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A statistical inversion method is proposed for the photon–photoelectron-counting statistics in quantum key distribution experiment. With the statistical viewpoint, this problem is equivalent to the parameter estimation for an infinite binomial mixture model. The coarse-graining idea and Bayesian methods are applied to deal with this ill-posed problem, which is a good simple example to show the successful application of the statistical methods to the inverse problem. Numerical results show the applicability of the proposed strategy. The coarse-graining idea for the infinite mixture models should be general to be used in the future. 相似文献
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Synthesis of hydrothermally stable and long-range ordered Ce-MCM-48 and Fe-MCM-48 materials 总被引:1,自引:0,他引:1
The hydrothermally stable and long-range ordered Ce-MCM-48 and Fe-MCM-48 were conveniently synthesized at 393 K for 24 h by directly adding fluoride ions to the initial gel without posttreatment and pH adjustment. The Ce-MCM-48 with a Si/Ce of 200 and 100, which were prepared by directly adding fluoride ions, could still maintain their mesoporous structures after refluxing in boiling water for 3 days. The incorporation of Ce into MCM-48 could enhance the hydrothermal stability of MCM-48 in the absence of fluoride ions; however, the incorporation of Fe into MCM-48 materials barely improved the hydrothermal stability of MCM-48 materials. The effect of adding NaF was much more efficient in enhancement of hydrothermal stability than that of the incorporation of Ce. The addition of fluoride ions mainly improves the degree of polymerization of silicates. The Ce(4+) ions in Ce-MCM-48 appear to be present partly in tetrahedral coordination in the framework and partly as CeO(2) particles on the surface of framework. The Ce positioned on the surface of pore walls and in the framework both provide the protection against water attack. 相似文献
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We report a new kind of experimental realization of a molecular rectifier, which is based on a single azafullerene C59N molecule in a double-barrier tunnel junction via the single electron tunneling effect. An obvious rectifying effect is observed. The positive onset voltage is about 0.5-0.7 V, while the negative onset voltage is about 1.6-1.8 V. Theoretical analyses show that the half-occupied molecular orbital of the C59N molecule and the asymmetric shift of the molecular Fermi level when the molecule is charged are responsible for the molecular rectification. 相似文献
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Guangyi?Gu Bing?Dai Xunlei?Ding Jinlong?YangEmail author 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2004,29(1):27-31
Hybrid density functional calculations are performed to study the structural and electronic properties of neutral, anionic and cationic Y3O clusters. The most stable structures of these clusters are found to be triply bridging oxygen atom structures with CS symmetry. The ground states of Y3O, Y3O- and Y3O + are doublet (2A), triplet (3A) and singlet (1A), respectively. The calculated electron affinities and ionization potentials are in good agreement with the available experimental data. Time-dependent density functional theory is used to calculate the low-lying excited states. A theoretical assignment for the features in the experimental photoelectron spectra is given.Received: 5 November 2003, Published online: 20 January 2004PACS:
36.40.Mr Spectroscopy and geometrical structure of clusters - 31.15.Ew Density-functional theory - 34.50.Gb Electronic excitation and ionization of molecules; intermediate molecular states (including lifetimes, state mixing, etc.) 相似文献
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采用双波长注入一包含伪随机码发生器与相位调制器的光电振荡器可以同时得到非归零(NRZ)码,归零(RZ)码以及光,电时钟信号输出。该方案使用了光域耦合的双环路结构,在不增加有源器件的条件下实现边模抑制。相位调制器用于反馈调制并同时实现占空比可调的非归零码到归零码的转换。双波长的注入排除了编码信号在振荡器中引入的非时钟频率成分。实验给出了10 Gb/s工作速率下的结果,得到了抖动为637 fs的光信号输出。转换得到的归零码信号占空比约为33%。输出电时钟信号的相位噪声在频偏10 kHz处为-109 dBc/Hz,边模抑制比为58 dB。 相似文献
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