PICO－TAG反相色谱法测定鸡蛋中氨基酸含量

采用ＰＩＣＯ－ＴＡＧ反相色谱法测定了氨基酸，方法的相对标准偏差为０．７５％，平均回收率为９７．１２％。对鸡蛋样品进行了测定，发现不同产地不同皮色鸡蛋中氨基酸含量无显著差异，样品测定相对标准偏差为１．６７％。结果表明测定方法快速、灵敏、准确、重现性好。     

红外显微化学图像技术在空心微球制备中的应用

在考察聚苯乙烯(PS)与聚乙烯基苄氯(PVBCl)相容性及干涉效应对测量结果影响的基础上,使用红外显微化学图像技术研究表征了PS与PVBCl混合物薄膜和微球的相分离情况,对比分析了不同处理条件下制备的微球半球壳中两种聚合物的相分离红外显微化学图像。研究结果表明建立的研究方法可以用来定性或半定量的分析球壳内PS和PVBCl两聚合物的分相情况,在测试中样品的干涉效应会对测量造成较大的不确定度,在不同温度下获得的聚合物微球样品中,40℃条件下两聚合物的分相情况更为理想。该研究为探索非均相双半球型聚合物微球制备条件以及红外显微化学图像法表征聚合物相分离提供了一种直观可行的表征方法,但受空间分辨率的影响,该方法不适合于6.25μm×6.25μm以下尺寸样品的分析。     

Self-assembly of composite nanotubes and their applications

Combination of the layer-by-layer (LbL) technique with the porous template method has attracted significant interest as a versatile approach that has been used to prepare tubular nanomaterials with tailored properties. The process involves the sequential deposition of different species, such as polymers, nanoparticles, lipids, proteins, dyes and organic or inorganic small molecules into various porous templates, which are subsequently removed to yield free-standing nanotubes. At the same time, this approach permits the formation of composite nanotubes with the engineering features, including size, shape, composition and function. In this review, we summarize the synthesis and properties of various LbL-assembled composite nanotubes based on electrostatic attraction, hydrogen bonding, and covalent bonding. These assembled nanotubes possess potential application in biomedical fields such as bioseparations, biocatalysis, biosensor, and drug delivery.     

熵函数法的数学理论

１．引言考虑复合函数其中ｇ;：Ｒ"－Ｒ,ｉ＝１,２,...;。连续可微．因的ｘ）的不可微性,涉及的ｘ）的优化问题,如极大极小问题Ｉｒｌｍｌｎｏｔｘｊ．ｆｉｊＺＦＲ"通常属不可微优化范畴．文山借助最大嫡原理推导出一类一致逼近一（Ｘ）的可微函数（称之为妨函数）Ｏ。ｉｌｌ--一ｉｆｌｙｌｌＸＤＣＱ．ｌｏｌｌ．ＩＪｊ容易证明ｔｉｍ人一中且对任意ｘＥＲ",ＣＭ＋ＯＯｇｂｃｌ（ｌ＞ｏｆｃ。（ｌ,ＶＣＺ＞ＣＩ＞０,（４ｉｌｌｆｆｉ０＜ｕｌ。（）ｄｉ（］＜．（５基于该性质,文山一【４］通过一次取定较大有限值Ｃ。＞０,将…     

N2+分子离子的B2Σu+、A2Πu和X2Σg+电子态光谱研究

采用光外差-磁旋转-速度调制吸收光谱技术, 在可见光波段范围16800～17573 cm-1, 对N2+的A 2Πu-X 2Σ+g(12,6)、(11,5)、(7,2)带和B 2Σ+u-X 2Σ+g (1,5)带进行了测量和分析,推导了双原子分子振转能级在受到微扰作用时的有效哈密顿量形式,并分析了N2+的A 2Πu-B 2Σ+u之间存在的微扰相互作用,通过与实验数据的拟合得到了精确的电子态微扰常数ξe、ηe .     

N2+分子离子的B2Σu+、A2Πu和X2Σg+电子态光谱研究

采用光外差 磁旋转 速度调制吸收光谱技术 ,在可见光波段范围 16 80 0～ 175 73cm-1,对N2 + 的A2 Πu-X2 Σ+ g(12 ,6 )、(11,5 )、(7,2 )带和B2 Σ+ u -X2 Σ+ g(1,5 )带进行了测量和分析 ,推导了双原子分子振转能级在受到微扰作用时的有效哈密顿量形式 ,并分析了N2 + 的A2 Πu-B2 Σ+ u 之间存在的微扰相互作用 ,通过与实验数据的拟合得到了精确的电子态微扰常数 ξe、ηe.     

辣根过氧化物酶生物传感器检测苯肼的研究

采用酸性溶胶法在碳纳米管(CNT)上负载纳米TiO2颗粒,制备了CNT-TiO2修饰电极,利用TiO2与辣根过氧化物酶(HRP)间的静电吸附及TiO2与羧基的高反应特性,实现了HRP在CNT-TiO2修饰电极表面的固定.实验发现,该生物传感器对邻氨基苯酚过氧化氢溶液的氧化还原有很好的催化作用,利用苯肼对HRP的抑制作用实现了对环境污染物苯肼的检测.该生物传感器寿命长,性能稳定且可以重复使用.     

载气组份对空心玻璃微球炉内成球过程的影响

为实现惯性约束聚变靶用空心玻璃微球的干凝胶法高效制备,从数值模拟和工艺实验两个方面研究了载气组份对干凝胶粒子炉内成球过程及最终空心玻璃微球性能的影响。结果表明:载气组份显著影响粒子/微球与载气之间的热量和质量传递过程,但载气组份对粒子/微球在炉内的下落速度影响很小;提高载气中氦气的体积分数可以显著提高干凝胶粒子在吸热阶段的升温速率,更为迅速有效地完成封装过程,这不仅使得干凝胶粒子发泡成为空心球的比例增大,而且还有利于制备得到大纵横比的空心玻璃微球;但是,在载气中保持适当体积分数的氩气,有利于提高玻璃微球的表面质量和成品率。当载气中氦气的体积分数在50%~80%时,干凝胶粒子的成球率较高,空心玻璃微球的球形度、同心度和表面粗糙度能满足制靶要求。     

Achievement on Unwrapping High Cycle Density of Noisy Phase Maps for Digital Holographic Microscopy

Phase unwrapping has been an important way to construct a 3‐dimensional image of the object in digital holographic microscopy. However, there is still a huge challenge currently on this technique at present, as it is still difficult to perfectly retrieve high wrapping density of phase maps which include different types of noise. This is because many details of high wrapping density of phase maps are buried in noise so that it is difficult to reconstruct them in digital holography. In order to solve this problem, a novel solution called I‐PUROR method is presented in this paper. In comparison to previous techniques, not only can the I‐PUROR algorithm effectively overcome the noise influence, but also reconstruct phase details very well in the phase unwrapping process. The experimental evaluation is fully consistent with theoretical analysis. It proves the validity of this new method.