骨小梁中超声背散射信号的频率分析及其微结构的估计

骨质疏松症是一种骨强度下降的全身性骨骼疾病,骨强度的下降是骨量减少和骨微结构退化的共同结果。相比于传统的超声透射方法,超声背散射法可提供更多的骨微结构信息,而对于松质骨结构的建模能有助于结构信息的获取。本文将骨小梁简化为单圆柱模型(圆柱状的单根骨小梁浸于骨髓中),并基于此模型对超声背散射与频率的关系进行分析。用铝线代替骨小梁做仿体实验,通过实验与理论结果的比较来验证单圆柱模型的可行性。     

超声轴向传播技术评价长骨的研究

用超声轴向传播技术评价长骨状况已成为近年来的一个研究热点。本文首先介绍了第一到达波(FAS)法、超声Lamb波及柱面导波法在评价长骨皮质骨状况方面的研究进展,最后分析和讨论了当前研究中存在的问题及应该研究的方向。     

Joint spectrogram segmentation and ridge-extraction method for separating multimodal guided waves in long bones

Ultrasonic guided waves (GWs) can be used to evaluate long bones effectively because of the ability to provide the information of the whole bone. In this study, a joint spectrogram segmentation and ridge-extraction (JSSRE) method was proposed to separate multiple modes in long bones. First, the Gabor time-frequency transform was applied to obtain the spectrogram of multimodal signals. Then, a multi-class image segmentation algorithm was used to find the corresponding region of each mode in the spectrogram, including an improved watershed transform and a region growing procedure. Finally, the ridges were extracted and the time domain signals representing individual modes were reconstructed from these ridges in each region. The validations of this method were discussed by simulated multimodal signals with different signal-to-noise ratios (SNR). The correlation coefficients between the original signals without noise and the reconstructed signals were calculated to analyze the results quantitatively. The results showed that the extracted ridges were in good agreement with generated theoretical dispersion curves, and the reconstructed signals were highly related to the original signals, even under the SNR=3 dB situation.     

Cyanobiphenyl-based liquid crystal dimers and the twist-bend nematic phase

ABSTRACT

The synthesis and characterisation of several members of the 1,ω-bis(4-cyanobiphenyl-4′-yl) alkane (CBnCB) and the 1-(4-cyanobiphenyl-4′-yloxy)-ω-(4-cyanobiphenyl-4′-yl) alkane (CBnOCB) homologous series are reported. The new odd members described CB5CB, CB13CB, CB4OCB, CB8OCB and CB10OCB all exhibit twist-bend nematic and nematic phases. The members of these series already reported in literature, CB7CB, CB9CB, CB11CB and CB6OCB, were also prepared in order to allow for a direct comparison of their transitional properties. The properties of these dimers are also compared to those of the corresponding members of the 1,ω-bis(4-cyanobiphenyl-4,-yloxy) alkanes (CBOnOCB). For any given total spacer length, for odd members of these series, the nematic–isotropic transition temperatures and associated entropy changes are greatest for the CBOnOCB dimer and lowest for the CBnCB dimer. These trends are understood in terms of molecular shape. For short spacer lengths, the twist-bend nematic–nematic transition temperature (T_NTBN) is higher for the CBnOCB series than for the CBnCB series but this is reversed as the spacer length increases. Of the CBOnOCB dimers, a virtual value of T_NTBN was estimated for CBO3OCB and T_NTBN was measured for CBO5OCB. These values are considerably lower than those observed for the corresponding members of the CBnCB or CBnOCB series. The dependence of T_NTBN on molecular structure is discussed not only in terms of the molecular curvature but also in the ability of the molecules to pack efficiently. As the temperature range of the preceding nematic phase increases, so the twist-bend nematic–nematic transition entropy change decreases and the transition approaches second order for the longer spacers. For comparative purposes, the transitional behaviour of the even-membered dimers CB6CB, CB5OCB and CBO4OCB is reported and differences accounted for in terms of molecular shape.     

Structural characteristics of different types of nanoparticles synthesised in mesomorphic metal alkanoates

The class of thermotropic ionic liquid crystals (LCs) of the metal alkanoates possesses a number of unique properties, such as intrinsic ionic conductivity, high dissolving ability and ability to form time-stable mesomorphic glasses. These ionic LCs can be used as nanoreactors for the synthesis and stabilisation of different types of nanoparticles (NPs). Thus, some semiconductors, metals and core/shell NPs were chemically synthesised in the thermotropic ionic liquid crystalline phase (smectic A) of the cadmium octanoate (CdC₈) and of the cobalt octanoate (CoC₈). By applying the scanning electron microscopy, the cadmium and cobalt octanoate composites containing CdS, Au, Ag and core/shell Au/CdS NPs have been studied. NPs’ sizes and dispersion distribution of the NPs’ size in the nanocomposites have been obtained.     

基于催化应用调控氧化铈纳米材料的形貌

催化剂的设计、合成和结构调控是获得优异性能的关键.传统的策略主要是尽量减小催化剂颗粒尺寸以增加活性中心的数目,即尺寸效应.近年来,材料科学的快速发展使得在纳米尺度上调变催化剂的尺寸和形貌成为可能,特别是通过形貌调控可暴露更多的高活性晶面,大幅度提高催化性能,即纳米催化中的形貌效应.因此,调节催化剂的尺寸与形貌可以单独或协同优化材料的性能.氧化铈作为催化剂的重要组分与结构、电子促进剂被广泛应用于多相催化剂体系.本文总结了近期氧化铈材料形貌可控合成的进展,包括主要的合成策略和表征方法; 进而分析了氧化铈和金-氧化铈催化材料的形貌效应,指出金-氧化铈之间独特的相互作用与载体形貌密切相关; 阐述了氧化铈纳米材料因暴露晶面的差异而获得不同催化性能的化学机制.     

超声诊断骨质疏松症中松质骨的模型

骨质疏松症(OP)是老龄化社会中影响健康的一个重要问题，超声技术已成为诊断骨质疏松症的一种常用方法。文中综述了近年来用超声诊断骨质疏松症中松质骨模型研究的进展，对棒状模型、流体多孔介质模型(Biot理论)和层状模型(schoenberg理论)进行了分析和讨论，指出了各理论模型存在的缺陷，对下一步的研究工作提出了建议。     

Valence state map of iron oxide thin film obtained from electron spectroscopy imaging series

This paper demonstrates the applicability of electron-spectroscopic imaging (ESI) for valence-state mapping of the iron oxide system. We have previously developed a set of signal-processing methods for an ESI series, to allow mapping of sp(2)/sp(3) ratio, dielectric function and energy bandgap. In this study, these methods are applied to generate a valence-state map of an iron oxide thin film (Fe/alpha-Fe(2)O(3)). Two problems, data undersampling and a convolution effect associated with extraction of the image-spectrum from the core loss image series, were overcome by using cubic-polynomial interpolation and maximum-entropy deconvolution. As a result, the reconstructed image-spectrum obtained from the ESI series images has a quality as good as that of conventional electron energy-loss spectra. The L(3)/L(2) ratio of the reconstructed ESI spectrum is determined to be 3.30+/-0.30 and 5.0+/-0.30 for Fe and alpha-Fe(2)O(3), respectively. Our L(3)/L(2) ratio mapping shows an accurate correspondence across the Cu/Fe/alpha-Fe(2)O(3) region. The effect of delocalization and chromatic aberration on the ESI resolution is discussed and estimated to be about 2 nm for the case of L(3)/L(2) ratio mapping.     

Die volumetrische Bestimmung des Kohlenstoffs in aliphatischen Verbindungen auf nassem Wege

Ohne Zusammenfassung