基于径向基函数的无网格方法

改进的基于径向基函数的强形式的无单元法（improved radial-basis-function strong-form meshless method,简称IRBFS）是真正意义上的无网格方法,介绍基本原理,求解弹性平面问题,验证了径向基函数的自由参数的最佳取值公式和稀疏化规律的适用性．     

辉光放电质谱法测定高纯材料中痕量硫杂质

准确测定并控制材料中杂质元素含量是发挥高纯材料性能不可或缺的环节。辉光放电质谱法(GDMS)是准确、快速、高灵敏分析高纯材料中痕量及超痕量硫的理想方法。对GDMS分析高纯铜和镍基高温合金中痕量硫的质谱干扰进行了讨论,优化了放电电流和放电电压,采用多种标准物质对硫的相对灵敏度因子(RSF)进行了校准和验证,并与二次离子质谱法(SIMS)进行分析结果比对,验证了GDMS定量分析结果的准确性和可靠性。     

Crystal Engineering of Acentric Diamondoid Metal–Organic Coordination Networks

Acentric three‐dimensional coordination polymers bis(isonicotinato)zinc ( 1 ) and bis(4‐pyridylacrylato)cadmium⋅H₂O ( 2 ) were synthesized under hydro(solvo)thermal conditions; they exhibit a threefold (see picture) and fivefold diamondoid structure, respectively. Both 1 and 2 are active for second harmonic generation and exhibit remarkable thermal stability.     

Phosphate Coordination to Metal-Organic Layer Secondary Building Units Prolongs Drug Retention for Synergistic Chemoradiotherapy

Chemoradiotherapy combines radiotherapy with concurrent chemotherapy to potentiate antitumor activity but exacerbates toxicities and causes debilitating side effects in cancer patients. Herein, we report the use of a nanoscale metal-organic layer (MOL) as a 2D nanoradiosensitizer and a reservoir for the slow release of chemotherapeutics to amplify the antitumor effects of radiotherapy. Coordination of phosphate-containing drugs to MOL secondary building units prolongs their intratumoral retention, allowing for continuous release of gemcitabine monophosphate (GMP) for effective localized chemotherapy. In the meantime, the MOL sensitizes cancer cells to X-ray irradiation and provides potent radiotherapeutic effects. GMP-loaded MOL (GMP/MOL) enhances cytotoxicity by 2-fold and improves radiotherapeutic effects over free GMP in vitro. In a colon cancer model, GMP/MOL retains GMP in tumors for more than four days and, when combined with low-dose radiotherapy, inhibits tumor growth by 98 %. The synergistic chemoradiotherapy enabled by GMP/MOL shows a cure rate of 50 %, improves survival, and ameliorates cancer-proliferation histological biomarkers.     

三点起爆控制参数对尾翼爆炸成型弹丸成型的影响

针对三点起爆控制参数（起爆直径、起爆同步误差）对尾翼爆炸成型弹丸（explosively formed projectile,EFP）成型的影响问题,理论分析了三点起爆条件下爆轰波的马赫碰撞,计算获得了不同起爆直径下马赫波的相关参数,利用LS-DYNA有限元软件通过数值模拟研究了不同起爆直径下三点起爆同步误差对EFP尾翼成型及飞行速度的影响规律。结果表明,起爆直径越大,马赫波在药型罩上的作用面积越小,马赫超压越大,形成的EFP长径比和速度越大;起爆直径为30、40、50 mm三点起爆成型装药形成较佳尾翼EFP应满足的最大起爆同步误差分别为50、100、150 ns;此外,尽量使中间起爆点起爆同步误差约为最大同步误差的一半,有利于降低尾翼EFP的侧向分速度,提高飞行稳定性。     

Ag–N dual-accept doping for the fabrication of p-type ZnO

P-type ZnO was realized by dual-doping with nitrogen and silver via electrostatic-enhanced ultrasonic spray pyrolysis. The structural, electrical, and optical properties were explored by XRD, Hall-effect, and optical transmission spectra. The resistivity of ZnO:(N,Ag) film was found to be 56 Ω cm⁻¹ with the high mobility of 76.1 cm²/V s. Compared with ZnO:Ag film, ZnO:(N,Ag) film exhibited a higher and more stable optical transmittance.     

Synthesis and microstructure analysis of composite Nd:YAG/YAG transparent ceramics

Transparent Nd：YAG/YAG composite ceramics are synthesized by solid-state reaction method using high- purity Y203, A1203, and Nd203 powders as raw materials. The mixed powder compacts are sintered at 1780 ℃ for 10 h under vacuum and annealed at 1450 ~C for 20 h in air. The Nd：YAG/YAG ceramics exhibit a pore free structure with an average grain size of about 30 μm. The microstructure of the Nd：YAG/YAG composite transparent ceramics is studied and there is no interface between Nd：YAG and YAG ceramics. The Nd ion distribution in one grain is also studied, which shows that there is no segregation of Nd ions as in Nd：YAG crystals.     

LaB6场发射阵列牺牲层制备工艺

 分析了传统牺牲层材料铝在制备LaB6场发射阵列时存在的问题,利用溅射及热蒸发工艺依次制备铝膜和氧化锌膜,制备出了一种新型的牺牲层——ZnO-Al复合牺牲层,并对所制备的阵列进行了测试。实验结果表明：ZnO-Al复合牺牲层能够有效地解决电化学腐蚀的问题,所制备出的LaB₆场发射阵列尖锥保持了完好的形貌,其发射特性也达到了最初制备场发射阵列的要求,说明ZnO-Al复合牺牲层是作为LaB₆场发射阵列牺牲层的理想材料。     

NO分子和氧原子的高分辨离子谱实验研究

共振增强多光子电离及飞行时间质谱技术是一种具有高分辨率、高灵敏度的光谱研究技术。利用上述技术研究了由激光光解NO2产物-NO与原子O的离子谱,获得了振转态高度分辨的NO(X^2П,v″,J″)γ(0,0)γ(0,1)γ(1,1)带的离子谱以及自旋-轨道精细能级分辨的氧原子O(2P^3PJ^″=2,1,0)离子谱。氧原子O(2P^3PJ^″=2→3P^3PJ^″、2P^3PJ^″=1→3P^3PJ′、2P^3PJ″=0→3P^3PJ′)的离子信号位于紫外电离探测激光的波长分别为225．65nm,226．04nm,226．23nm。实验表明,共振增强多光子电离加飞行时间技术研究原子、分子光谱其灵敏度与分辨率远高于常用的激光感生荧光方法。所得到的NO分子与氧原子的离子谱及它们的离子信号对NO2分子光解及NO分子与氧原子的电离动力学研究提供了有益的实验信息。     

采用CCD技术的微型光机电系统光开关测试方法

在研制基于微型光机电系统技术的光电器件过程中,需要精确测定器件在给定驱动条件下的运动情况。在对制作完成的光开关进行性能测试时,由于微型光机电系统光开关的几何尺寸的限制,如果要准确测定光开关微反射镜的运动位移。将会有一定的困难。提出了一种采用线阵CCD技术的光学测量方法,实现了对光开关悬臂梁在驱动电压作用下的旋转角度的精确测量。通过理论推导得到了悬臂梁扭转角度与可测量物理量的关系．通过求解方程得到了各个物理量的数值选择对于测量结果的影响,并且给定了测量时各个物理量的参考值。通过实验测量,误差小于10％,表明这是一种具有实际意义的测量方案。