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61.
以3-甲基-4-氨基-5-乙氧羰基甲硫基-1,2,4-三唑为原料,与取代芳醛合成9种3-甲基-4-(X-取代基苯亚甲基氨基)-5-乙氧羰基甲硫基-1,2,4-三唑席夫碱化合物a~i。 产物结构经1H NMR、IR和MS等技术手段确证。 其中化合物3-甲基-4-(4-羟基苯亚甲基氨基)-5-乙氧羰基甲硫基-1,2,4-三唑h进一步经X射线单晶衍射得到其晶体结构(CCDC:910927):C14H16N4O3S,Mr=320.37,Orthorhombic,P2(1)2(1)2(1)/n,a=0.9220(10) nm,b=1.5823(17) nm,c=2.1667(2) nm,V=3.161(6) nm3,Z=8,F(000)=1344。 化合物对4种植物病原菌的初步生物活性测试结果(EC95值)表明,化合物d、e、f对供试菌种西瓜枯萎病和小麦赤霉病的抑菌活性优于对照原药三唑酮。 相似文献
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Shengqiang Nie Jiazhou Zeng Hui Qin Xiaolu Xu Jia Zeng Chunlin Yang Jun Luo 《先进技术聚合物》2019,30(4):923-931
In this study, we have provided a highly efficient, convenient, and universal protocol for preparing polyvinylidene fluoride (PVDF) membranes with low blood contact activation via in situ cross‐linking copolymerization of 2‐hydroxyethl methacrylate (HEMA) and acrylic acid (AA) in a solution of PVDF. The modified membranes were prepared from PVDF solution by phase inversion technology. The composition and morphology of the modified membranes were confirmed by attenuated total reflectance‐Fourier transform infrared (ATR‐FTIR) spectroscopy, thermogravimetric (TG) analysis, and scanning electron microscopy (SEM). Protein adsorption, clotting time, and contact activation on the modified PVDF membranes were systematically studied, the results indicating that after the incorporation of AA and HEMA, the modified PVDF membranes possessed anticoagulant properties in addition to low contact activation of blood components when in contact with blood. Therefore, fluorinated PVDF membranes with surfaces enriched with carboxyl and hydroxyl groups possessed the potential for use in long‐term blood‐contacting devices. 相似文献
64.
Xiaobing Fan Jianhong Gao Wei Wang Shengqiang Xiao Chun Zhan Xinhui Lu Qichun Zhang 《化学:亚洲杂志》2019,14(10):1814-1822
The ladder‐type nonacyclic arene (bis(thieno[3,2‐b]thieno)cyclopentafluorene (BTTF)) has been designed and synthesized through fusing thienothiophenes with the fluorene core from the synthon of dimethyl 9,9‐dioctyl‐2,7‐bis(thieno[3,2‐b]thiophen‐2‐yl)fluorene‐3,6‐dicarboxylate. With BTTF as the central donor unit, a novel acceptor–donor–acceptor (A‐D‐A) type non‐fullerene small‐molecule acceptor ( BTTFIC ) was prepared with 1,1‐dicyanomethylene‐3‐indanones (IC) as the peripheral acceptor units. The energy level of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of BTTFIC locate at ?5.56 and ?3.95 eV, respectively, presenting a low optical band gap of 1.58 eV. Encouragingly, polymer solar cells based on the blends of BTTFIC with both the representative wide‐ and low‐bandgap polymer donors (PBDB‐T, 1.82 eV. PTB7‐Th, 1.58 eV) offer power conversion efficiencies over 8 % (8.78±0.18 % for PBDB‐T: BTTFIC and 8.18±0.29 % for PTB7‐Th: BTTFIC ). These results highlight the advantage of ladder‐type BTTF on the preparation of nonfullerene acceptors with extended conjugated backbones. 相似文献
65.
Rui CHEN Wei WANG Tongle BU Zhiliang KU Jie ZHONG Yong PENG Shengqiang XIAO Wei YOU Fuzhi HUANG Yibing CHENG Zhengyi FU 《物理化学学报》2019,35(4):401-407
Organic-inorganic hybrid perovskite solar cells (PSCs) have attracted significant attention owing to their high absorption coefficient and ambipolar charge transport properties. With only several years of development, the power conversion efficiency (PCE) has increased from 3.8% to 22.7%. In general, PSCs have two types of structural architecture: mesoporous and planar. The latter possesses higher potential for commercialization due to its simpler structure and fabrication process, especially the inverted planar structure, which possesses negligible hysteresis. In an inverted PSC, the electron transport materials (ETM) are deposited on a perovskite film. Only a few ETMs can be used for inverted PSCs as the perovskite film is easily damaged by the solvent used to dissolve the ETM. Furthermore, the energy levels of the ETM should be well aligned with that of the perovskites. Normally it is difficult to use inorganic ETMs as they require high temperatures for the annealing process to improve the electron conductivity; the perovskite film cannot sustain these high temperatures. To date, the fullerene derivative, [6, 6]-phenyl-C61-butyric acid methyl ester (PCBM), is the most commonly used organic ETM for high efficiency inverted planar PSCs. However, the high manufacturing cost due to its complex synthesis retards the industrialization of the PSCs. Here, we introduce a fullerene pyrrolidine derivative, N-methyl-2-pentyl-[60]fullerene pyrrolidine (NMPFP), synthesized via the Prato reaction of C60 directly with cheap hexanal and sarcosine. Then the NMPFP electron transport layer (ETL) was prepared by a simple solution process. The properties of the resulting NMPFP ETLs were characterized using UV-Vis absorption spectroscopy, cyclic voltammetry measurements, atomic force microscopy, and conductivity test. From the results of the UV-Vis absorption spectroscopy and cyclic voltammetry measurements, the LUMO level of NMPFP ETL was calculated to be 0.2 eV higher than that of the PCBM ETL. This contributes to a higher open-circuit photovoltage. In addition, the NMPFP film presented higher conductivity than the PCBM film. Thus, the photo-generated charge carriers in the perovskite films should be transported more efficiently to the NMPFP electron transport layer (ETL) than to the PCBM ETL. This was confirmed by the results of the steady-state photoluminescence spectroscopy. Finally, the NMPFP as an alternative low-cost ETL was employed in an inverted planar PSC to evaluate the device performance. The device made with the NMPFP ETL yielded an efficiency of 13.83% with negligible hysteresis, which is comparable to the PCBM counterpart devices. Moreover, since stability is another important parameter retarding the commercialization of PSCs, the stability of the PCBM and NMPFP base PSCs were investigated and compared. It was found that the NMPFP devices possessed significantly improved stability due to the higher hydrophobicity of the NMPFP. In conclusion, this research demonstrates that NMPFP is a promising ETL to replace PCBM for the industrialization of cheap, efficient and stable inverted planar PSCs. 相似文献
66.
This paper is devoted to study Frobenius Poisson algebras. We introduce pseudo-unimodular Poisson algebras by generalizing unimodular Poisson algebras, and investigate Batalin-Vilkovisky structures on their cohomology algebras. For any Frobenius Poisson algebra, all Eatalin-Vilkovisky opera tors on its Poisson cochain complex are described explicitly. It is proved that there exists a Batalin-Vilkovisky operator on its cohomology algebra which is induced from a Batalin-Vilkovisky operator on the Poisson cochain complex, if and only if the Poisson st rue ture is pseudo-unimodular. The relation bet ween modular derivations of polynomial Poisson algebras and those of their truncated Poisson algebras is also described in some cases. 相似文献
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1IntroductionRecent1ytheso-calledsinglespeciesm0delwasconsidered,andmanyrcsultshavebeen.bt.in.d[1-7J.In[l],thesinglespeciesmodelwithstage-structtlredinthefOrmofisstudied,whereIi(t)andx.(t)representtheimmatureandmaturepopu-lati0nsdensitiesrespectively;ofisthe0bservedorassumedbirthrateofxi(t)attimet(-T5t5O),andTrepresentsac0nstanttime1engthfortheiITl-maturetobecomematurity.aisthebirthrateofmaturepopulation.7isthedeathrateofimmaturepopulationandfiistheLogisticconstantofthemature.Somesufficien… 相似文献
69.
Shengqiang Tang Lijing Qiao Hualiang Fu 《Journal of Applied Analysis & Computation》2013,3(4):399-403
In this paper, the qualitative analysis methods of a dynamical system are used to investigate the peakon soliton solutions of K(2;-2; 4) equation: ut + a(u2)x + b[u-2(u4)xx]x = 0. The phase portrait bifurcation of the traveling wave system corresponding to the equation is given. The explicit expressions of the peakon soliton solutions are obtained by using the portraits. The graph of the solutions are given with the numerical simulation. This supplements the results obtained in [4]. 相似文献
70.