β-二亚胺配体支持的铝胺化合物的制备及其催化ε-己内酯开环聚合的高效性能

成功合成了由β-二亚胺配体(L)支持的铝胺化合物(L)AlH(NMe2)2(L=HC(C(Me)NAr)2,Ar=2,6-iPr2C6H3)(1)。该化合物采用分步合成法进行制备,以n-BuLi与HNMe2反应生成的锂盐LiNMe2作为前驱体,进一步与(L)AlH2溶液共混通过消除LiH得到目标产物。通过核磁共振谱、元素分析、红外漫反射光谱和X射线单晶衍射确定了铝胺化合物(L)AlH(NMe2)2的组成与结构。该铝胺化合物中,金属Al中心同时形成Al-H和Al-NMe2基团,在催化ε-己内酯的开环聚合的反应中展现出了优异的催化活性。通过高效凝胶渗透色谱测定了所得聚合物的分子量和分子量分布。     

Catalytic transfer hydrogenation of biomass-derived furfural to furfuryl alcohol with formic acid as hydrogen donor over CuCs-MCM catalyst

Catalytic transfer hydroge nation(CTH) of furfural(FF) to furfu ryl alcohol(FFA) has received great intere st in recent years.He rein,Cu-Cs bimetallic supported catalyst,CuCs(2)-MCM,was developed for the CTH of FF to FFA using formic as hydrogen donor.CuCs(2)-MCM achieved a 99.6% FFA yield at an optimized reaction conditions of 170℃,1 h.Cu species in CuCs(2)-MCM had dual functions in catalytically decomposing formic acid to generate hydrogen and hydrogenating FF to FFA.The doping of Cs made the size of Cu particles smaller and improved the dispersion of the Cu active sites.Impo rtantly,the Cs species played a favorable role in enhancing the hydrogenation activity as a promoter by adjusting the surface acidity of Cu species to an appropriate level.Correlation analysis showed that surface acidity is the primary factor to affect the catalytic activity of CuCs(2)-MCM.     

A new hyperbranched star polyether electrolyte with high ionic conductivity

Hyperbranched poly(glycidol) containing hydroxyl groups was firstly synthesized via anionic polymerization and then reacted with 2-bromoisobutyl bromide to form macroinitiator HPG-Br. Finally, a hyperbranched star polymer (HPG-PPEGMA) was successfully prepared by atom transfer radical polymerization (ATRP) of poly(ethylene glycol) methyl ether methacrylate using HPG-Br as macroinitiator. The structures and properties of the obtained polymers were characterized by ¹H NMR, attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The ionic conductivity of the polymer electrolytes composed of HPG-PPEGMA and lithium bis(trifluoromethanesulfonimide) (LiTFSI) was investigated via electrochemical impedance spectroscopy. The results showed that the room temperature ionic conductivity of the prepared hyperbranched star polymer electrolytes had a higher ionic conductivity. When [EO]/[Li] was 20, the ionic conductivity of the hyperbranched star polymer electrolyte was up to 1?×?10^?4 Scm^?1 at 30 °C. The onset decomposition temperature of the hyperbranched star polyether could reach 374 °C, indicating that the hyperbranched star polymer had a good thermal stability. The XRD results showed that the structure of the hyperbranched star polymer was beneficial to improve the ionic conductivity due to possessing a low degree of crystallinity.     

双城记——星系并合和星系对

在重子世界中,星系是宇宙构成的砖块,但是星系在宇宙中的分布却不是随机的。在大尺度上,星系的分布是网状的;在小尺度上,星系往往也会成对存在,比如本地星系群中的银河系和仙女座大星云。星系对最终会发生并合,而这个并合过程是星系增长的主要途径之一。对星系对进行的观测研究能够帮助人们理解星系的相互作用和增长过程。文章重点介绍了现代星系巡天中对星系对进行的观测,特别是中国的重大科学工程郭守敬望远镜在其中所发挥的作用。     

圆形薄板二维驻波的研究

在理论上和实验上对圆形薄板二维驻波波节图形(克拉尼图形)进行了研究,通过在极坐标下对圆形薄板的竖向小振动方程进行分离变量,求解出圆形薄板小振动方程在自由边条件下的解析解的简正模式,并进行了数值模拟.发现通过调节圆形薄板上点振动源的位置和频率,可精确控制薄板上出现的克拉尼图形.实验上观察到了仅有圆形波节线,仅有辐射状波节线,以及两种波节线同时存在3种情形,且波节线的数量可严格控制.并在此基础上计算了圆形薄板上二维振动的波矢和波速,以及弹性模量等物理量,且理论结果跟实验符合得很好.     

基于一组卡尔曼滤波器信息融合的故障诊断

为了能及时准确地诊断发动机的传感器和执行机构故障,文章提出了基于一组卡尔曼滤波器信息融合的方法进行故障诊断;首先根据传感器特性设计了一组滤波器用于传感器故障诊断、隔离,每个滤波器针对一个传感器进行设计;其次根据执行机构故障特性设计了一组卡尔曼滤波器进行执行机构偏差估计,从而对执行机构进行故障诊断、隔离;接着给出了传感器、执行机构信息融合的诊断方案;最后分别给传感器、执行机构添加故障进行方案验证,仿真结果得出在传感器或者执行机构任意部件出故障的情况下,该融合方法可以有效地诊断并隔离出有故障的传感器或者执行机构。     

Is JPC=3-+ molecule possible?

The confirmation of charged charmonium-like states indicates that heavy quark molecules should exist.Here we discuss the possibility of a molecule state with J P C= 3-+. In a one-boson-exchange model investigation for the S wave C = + D* ˉD*2states, one finds that the strongest attraction is in the case J = 3 and I = 0 for bothπ and σ exchanges. Numerical analysis indicates that this hadronic bound state might exist if a phenomenological cutoff parameter around 2.3 Ge V(1.5 Ge V) is reasonable with a dipole(monopole) type form factor in the one-pionexchange model. The cutoff for binding solutions may be reduced to a smaller value once the σ exchange contribution is included. If a state around the D* ˉD*2threshold(≈4472 Me V) in the channel J/ψω(P wave) is observed, the heavy quark spin symmetry implies that it is not a cˉc meson and the J P C are likely to be 3-+.