The measurement of the rotational relaxation times of OCS from the nutation signals

The time dependence of microwave absorption was measured for the J = 2-1 and J = 3-2 transitions of OCS under on- and off-resonant conditions utilizing Stark and source modulation, respectively. The two effective pressure parameters obtained under the two conditions, which correspond to $\text{(T}{}_2{}^{\mathrm{?1}}\text{+ T}{}_1{}^{\mathrm{?1}}\text{)}\text{4πP}$ and $\text{(2πT}{}_2\text{P)}{}^{\mathrm{?1}}$, respectively, according to the Bloch equation, are different beyond experimental error; the difference $\text{(T}{}_2{}^{\mathrm{?1}}\text{? T}{}_1{}^{\mathrm{?1}}\text{)}\text{2πP}$ is 0.94 ± 0.38 (2.5σ) MHz/Torr for J = 2?1. This difference was also determined to be 1.19 ± 0.30 MHz/Torr from the dependence of the nutation frequency on the microwave power.     

Asymmetrischselektive Copolymerisation von (R)- und (S)-tert.-Butyl?thylenoxiden mit K-tert.-Butoxid

Ohne Zusammenfassung     

A high-precision wavelength meter for tunable diode laser: Measurements of CO2 and N2O bands at 10 μm

We construct a high-precision wavelength meter for infrared tunable diode lasers (TDL) which consists of moving corner reflectors forming a Michelson interferometer, with a single-frequency HeNe laser as a standard. The design of the wavelength meter is described in detail, and possible sources of errors are discussed. An absolute accuracy of 10^?7 is demonstrated by measuring CO₂ laser wavelengths and almost the same order of accuracy is achieved by applying the wavelength meter to the ν₁ band of N₂O observed by a TDL.     

Studies on isoindoline derivatives and related compounds. I Synthesis and reduction of 1,3-dicarboethoxymethyleneisoindoline

The reaction of iminoether III with benzyl cyanoacetate gave ethyl 1-(α-cyanocarbobenzyl-oxymethylene)isoindoline-3-acetate (V) in a 26% yield. Decarboxylation of ethyl 1-(α-cyanocarboxymethylene)isoindoline-3-acetate (VI), obtained by hydrogenolysis of V, gave a mixture of 1-carboethoxymethyleneisoindoline-3-acetonitrile (VII) as major component and 1-carboethoxymethylene-3-cyanomethyleneisoindoline (VIII) as minor component, which were reconvertible into each other. On the other hand, decarboxylation of VI was successfully carried out to give VII as a single product under a nitrogen atmosphere. Ethanolysis and autoxidation of VII gave crystalline diethyl 1,3-dicarboethoxymethyleneisoindoline (XIII). Catalytic hydrogenation of of XIII over platinum oxide gave diethyl isoindoline-cis-1,3-diacetate (XIV) in a yield of 92%. The uv spectra of these 1,3-disubstituted isoindoline derivatives are summarized in Table I.     

Electrical and electrochemical properties of glass-ceramic electrolytes in the systems Li2S-P2S5-P2S3 and Li2S-P2S5-P2O5

Electrical and electrochemical properties of the 70Li₂S·(30 − x)P₂S₅·xP₂S₃ and the 70Li₂S·(30 − x)P₂S₅·xP₂O₅ (mol%) glass-ceramics prepared by the mechanical milling technique were investigated. Glass-ceramics with 1 mol% P₂S₃ and 3 mol% P₂O₅ showed the highest conductivity of 5.4 × 10^− 3 S cm^− 1 and 4.6 × 10^− 3 S cm^− 1, respectively. Moreover, these glass-ceramics showed higher electrochemical stability than the 70Li₂S·30P₂S₅ (mol%) glass-ceramic. From the XRD patterns of the obtained glass-ceramics, trivalent phosphorus and oxygen were incorporated into the Li₇P₃S₁₁ crystal. We therefore presume that the Li₇P₃S₁₁ analogous crystals, which were formed by incorporating trivalent phosphorus and oxygen into the Li₇P₃S₁₁ crystal, improve the electrical and electrochemical properties of the glass-ceramics. An all-solid-state cell using the 70Li₂S·29P₂S₅·1P₂S₃ (mol%) glass-ceramic as solid electrolyte operated under the high current density of 12.7 mA cm^− 2 at the high temperature of 100 °C. The cell showed an excellent cyclability of over 700 cycles without capacity loss.     

Generation of flat optical frequency comb by fiber loop modulation

We propose a novel flat optical frequency comb generation system that employs fiber loop modulation and experimentally demonstrate its operation. Generally, when an external laser beam is injected into a fiber loop system including an optical modulator and an amplifying medium, multiple sidebands are generated exponentially. On the other hand, the fiber loop starts mode-locked oscillation at a center frequency to maximize the round-trip gain in the fiber loop from the seeds of the injected laser sidebands. By locking the sidebands from fiber loop modulation with the mode-locked oscillation in the fiber loop, the synchronous spectrum between the mode-locked oscillation and the sidebands can be shaped into a flat spectrum. Thus, a flat optical frequency comb with a flatness of about ±1 dB is obtained in the spectral bandwidth of about 1 THz.