首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   434篇
  免费   82篇
  国内免费   99篇
化学   279篇
晶体学   13篇
力学   32篇
综合类   3篇
数学   128篇
物理学   160篇
  2023年   5篇
  2022年   7篇
  2021年   9篇
  2020年   16篇
  2019年   16篇
  2018年   12篇
  2017年   10篇
  2016年   19篇
  2015年   20篇
  2014年   33篇
  2013年   33篇
  2012年   36篇
  2011年   32篇
  2010年   32篇
  2009年   26篇
  2008年   41篇
  2007年   24篇
  2006年   19篇
  2005年   23篇
  2004年   20篇
  2003年   20篇
  2002年   38篇
  2001年   25篇
  2000年   13篇
  1999年   12篇
  1998年   7篇
  1997年   6篇
  1996年   6篇
  1995年   10篇
  1994年   10篇
  1993年   14篇
  1992年   6篇
  1991年   4篇
  1990年   2篇
  1989年   2篇
  1988年   3篇
  1987年   2篇
  1986年   1篇
  1957年   1篇
排序方式: 共有615条查询结果,搜索用时 812 毫秒
61.
本文针对V循环、W循环和多重网格法中最优光滑次数及循环体个数难以确定的缺点,以Helmholtz方程为例给出自适应的多重网格算法和自适应的完全多重网格算法。  相似文献   
62.
Single-mode backward wave is shown to be guided in a planar dielectric waveguide with a strong chiral core. The significant difference of such a waveguide from the traditional one is the guidance of single-mode backward wave, without using negative permittivity and/or negative permeability. In the design, we generalize the idea of total internal reflection to the chiral medium and make a numerical analysis on the reflection with oblique incidence. We deduce rigorously a general solution of incident wave on the boundary of two arbitrary chiral magneto-electric media. We observe that the impedance matching can eliminate the coupling between two eigenwaves in chiral media. With strong chiral core and the matched impedance with cladding, one eigenwave becomes a backward wave and can be guided without transferring to the other eigenwave. If a single-mode propagation condition is satisfied, we will get single-mode backward guided wave. A special interface has been designed to prevent the forward wave entering the waveguide from the source.  相似文献   
63.
采用金属有机分解法在p型Si衬底上制备了SrTiO3(STO)薄膜.研究了STO薄膜金属 绝缘体 半导体(MIS)结构的介电和界面特性.结果表明,STO薄膜显示出优异的介电性能,在10kHz处的介电常数约为105,损耗低于001,这来源于多晶结构和良好的结晶性;MIS结构中的固定电荷密度Nf和界面态密度Dit分别约为15×1012cm-2和(14—35)×1012cm-2eV-1,这主要与Si/STO界面处形成的低介电常数界面层有关. 关键词: SrTiO3薄膜 MIS结构 介电性能 Si/STO界面  相似文献   
64.
三元乙丙橡胶的13C-NMR定量分析   总被引:1,自引:0,他引:1       下载免费PDF全文
用13C核磁共振波谱法对三元乙丙橡胶进行了研究,通过图谱中各个峰的积分值,并用特定的计算公式测定了三元乙丙橡胶中乙烯及第三单体乙叉降冰片烯的含量,为红外光谱批量的定量分析建立了基准化的标定。  相似文献   
65.
本文研究有限元Ritz-Volterra投影的超收敛性质.利用一种新型的Green函数,证明了该投影具有与有限元Ritz投影相平行的函数和导数逼近的超收敛性质.这些结果被应用于抛物型积分微分方程和Sobolev方程的半离散有限元近似.  相似文献   
66.
Mo2O2S2(HGly)(Gly)2 1 and K6[Mo2O2S2(nta)2][Mo2O2S2(ntaH)2]·4H2O 2 were synthesized by the reactions of (NH4)2MoS4 and amino acids L (L = glycine, nitrilotriacetic acid) in ethanol–water medium at ambient temperature. The two complexes were characterized by elemental analysis, infrared spectra, UV–visible spectra, TG–DTA and XPS. X‐ray crystallographic structural analyses revealed that compound 1 is a binuclear Mo? S? glycinate complex, a glycinate ligand is coordinated to each molybdenum atom through its amine nitrogen and carboxylato oxygen, respectively, and the third glycinate acts as a bridge through its two carboxylato oxygens linking the two molybdenum atoms. Compound 2 is also a binuclear Mo? S complex with two nitrilotriacetate ligands, each of which is coordinated to a molybdenum atom via its two β‐carboxylato oxygens and a nitrogen atom. Simultaneously, each molybdenum atom in 1 and 2 is chelated to a terminal oxygen and two bridging sulfurs to complete the octahedral configuration. Their catalytic activities in the reduction from C2H2 to C2H4 as well as other binuclear Mo? S? polycarboxylate complexes, a [Fe4S4] single cubane and a chainlike Mo? Fe? S compound were investigated and it was found that 1 exhibited relatively good catalytic activity. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
67.
Stokes型积分——微分方程的Galerkin近似   总被引:2,自引:0,他引:2  
本文讨论一类具有Stokes方程结构的积分一微分方程的Galerkin近似,论证了近似解的存在唯一性,并分别导出速度和压力近似解的最优阶L_2模误差估计。  相似文献   
68.
69.
AdsorptionofBenzeneonthePotassiumExchangedHbetaZeolitesSHENJian-ping;MAJun;SUNTieandJIANGDa-zhen(DepartmentofChemistry,JilinU...  相似文献   
70.
Six tetraphenylporphyrins (TRPPH2) with different horizontal substituents R (R = H, CH3, OH, F, Cl, Br) were synthesized, and the organic light‐emitting diode (OLED) devices with a general configuration of ITO/TPD/Alq3:2%TRPPH2/Alq3/Al were prepared. The substituted TRPPH2 was used as the host dopant, 4,4‐bis‐(m‐tolyphenylamino)biphenyl (TPD) was used as a hole‐transporting material, and aluminum tris(8‐quinolinolato) (Alq3) was used as an electron‐transporting material. The electroluminescent (EL) properties of these devices were studied to understand the light emitting properties of the substituted TRPPH2. Previous studies have found that the color emitted by the devices was dependent on the TRPPH2 dye concentration. The electronic effect of the horizontal substituents R of TRPPH2 influenced the turn‐on voltage, brightness, and power efficiency of the devices. Also, the electroluminescence performance of the porphyrin‐doped OLED devices depended on the effectual overlaps between the emission of electron‐transporting material and the absorption of the dopants. This means that it is possible to evaluate the electroluminescence performance of the porphyrin‐doped OLED devices based on the emission of electron‐transporting material and the absorption of the dopants. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号