Mononuclear and binuclear sandwich copper(II) complexes with poly(pyrazolyl)borate ligands: syntheses, structures and properties

A series of Cu(II) complexes Cu(2)[micro-pz](2)[HB(pz)(3)](2) (1), Cu[H(2)B(pz)(2)](2) (2), Cu[HB(pz)(3)](2) (3), Cu[HB(pz(Me2))(3)](2) (4), Cu[B(pz)(4)](2) (5) (pz=pyrazole), have been synthesized and characterized by elemental analysis, IR, UV-vis, X-ray diffraction, thermal analysis and theoretical analysis. The IR spectra give the Cu-N vibration modes at 322, 366, 344, 387, and 380 cm(-1) in complexes 1-5, respectively. The UV spectra show all the complexes have same UV absorption at 232 nm; there is another band at 332 nm for complexes 1, 2 and 4, while for complexes 3 and 5, the bands are at 272 and 308 nm, respectively. Complex 1 has a binuclear structure in which two pyrazole ligands bridge two Cu-Tp units. In 2-5, the Cu(II) centers are coordinated with dihydrobis(pyrazolyl)borate (Bp), hydrotris(pyrazolyl)borate (Tp), hydrotris(3,5-Me2pyrazolyl)borate (Tp'), tetrakis(pyrazolyl)borate (Tkp) respectively to form a mononuclear structure. The results of thermal analysis for complexes 1-5 are discussed too.     

Study of bis(bibenzyls) in bryophytes using electron ionization time-of-flight and electrospray ionization triple-quadrupole mass spectrometry

A detailed analysis of mass spectra generated from bis(bibenzyl) compounds in bryophytes under electron ionization time-of-flight (EI-TOF) and electrospray ionization triple-quadrupole (ESI-TQ) mass spectrometry conditions is reported. Proposed structures of the fragment ions were obtained by tracking the functional groups of 15 bis(bibenzyls), the structures of which are similar except for some alkoxyl substituents and linkage sites of biphenyl ether bonds. The elucidation was aided by the use of accurate mass measurements. Attempts have been made to provide rational pathways for the formation of these fragment ions, and a generalized fragmentation mechanism is proposed. The bis(bibenzyls) mentioned in this study include three types according to their structure characteristics, i.e. one biphenyl ether bond (A-type), two biphenyl ether bonds (B-type), one biphenyl ether and one biphenyl bond (C-type). The three types display different EI-MS and ESI-MS/MS product profiles, by which the bis(bibenzyl) type and the number of alkoxyl substituents can be identified. Isomers of bis(bibenzyls) can be differentiated to some extent, while the linkage sites of biphenyl ether bonds are difficult to identify. The structure-fragmentation relationships will facilitate the characterization of other bis(bibenzyls) and this will be of value for the high-throughput screening of novel bis(bibenzyls) in bryophytes.     

Immersed Hypersurfaces in the Unit Sphere S^m＋1 with Constant Blaschke Eigenvalues

For an immersed submanifold x ： M^m→ Sn in the unit sphere S^n without umbilics, an eigenvalue of the Blaschke tensor of x is called a Blaschke eigenvalue of x. It is interesting to determine all hypersurfaces in Sn with constant Blaschke eigenvalues. In this paper, we are able to classify all immersed hypersurfaces in S^m＋1 with vanishing MSbius form and constant Blaschke eigenvalues, in case （1） x has exact two distinct Blaschke eigenvalues, or （2） m = 3. With these classifications, some interesting examples are also presented.     

La(BO_2)_3基质中Eu~(3+)的发光性质与晶体结构的关系

采用高温固相反应合成了 (La1-xEux) (BO2 ) 3 ,利用X射线粉末衍射方法确定其晶体结构 ,利用红外光谱探讨了 [BO3 ]单元的聚合情况。根据 (La1-xEux) (BO2 ) 3 所属空间群中等效点系的对称性分析及Eu3 + 的荧光光谱 ,详细地探讨了Eu3 + 的发光性质与其所处格位点对称性的关系。La(BO2 ) 3 ∶Eu3 + 体系中 ,Eu3 + 出现较强的5D0 →7F1磁偶极跃迁 ,因而Eu3 + 主要占据点对称性为Ci 的格位 ,出现的其它跃迁是部分Eu3 + 占据偏离Ci 的格位 ,而并非占据C2 或C1格位 ,另外 ,5D0 →7F4 跃迁发射很强 ,其原因尚不清楚。选择适当的助熔剂可以提高样品的结晶程度 ,有利于Eu3 + 占据严格的Ci 格位 ,增强材料的发光性能。     

空间编码与灰度投影相结合实现高效3-D形貌测量的研究

介绍了一种结合空间编码与灰度投影来实现高效三维形貌测量的方法。用空间编码完成对被测空间的粗略编码,用灰度投影完成精确编码,将它们结合起来得到被测物体表面丰富的编码信息,作为一种基于三角法的三维形貌测量方法,能够在物体表面非常不连续和外部光照造成的背景光强分布不确定的情况下工作良好。同时,与传统的空间编码方法相比,它大大提高了空间编码的效率。实验表明,该方法用５ 幅图像取得了与灰度码１０幅图像相当的测量结果。     

红外寻的演示枪

韩长明 主持 “红外寻的演示枪”是用于讲述凸、凹透镜原理应用方面的演示实验装置．其利用面透镜会聚和四透镜发散的基本原理,组成了一个简单的红外搜寻瞄准系统,能自动搜寻前方一定立体空间内任意位置的所有燃烛,并以０．４ｍｍ口径的水枪将其逐个准确摧灭． “红外寻的演示枪”突破了在中学几十年来透镜成像的应用仅限于照相机、幻灯机、放大镜的僵化格局． 其规格及性能指标为; １）枪长; ２５０ｍｍ,水枪口径：０．４ｍｍ; ２）水平方向（Ｘ）扫描范围：３０”,有效灭烛距离范围： １５００～２０００ｍｍ; ３）竖直方向（Ｙ…     

金属离子和磺化酞菁反应动力学研究

本文首次采用分光光度法研究金属离子和磺化酞菁反应动力学,给出精确求解方法。并用这一方法研究了Cu(Ⅱ)与三磺化酞菁(L)的反应动力学,提出了可能的反应机理。 1 计算原理 在磺化酞菁L与金属离子M的反应体系中,可能存在下列反应:2LL_2,L_2+MML+L,L+M ML,L_2+2M(ML)_2,2ML(ML)_2。选择适当的反应条件,使得金属离子在测定波长下无吸收;磺化酞菁金属配合物的二聚可忽略。若某一时刻体系在一特     

双周期裂纹场平面弹性焊接的数学问题

本文讨论双周期胞腔中含任意形状裂纹的不同材料的弹性平面焊接(焊线为任意形状的封闭光滑曲线)的第二基本问题.运用Мусхелишвили复变函数方法,对这类弹性平面问题建立起了数学模型,将求解弹性平衡问题化归为寻求复应力函数满足一定边界条件的边值问题,然后构造其解的形式,再将其转化为正则型的奇异积分方程,数学上严格证明其解的存在与唯一.     

Study of Ternary Fission Produced in 12C Bombarding 209Bi Target with Medium Energy

Alternative layers of target material,which were prepared by evaporating ²⁰⁹Bi on the surface of mica foils,were irradiated with ¹²C ions.Ternary fission events in which three fragments of comparable mass were produced in 2525－47.5MeV/A ¹²C+²⁰⁹Bi reaction,were recorded by the mica detectors with 2π geometry.The observed probability ratio of ternary fission relative to binary fission in 2π geometry was modified to 4π geometry spatial in terms of the Monte Carlo method.The values of ratioes increase with the bombarding energy,and are compared with the calculation result of the cascade fission model.     

some general theorems and generalized and piecewise generalized variational principles for linear elastodynamics

From the concept of four-dimensional space and under the four kinds of time limit conditions, some general theorems for elastodynamics are developed, such as the principle of possible work action, the virtual displacement principle, the virtual stress-momentum principle, the reciprocal theorems and the related theorems of time terminal conditions derived from it. The variational principles of potential energy action and complementary energy action, the H-W principles, the H-R principles and the constitutive variational principles for elastodynamics are obtained. Hamilton's principle, Toupin's work and the formulations of Ref. [5], [17]-[24] may be regarded as some special cases of the general principles given in the paper. By considering three cases: piecewise space-time domain, piecewise space domain, piecewise time domain, the piecewise variational principles including the potential, the complementary and the mixed energy action fashions are given. Finally, the general formulation of piecewise variati