全文获取类型
收费全文 | 7256篇 |
免费 | 1237篇 |
国内免费 | 1245篇 |
专业分类
化学 | 5641篇 |
晶体学 | 75篇 |
力学 | 385篇 |
综合类 | 82篇 |
数学 | 975篇 |
物理学 | 2580篇 |
出版年
2024年 | 8篇 |
2023年 | 130篇 |
2022年 | 161篇 |
2021年 | 221篇 |
2020年 | 293篇 |
2019年 | 260篇 |
2018年 | 203篇 |
2017年 | 240篇 |
2016年 | 356篇 |
2015年 | 365篇 |
2014年 | 432篇 |
2013年 | 563篇 |
2012年 | 650篇 |
2011年 | 651篇 |
2010年 | 529篇 |
2009年 | 551篇 |
2008年 | 522篇 |
2007年 | 484篇 |
2006年 | 435篇 |
2005年 | 405篇 |
2004年 | 350篇 |
2003年 | 360篇 |
2002年 | 313篇 |
2001年 | 238篇 |
2000年 | 195篇 |
1999年 | 139篇 |
1998年 | 94篇 |
1997年 | 85篇 |
1996年 | 108篇 |
1995年 | 58篇 |
1994年 | 62篇 |
1993年 | 51篇 |
1992年 | 48篇 |
1991年 | 47篇 |
1990年 | 43篇 |
1989年 | 16篇 |
1988年 | 13篇 |
1987年 | 19篇 |
1986年 | 15篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1968年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有9738条查询结果,搜索用时 15 毫秒
61.
双(十二烷基亚磺酰)乙烷溶剂萃取钯及其机理的研究 总被引:2,自引:0,他引:2
本文研究用双(十二烷基亚磺酰)乙烷萃取钯的性能,在KI存在下从7mol/L盐酸介质中用含有BDSE的氯仿能定量萃取钯,有机的钯可被硫脲或氨溶液反萃继之用TMK-TritonX-100光度法测定,研究了萃取的最佳条件及干扰情况,斜率法测得萃合物组成为Pd:I:BDSE=1:2:1,红外光谱证实萃合物中BDSE的二个亚砜以硫原子与钯配位,萃合物为异位体络合物,提出了选择性萃取分离钯的新方法。 相似文献
62.
A new two-sided model of vapour-liquid layer system with a deformable interface is proposed. In this model, the vapour recoil effect on the Marangoni-Bénard instability of a thin evaporating liquid layer can be examined only when the interface deflexion is considered. The instability of a liquid layer undergoing steady evaporation induced by the coupling of vapour recoil effect and the Marangoni effect is analysed using a linear stability theory. We modify and develop the Chebyshev-Tau method to solve the instability problem of a deformable interface system by introducing a new equation at interface boundary. New instability behaviour of the system has been found and the self-amplification mechanism between the evaporation flux and the interface deflexion is discussed. 相似文献
63.
64.
Wei‐Lie Xiao Jian‐Xin Pu Rui‐Rui Wang Liu‐Meng Yang Xiao‐Li Li Sheng‐Hong Li Rong‐Tao Li Sheng‐Xiong Huang Yong‐Tang Zheng Han‐Dong Sun 《Helvetica chimica acta》2007,90(8):1505-1513
Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1. 相似文献
65.
In this article we consider partitioned Runge-Kutta (PRK) methods for Hamiltonian partial differential equations (PDEs) and present some sufficient conditions for multi-symplecticity of PRK methods of Hamiltonian PDEs.
66.
具有转向点超曲面的奇摄动椭圆型方程边值问题 总被引:5,自引:0,他引:5
本文利用多重尺度法和比较定理,研究了n维空间中一类具有转向点超曲面的奇摄动椭圆方程边值问题,研究了该值问题解的渐近性态。 相似文献
67.
Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with 1H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. 1H NMR spectra carried out in CDCl3 and D2O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006 相似文献
68.
69.
Yunchun Zhou Jianxin Geng Gao Li Enle Zhou Liang Chen Wanjin Zhang 《Journal of Polymer Science.Polymer Physics》2006,44(4):764-769
A series of crystals of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 Å, b = 8.82 Å, c = 23.20 Å, and β = 95.03°, as determined using electron diffraction tilting method combined with wide‐angle X‐ray diffraction experiment. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 764–769, 2006 相似文献
70.
Degradation of 4-chlorophenol in aqueous solution by γ-radiation and ozone oxidation 总被引:5,自引:2,他引:3
HU Jun WANG Jianlong & CHEN Rong . Laboratory of Environmental Technology Institute of Nuclear Energy Technology Tsinghua University Beijing China . State Key Joint Laboratory of Environmental Simulation Pollution Control Tsinghua University Beijing China Correspondence should be addressed to Wang Jianlong 《中国科学B辑(英文版)》2006,(2)
The application of radiation technology in the en-vironmental protection was listed as one of the mostimportant research fields by the International AtomicEnergy Agency (IAEA) for the peaceful use of nuclearenergy. It has great research value and potential appli-cation. Because of their broad-spectrum antimicrobialproperties, Cholophenols (CPs) have been used aspreservative agents for wood, paints, vegetable fibersand leather and as disinfectants. In addition, they havebeen widely employed… 相似文献