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71.
Controlled functionalization of carbon nanotubes (CNTs) through the use of cycloaddition reactions is described. By employing various cycloaddition reactions, a wide range of molecules could be coupled onto CNTs without disruption of the structural integrity as well as with a statistical distribution of functional groups onto the surface of the CNTs. The cycloaddition reactions represent an effective and tailored approach for preparing CNT-based advanced hybrid materials that would be useful for a wide range of applications from nanobiotechnology to nanoelectronics. 相似文献
72.
A series of novel thiourea based receptors (1-12) with different signaling units and spacers have been synthesized for the detection of cyanide ion. Among these receptors, 4,4'-bis-[3-(4-cyanophenyl)thiourea]diphenyl sulfide 6 and 4,4'-bis-[3-(3-cyanophenyl)thiourea]diphenyl sulfide 9 exhibited selective detection of cyanide by the naked-eye as well as by UV-Vis spectroscopy. Furthermore, the chemosensor is insensitive to the presence of other environmentally relevant anions. The chromogenic transformation permits the detection of cyanide (TBA(+) and K(+) salts) in the natural environment. 相似文献
73.
It has been reported that the introduction of a dielectric barrier between adjacent digits of an interdigitated electrode array can improve the sensitivity of the array as an electrochemical impedance biosensor. Here we present an in‐depth analysis of the impedance in planar interdigitated electrodes and 3‐D interdigitated electrodes (with dielectric barriers). The analysis indicates that the planar geometry not only provides lower impedance but also a higher change impedance as a result of molecular immobilization on the electrode array surface. 相似文献
74.
A new copper modified amine functionalized zirconia has been synthesized by a co-condensation method using zirconium butoxide and aminopropyltriethoxy-silane (APTES) in the presence of a cationic surfactant CTAB followed by impregnation of copper. Nitrogen adsorption-desorption, X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), (13)C nuclear magnetic resonance (NMR), scanning electron micrography (SEM), transmittance electron micrography (TEM), thermo gravimetric analysis-differential thermal analysis (TGA-DTA), X-ray photoelectron spectroscopy (XPS) and UV-vis DRS spectroscopic tools are used to characterize the materials. FT-IR and DRS results indicated the incorporation of Cu and amino groups on the surface of zirconia. This Cu-anchored mesoporous material acts as an efficient, reusable catalyst in the aryl-sulfur coupling reaction between aryl iodide and thiophenol for the synthesis of value added diarylsulfides. 相似文献
75.
Organocatalytic conjugate addition of thiols to α-substituted N-acryloyloxazolidin-2-ones followed by asymmetric protonation has been studied in the presence of cinchona alkaloid derived thioureas. Both of the enantiomers are accessible with the same level of enantioselectivity using pseudoenantiomeric quinine/quinidine derived catalysts. The addition/protonation products have been converted to useful biologically active molecules. 相似文献
76.
The present investigation is concerned with the study of extensional wave motion in an infinite homogenous isotropic, thermoelastic plate by using asymptotic method. The governing equation for the extensional wave motions have been derived from the system of three-dimensional dynamical equations of linear coupled theory of thermoelasticity. All coefficients of the differential operator are expressed as explicit functions of the material parameters. The velocity dispersion equation for the extensional wave motion is deduced from the three-dimensional analog of Rayleigh–Lamb frequency equation for thermoelastic plate waves. The approximations for long and short waves and expression for group velocity are also derived. The thermoelastic Rayleigh–Lamb frequency equations for the considered plate are expanded in power series in order to obtain polynomial frequency and velocity dispersion relations whose equivalence is established to that of asymptotic method. The dispersion curves for phase velocity and attenuation coefficient are shown graphically for extensional wave motion of the plates. 相似文献
77.
Akhtar J Mehmood RF Malik MA Iqbal N O'Brien P Raftery J 《Chemical communications (Cambridge, England)》2011,47(6):1899-1901
We describe for the first time the use of a single source precursor to deposit thin films and nanocrystals of palladium selenide. 相似文献
78.
The Ramanujan Journal - In this paper, we provide the combinatorial interpretations of many mock theta functions and some generalizations using Frobenius partitions with attached weights. We... 相似文献
79.
Elzain M. Al Rawas A. Yousif A. Gismelseed A. Rais A. Al-Omari I. Bouziane K. Widatallah H. 《Hyperfine Interactions》2004,158(1-4):205-209
Time differential perturbed γ-γ angular correlation technique was used to measure the magnetic hyperfine field (MHF) at Tb
sites in the intermetallic compound Tb3In5 using the 140La → 140Ce nuclear probe. The measurements were carried out in the temperature range of 8 to 295 K. Two different temperature dependent
magnetic frequencies were observed below 30 K, which were assigned as 140Ce substituting the two inequivalent Tb sites in the orthorhombic structure of Tb3In5. The temperature dependence of MHF also shows a possible deviation from an expected Brillouin-like behavior for temperatures
below 18 K. A Néel transition at 27 K was observed from magnetization measurements in the samples. The magnetization as a
function of the applied magnetic field was measured at two temperatures, 5 and 40 K, and the results show antiferromagnetic
and a typical paramagnetic behavior, respectively. In both cases it was not observed saturation under high magnetic field. 相似文献
80.