A Facile Preparation of N2-Arylisocytosines

N²-Arylisocytosines were obtained in good yields varying from 59 to 96% by a simple two-step process starting from 2-thiouracil via readily accessible 2-(methylthio)pyrimidin-4(3H)-one.     

Reconstruction of the Sea Bottom Parameters for Coherent Seismoacoustic Sounding: I. Decision Rules

We have developed an algorithm for reconstructing the geoacoustic parameters of bottom layers using parametric models of the formation of signals reflected from a layered halfspace during coherent sounding of the bottom of a sea shelf. We propose a method for layer-by-layer reconstruction that makes it possible to efficiently search for a solution in the multiparameter space with limited a priori data.     

Solid State Synthesis of Spinel-Type Metal Oxide Mg1.5Fe0.5MnO4 and Study of Its Exchange Capability for Li+

Russian Journal of Applied Chemistry - The spinel-type composite metal oxide, magnesium-manganese-titanium oxide (Mg1.5Fe0.5MnO4), was prepared by the method of solid state crystallization. As a...     

A Mesoporous Сarbon Prepared by Сarbonizing Cu(II)–p-Phenylenediamine Polymer for the Adsorption of Methyl Orange from Water

Russian Journal of Physical Chemistry A - A new mesoporous carbon containing nitrogen and copper was prepared by carbonizing a polymer obtained by blending p-phenylenediamine, copper(II) sulfate,...     

首次积分法求Boussinesq 方程的精确尖波解

首次积分法是一种求解非线性偏微分方程精确解的有效方法,利用首次积 分法获得了Boussinesq方程的一个精确尖波解.     

Capillary electrophoresis in the diagnosis of surgical site infections

A surgical site infection (SSI) is an infection that occurs after surgery in the part of the body where the surgery took place. An SSI may range from a spontaneously limited wound discharge within 7–10 days of an operation to a life‐threatening postoperative complication, such as a sternal infection after open heart surgery. Most SSIs are caused by contamination of an incision with microorganisms from the patient's own body during surgery. From the analytical point of view, the complex nature of these samples as well as the low concentrations of analytes require a system with high sensitivity and efficiency. Such situation requires a technique such as CE, which is a powerful and versatile separation technique that promises to rival HPLC when applied to the separation of both charged and neutral species. During the study, it has been demonstrated that CZE identifies characteristics of such groups of pathogens such as bacteria Gram (+) and different species of bacteria Gram (?), and also develops weekly individual profiles for patients after application of antibiotics. This was done in order to show the impact of antibiotic therapy in change “numbers” of bacteria present in the wound after surgery. The method proved to be the ideal straight specificity in the case of Escherichia coli (100%). Finally, analysis of the spectra and the second derivatives of the UV‐Vis spectra confirmed the similarity in the profiles and showed that the CZE is a great method for fast screening test in bacterial infection.     

Absolute configurations of C34 and C35 of antibiotic niphimycin A

The relative configurations of four stereogenic centers of the C33‐C42 fragment of niphimycin A were assigned as 2S*, 3R*, 4S* and 6S*, based upon ¹H NMR analysis with double‐quantum filtered COSY and nuclear Overhauser spectroscopy experiments. These data were then correlated with absolute configurations at C36 and C38 of niphimycin A, which were declared previously as 36S and 38S [3]. This allowed for the assignment of the absolute configurations at C34 and C35 of niphimycin A as 34S and 35R. Copyright © 2012 John Wiley & Sons, Ltd.     

Multinuclear magnetic resonance studies of 2‐aryl‐1,3,4‐selenadiazoles

2‐Aryl‐1,3,4‐selenadiazoles were studied by ¹H, ¹³C, ¹⁵N and ⁷⁷Se NMR spectroscopy. The results (chemical shifts and coupling constants) were correlated with Hammett substituent parameters as well as calculated chemical shifts and bond lengths. Copyright © 2012 John Wiley & Sons, Ltd.     

BMD-TLC — the Useful Technique for Quantitative Analysis of Chelidonine,Chelerithrine and Berberine in Herbal Drugs

JPC – Journal of Planar Chromatography – Modern TLC - Three step bivariant multiple development thin-layer chromatography (BMD-TLC) technique was used in the quantitative analysis of...