrations of high valence cation and oxygen vacancy,which enhance the catalytic activity for soot combustion.The optimal substitution amount of K was equal to x=0.4 among these samples.Tp(peak temperature)in O2-TPO profile was 420-C and Tp in O2/NOx-TPO profile was 370-C over La1.6K0.4NiMnO6 catalyst for soot particulates combustion under loose contact conditions between catalyst and soot.     

高选择性的Hg2＋识别体的合成及性能

设计合成出一种新型的对Hg2＋具有高选择性的识别体化合物1-羟基-2-（α-偶氮吡啶）-8-氨基-3,6-萘-二磺酸钠盐（HAANDS）,并利用紫外-可见吸收光谱对它与Hg2＋的相互作用进行了研究。结果表明：在中性100%水溶液中,HAANDS识别体仅仅对Hg2＋在长波区有新峰出现,而且存在很好的线性关系。     

一类满足FSAL技术的RKNd方法

陈丙振和游雄给出了内级阶比传统 RK 方法高一阶的 RKNd 方法.FSAL技术是一种常用的节省函数计算量的手段. 其主要思想是,方法的更新与内级的最后一步相同. 本文正是给出满足FSAL技术的RKNd 方法. 数值试验表明, 本文的 RKNdF 方法比RKNd 方法在计算效率上具有一定的优越性.     

基于形态学与遗传粒子滤波器的红外小目标检测与跟踪算法

针对复杂背景下红外小目标的检测与跟踪,提出了一种融合了top-hat算法、遗传算法以及粒子滤波器的新方法.该方法首先采用提取副帧的方法去除目标周围部分的背景和噪音,有效地减少了参与运算的像素数目;其次,将具有不同边缘特性的多个结构体应用于top-hat检测算法中,提高了副帧中预目标的有效性;接着,利用目标时空运动的相关性,结合阈值判断来去除虚假目标,增强了目标检测的可靠性;最后,将遗传算法引入粒子滤波算法,较好地改善了粒子的多样性,在保障跟踪实时性的同时,提高了粒子滤波的准确度.实验结果表明,该算法在检测准确度、跟踪准确度和鲁棒性都具有一定的优越性.     

Electrosyntheses and Characterization of Poly-N-(9-Fluorenylmethoxycarbonyl)-L-isoleucine (PFI) with Chirality

Poly-(N-(9-fluorenylmethoxycarbonyl)-L-isoleucine) (PFI) films with chirality were synthesized electrochemically by direct anodic oxidation of N-(9-fluorenylmethoxy- carbonyl)-L-isoleucine (FI) in a medium strong Lewis acid, boron trifluoride diethyl etherate (BFEE). The oxidation potential of FI in BFEE was only 0.6 V vs. Pt, which was much lower than that determined in acetonitrile + 0.1 mol L^?1 tetrabutylammonium tetrafluoroborate (TBATFB) (1.0 V vs. Pt). Results of FT-IR, UV–visible spectra and ¹H NMR spectra indicated that FI was polymerized successfully and the polymerization positions were C2 and C7. Results of electrochemical measurements showed PFI had good redox activity and stability. SEM provided the surface morphology of the PFI film. Result of thermogravimetric analyses (TG) indicated PFI films obtained from BFEE had good thermostability. As-formed PFI films can be dissolved in ethanol, N,N-Dimethylformamide(DMF), etc.     

基于DEA模型的中国家电上市公司效率实证分析

基于规模报酬可变的DEA模型和Malmquist指数方法,利用中国22家家电上市公司2006-2011年间的截面数据和面板数据,从静态视角和动态视角双维度考察了这一时期中国家电上市公司效率状况.研究发现,2006-2011年期间中国家电上市公司技术效率状况不佳,平均值为0.87,技术效率经历了下降后缓慢上升的趋势;中国家电上市公司动态效率较低,平均增长率为2.3%,且动态效率具有明显的波动性,缺乏持续的增长趋势,技术进步是中国家电上市公司动态效率增长主要动力,技术效率对其增长贡献较小.