全文获取类型
收费全文 | 958篇 |
免费 | 42篇 |
国内免费 | 4篇 |
专业分类
化学 | 655篇 |
晶体学 | 7篇 |
力学 | 19篇 |
数学 | 119篇 |
物理学 | 204篇 |
出版年
2023年 | 5篇 |
2022年 | 14篇 |
2021年 | 15篇 |
2020年 | 13篇 |
2019年 | 20篇 |
2018年 | 13篇 |
2017年 | 5篇 |
2016年 | 41篇 |
2015年 | 31篇 |
2014年 | 38篇 |
2013年 | 67篇 |
2012年 | 60篇 |
2011年 | 64篇 |
2010年 | 50篇 |
2009年 | 40篇 |
2008年 | 59篇 |
2007年 | 57篇 |
2006年 | 46篇 |
2005年 | 41篇 |
2004年 | 42篇 |
2003年 | 25篇 |
2002年 | 36篇 |
2001年 | 10篇 |
2000年 | 17篇 |
1998年 | 10篇 |
1997年 | 14篇 |
1996年 | 11篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1972年 | 8篇 |
1971年 | 4篇 |
1961年 | 3篇 |
排序方式: 共有1004条查询结果,搜索用时 15 毫秒
51.
52.
Cover Picture: Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports (Angew. Chem. Int. Ed. 25/2016)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Han Zhang Prof. Qiang Xiao Prof. Xianghai Guo Prof. Najun Li Prashant Kumar Neel Rangnekar Mi Young Jeon Prof. Shaeel Al‐Thabaiti Prof. Katabathini Narasimharao Prof. Sulaiman Nasir Basahel Prof. Berna Topuz Frank J. Onorato Prof. Christopher W. Macosko Prof. K. Andre Mkhoyan Prof. Michael Tsapatsis 《Angewandte Chemie (International ed. in English)》2016,55(25):7009-7009
53.
Andre Arnebold Oliver Schorsch Johannes Stelten Andreas Hartwig 《Journal of polymer science. Part A, Polymer chemistry》2014,52(12):1693-1699
The industrial applications of benzoxazines are limited due to their high curing temperatures. This drawback can be overcome by more reactive precursor compared to conventional benzoxazines or by application of efficient initiators. We report the synthesis of a new resorcinol‐based benzoxazine and its cationic polymerization with thermolatent super acids, namely organic sulfonium hexafluoroantimonates. This combination of a reactive precursor and an efficient initiator results in a curing temperature below 100 °C (differential scanning calorimetry onset) which is up to now one of the lowest polymerization temperatures for benzoxazine systems. Furthermore, the thermal stability of the formed polybenzoxazine has not been influenced by the applied initiators. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1693–1699 相似文献
54.
Lyubov I. Kazakova Lyudmila I. Shabarchina Salzitsa Anastasova Anton M. Pavlov Pankaj Vadgama Andre G. Skirtach Gleb B. Sukhorukov 《Analytical and bioanalytical chemistry》2013,405(5):1559-1568
The concept of enzyme-assisted substrate sensing based on use of fluorescent markers to detect the products of enzymatic reaction has been investigated by fabrication of micron-scale polyelectrolyte capsules containing enzymes and dyes in one entity. Microcapsules approximately 5 μm in size entrap glucose oxidase or lactate oxidase, with peroxidase, together with the corresponding markers Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride (Ru(dpp)) complex and dihydrorhodamine 123 (DHR123), which are sensitive to oxygen and hydrogen peroxide, respectively. These capsules are produced by co-precipitation of calcium carbonate particles with the enzyme followed by layer-by-layer assembly of polyelectrolytes over the surface of the particles and incorporation of the dye in the capsule interior or in the multilayer shell. After dissolution of the calcium carbonate the enzymes and dyes remain in the multilayer capsules. In this study we produced enzyme-containing microcapsules sensitive to glucose and lactate. Calibration curves based on fluorescence intensity of Ru(dpp) and DHR123 were linearly dependent on substrate concentration, enabling reliable sensing in the millimolar range. The main advantages of using these capsules with optical recording is the possibility of building single capsule-based sensors. The response from individual capsules was observed by confocal microscopy as increasing fluorescence intensity of the capsule on addition of lactate at millimolar concentrations. Because internalization of the micron-sized multi-component capsules was feasible, they could be further optimized for in-situ intracellular sensing and metabolite monitoring on the basis of fluorescence reporting. 相似文献
55.
56.
Lipases and esterases are important catalysts with wide varieties of industrial applications. Although many methods have been established for detecting their activities, a simple and sensitive approach for picogram detection of lipolytic enzyme quantity is still highly desirable. Here we report a lipase detection assay which is 1000-fold more sensitive than previously reported methods. Our assay enables the detection of as low as 5 pg and 180 pg of lipolytic activity by direct spotting and zymography, respectively. Furthermore, we demonstrated that the detection sensitivity was adjustable by varying the buffering capacity, which allows for screening of both high and low abundance lipolytic enzymes. Coupled with liquid chromatography-mass spectrometry, our method provides a useful tool for sensitive detection and identification of lipolytic enzymes. 相似文献
57.
Jadriane A. Xavier Thaissa L. Silva Eduardo Caio Torres-Santos Camila Calado de Vasconcelos Anastacio Boane Ricardo Alexandre dos Santos Andre Felippe A. Xavier Marília O.F. Goulart 《Current Opinion in Electrochemistry》2021
This review discusses the state of the art, challenges, and perspectives in recent applications of nitroaromatics and nitroheteroaromatics, which are redox-bio-activated drugs or leads, in Medicinal Chemistry. It deals mainly with the electrochemical approach toward the electron transfer-based molecular mechanisms of drug action, drug design, estimation and measurement of redox potentials, correlation of physicochemical and pharmacological data, and electrochemical studies of the main representatives of nitro-containing prodrugs, along with approaches to combat their toxicity issues, aiming at a better therapeutic profile. Electrochemical investigation plays essential roles, being strategic in the design and discovery of potential medicines. 相似文献
58.
Vladimir Fal’ko Andre Geim Sankar Das Sarma Allan MacDonald Philip Kim 《Solid State Communications》2009,149(27-28):1039-1040
59.
Catherine Bourdieu Andre Foucaud 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):365-368
Abstract 1,2-Dihydro 1,2-Δ3? azaphosphorines were prepared by reaction of dichlorophenylphosphine with two equivalents of imines. 2-Oxo 1,2-azaphospholenes were also obtained in some cases. 相似文献
60.