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21.
RUAN Manqi XU Gang & ZENG Jinyan Department of Physics Tsinghua University Beijing China Department of Physics Peking University Beijing China Correspondence should be addressed to Zeng Jinyan 《中国科学G辑(英文版)》2004,47(1):36-41
Foratwo-particle(spin1/2)systemthespinstateisdescribedusingavectorinafour-dimensionalHilbertspace.Inangularmomentumcouplingtheory[1],theangularmomentumuncouplingandcouplingrepresentationsareusuallyadopted.WhilethesimultaneouseigenstatesoftheCSCO(s1z,s2z),12,12,12and12,arechosenasthebasisofangularmomentumuncouplingscheme,thesimultaneouseigenstatesoftheCSCO(2,zSS),,SM(12=+Sss),arechosenasthebasisofangularmomentumcouplingscheme,1212100,2轾=-臌1212110,2轾=+臌121211,1,1.=-=Thefo… 相似文献
22.
Fei Chang Dongheng Zhang Haijian Yang Haibin Song 《Journal of organometallic chemistry》2004,689(5):936-946
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene. 相似文献
23.
Haibo Peng Boyu Wu Qiong Song Fei Lu Shuyun Luo 《International Journal of Infrared and Millimeter Waves》2003,24(9):1587-1596
Hybrid electrode combined coplanar waveguide (CPW) and microstrip lines in ultra-broadband electro-optic modulators. The characteristics of the modulators with hybrid electrode is like that of the modulator with the microstrip lines, in which the microstrip electrode is loaded above only one arm of Mach-Zehnder (M-Z) optical waveguide, besides the problem of microstrip line to coaxial transition and corona polarization in polymer modulators have been best solved at the same time. By using finite element method (FEM), the characteristic parameters such as half-wave voltage, modulation bandwidth characteristic impedance, effective microwave refractive index of polymer modulators with microstrip line and hybrid electrode are analysed and compared in this paper. The results present that velocity match, impendence match and lower microwave propagating loss is easily realized in modulators with hybrid electrode. 相似文献
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使用结构简单的单温炉设备,通过三步升温热解二茂铁、三聚氰氨混合物方法,在二氧化硅、多晶陶瓷基底上分别合成了碳纳米管阵列、碳纳米管捆束.使用扫描电子显微镜、透射电子显微镜、电子能量损失谱和x射线光电子能谱对合成样品进行了结构和成分分析.结果显示:两种基底上合成的纳米管均为多壁纯碳管;生长于光滑二氧化硅表面的碳纳米管具有高度取向性和一致的外径,长度为10—40μm.碳纳米管采取催化剂顶端生长模式并展示出类杯状形貌;生长于粗糙多晶陶瓷表面的碳纳米管捆束随机取向,碳纳米管直径为15—80nm,长度在几百微米,展示
关键词:
碳纳米管
热解法
三步升温工艺 相似文献
26.
Herein we report a new method to collect a qualified infrared spectrum of a solute in solution by two solvent cells with different thickness during background single-beam spectrum scanning. By collecting the background spectrum with two cells (two stages), we successfully achieved accurate solvent compensation between a sample and a reference, namely, the solvent amounts in the sample and background measurements could become congruent. Therefore, the solvent bands were thoroughly suppressed in the infrared spectrum and a qualified spectrum of the solute was obtained. 相似文献
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Ping Li Fei Rong Yibing Xie Van Hu Chunwei Yuan 《Journal of Analytical Chemistry》2004,59(10):939-944
S-naproxen imprinted polymer was prepared with acrylamide as a functional monomer, 1,4-butanediyl diacrylate as a new kind of crossliner, and 2,4,6-trimethylbenzoylphenyl-phosphinic acid ethyl ester as photoinitiator. Their UV and IR spectra were applied to study the interactions between the template and the monomer. Binding experiments showed that the S-naproxen imprinted polymer had better recognition capability for the template than that of a blank polymer. The adsorption distribution coefficient KD of S-naproxen on molecularly-imprinted polymer was 153.2 g/mL, and the separation factor was 1.95 when the initial concentration of substrate was 2.0 mmol/L. Scatchard curves suggested that there were two classes of binding sites in the imprinted polymer and only one class in the blank polymer. Computer simulation using Hyperchem showed the existence of the interactions between the template and the functional monomer as well as the models of the complexes formed by the template and the monomer. 相似文献
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用量子化学从头算方法在B3LYP/6 311G 的水平上 ,研究了RuH2 和RuN2 可能的电子组态和光谱性质 .结果表明 ,RuH2 的3 B2 和5Σ-态对应于静电作用的物理吸附态 .RuN2 的一重态和三重态的计算结果跟钌单晶面上的实验值相接近 .而RuN2 在C∞v对称性时 ,五重态5Σ-的计算频率比实验值稍低 .在C2v对称性时 ,五重态的计算频率值则更低 ,3 B2 和5A1态不能稳定存在 相似文献