全文获取类型
收费全文 | 3309篇 |
免费 | 436篇 |
国内免费 | 390篇 |
专业分类
化学 | 2633篇 |
晶体学 | 22篇 |
力学 | 185篇 |
综合类 | 45篇 |
数学 | 294篇 |
物理学 | 956篇 |
出版年
2024年 | 11篇 |
2023年 | 47篇 |
2022年 | 82篇 |
2021年 | 95篇 |
2020年 | 110篇 |
2019年 | 123篇 |
2018年 | 84篇 |
2017年 | 100篇 |
2016年 | 122篇 |
2015年 | 133篇 |
2014年 | 179篇 |
2013年 | 233篇 |
2012年 | 295篇 |
2011年 | 305篇 |
2010年 | 215篇 |
2009年 | 201篇 |
2008年 | 211篇 |
2007年 | 202篇 |
2006年 | 181篇 |
2005年 | 141篇 |
2004年 | 127篇 |
2003年 | 100篇 |
2002年 | 87篇 |
2001年 | 89篇 |
2000年 | 90篇 |
1999年 | 87篇 |
1998年 | 87篇 |
1997年 | 67篇 |
1996年 | 67篇 |
1995年 | 41篇 |
1994年 | 27篇 |
1993年 | 30篇 |
1992年 | 23篇 |
1991年 | 26篇 |
1990年 | 17篇 |
1989年 | 20篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 5篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1966年 | 2篇 |
1931年 | 1篇 |
1924年 | 1篇 |
1884年 | 1篇 |
排序方式: 共有4135条查询结果,搜索用时 250 毫秒
81.
82.
Eu(Ⅲ)、Tb(Ⅲ)、Ho(Ⅲ)、Tm(Ⅲ)和Lu(Ⅲ)与N,N′-二(邻羟基亚甲基)乙二胺配合物的研究 总被引:1,自引:0,他引:1
Dutt曾合成稀土离子与N,N′-二(邻羟基亚甲基)乙二胺的稀土双希夫碱配合物。但未见报道Eu(Ⅲ),Tb(Ⅲ),Ho(Ⅲ),Tm(Ⅲ),Lu(Ⅲ)与双希夫碱N,N′-二(邻羟基亚甲基)乙二胺的配合物。本工作合成了这5种双希夫碱配合物。 所用稀土氧化物纯度大于99.9%(上海跃龙化工厂)。水杨醛(CP,用前经减压蒸馏提纯)。稀土硝酸盐Ln(NO_3)_3·xH_2_由稀土氧化物与硝酸反应制得。其余试剂均为分析纯。 仪器为Perkin-Elmer 240-C元素分析仪;Nicolet-5DX型红外光谱仪,KBr压片;岛津UV- 相似文献
83.
84.
85.
汞电极表面电荷的快速估算 总被引:1,自引:0,他引:1
本文报导了用交流示波极谱快速估算电极表面电荷的方法。该方法使用仪器简单,测量快速,操作简便,在吸附研究中很有用处。 相似文献
86.
87.
J. V. Crivello Daoshen Bi 《Journal of polymer science. Part A, Polymer chemistry》1993,31(12):3109-3119
Silicon-containing epoxide compounds bearing Si ? H groups can be readily prepared in high yields by the regioselective rhodium-catalyzed monohydrosilation of α,ω-dihydrogen functional siloxanes and silanes with vinyl epoxides. The remaining Si ? H groups in these compounds can be further selectively hydrosilated with unsaturated epoxides to give a series of unique ambifunctional monomers containing two different epoxide groups in the same molecule. The photopolymerization of these monomers has been studied using analytical techniques including real time infrared spectroscopy and differential scanning photocalorimetry. On photopolymerization, the new monomers yield interesting networks. © 1993 John Wiley & Sons, Inc. 相似文献
88.
Preparation of Nano-Sized γ-Al2O3 Supported Iron Catalyst for Fischer-Tropsch Synthesis by Solvated Metal Atom Impregnation Methods 下载免费PDF全文
Two types of small iron clusters supported on γ-Al2O3-RT(dehydroxylated at room temperature) and γ-Al2O3-800 (dehydroxylated at 800 ℃) were prepared by solvated metal atom impregnation (SMAI) techniques. The iron atom precursor complex, bis(toluene)iron(0) formed in the metal atom reactor, was impregnated into γ-Al2O3 having different concentrations of surface hydroxyl groups to study the effect of surface hydroxylation on the crucial stage of iron cluster formation. Catalysts prepared in this way were characterized by TEM, M(o)ssbauer, and chemisorption measurements, and the results show that higher concentration of surface hydroxyl groups of γ-Al2O3-RT favors the formation of more positively charged supported iron cluster Fen/γ-Al2O3-RT, and the lower concentration of surface hydroxyl groups of γ-Al2O3-800 favors the formation of basically neutral supported iron cluster Fen/γ-Al2O3-800. The measured results also indicate that the higher concentration of surface hydroxyl groups causes the rapid decomposition of precursor complex, bis(toluene)iron(0), and favors the formation of relatively large iron cluster. Consequently, these two types of catalysts show different catalytic properties in Fischer-Tropsch reaction. The catalytic pattern of Fen/γ-Al2O3-RT in F-T reaction is similar to that of the unreduced α-Fe2O3 and that of Fen/γ-Al2O3-800 is similar to that of the reduced α-Fe2O3. 相似文献
89.
Paul De Bièvre 《Accreditation and quality assurance》2000,5(10-11):423-428
Talking about "traceability" means talking about a "property of the result of a measurement", about "the value of a standard", about "stated references" and about an "unbroken chain of comparisons". It describes by which comparison, and to which other value, the result of a measurement has been obtained, i.e. is "traceable to". It is about the underlying structure of the measurement process of the result of a measurement and therefore about the authority of the result. Since values carried by (certified) reference materials have also been obtained by measurement, the definition of traceability equally applies. Traceability in the context of reference materials is also about the authority of the values carried by the (certified) reference materials and is, therefore, of key importance for the authority of the reference materials themselves. Hence, values of results of measurements constitute part of the traceability chain and their uncertainties are an intrinsic accompanying phenomenon. Uncertainties need a traceability chain against which they can be evaluated, and a traceability chain is an a priori requirement for evaluating the uncertainty budget of a measurement result. An attempt has been made to exemplify "traceability" chains in some types of chemical measurement and to identify the degree of international agreement on the key elements of "traceability". It is concluded that there is less than universal agreement on this issue. The debate should continue in order to arrive at the international understanding and agreement needed, as "traceability" is now being incorporated in the International Organization for Standardization (ISO), the International Laboratory Accreditation Co-operation (ILAC) and in other "guiding" or regulatory documents. It is also the reason why the Institute for Reference Materials and Measurements (IRMM) has taken up the study of the concept in its core programme on Metrology in Chemistry, and why it sponsored the Workshop in Bratislava. 相似文献
90.
Pure X-ray diffraction profiles have been analysed for polyamide 1010 and PA1010--BMI system by means of multipeak fitting resolution of X-ray diffraction.The methods ofvariance and fourth moment have been applied to determine the particle size and strainvalues for theparacrystalline materials.The results indicated that both variance and fourthmoment of X-ray diffraction line profile yielded approximately the same values of theparticle size and the strain.The particle sizes of(100)reflection have been found todecrease with increasing BMI content,whereas the strain values increased. 相似文献