排序方式: 共有114条查询结果,搜索用时 542 毫秒
21.
Dong-Liang Zhang Cheng-Long Deng Bin Xie Yu-Long Li Chuan Lai Wen-Yu Mou Lin-Xin He Xiao-Xue Bai Tao Li Jia-Xi Cao Jun Wang 《应用有机金属化学》2020,34(1):e5261
Six new O-alkyldithiophosphate nickel complexes with dcpf ligand, [(dcpf)Ni(S2P{O}OR)] (dcpf = 1,1′-bis (dicyclohexylphosphino)ferrocene, R = CH3 ( 1 ), CH3CH2 ( 2 ), Ph ( 3 ), 4-MeC6H4 ( 4 ), PhCH2 ( 5 ) and PhCH2CH2 ( 6 )), have been synthesized by the treatment of dcpf with ((RO)2PS2)2Ni in satisfactory yields. These complexes were characterized by elemental analysis, spectroscopy (FTIR, UV–vis, 1H, 13C, and 31P NMR), thermogravimetric analysis and single crystal X-ray diffraction. The nickel atom in 1 , 2 ·CH2Cl2, 3 ·CH2Cl2, 4 ·2CH2Cl2·THF, and 2( 5 )·hexane adopts a slightly distorted square-planar coordination environment finished by two phosphorus atoms of dcpf ligand and two sulfur atoms of O-alkyldithiophosphate ligand. Furthermore, the electrochemical properties for complexes 1 – 6 were also investigated by cyclic voltammetry. With the addition of 120 mM trifluoroacetic acid (TFA), the turnover frequency (TOF) values for 1 – 6 are estimated to be 1243.83, 1046.54, 1331.71, 2545.29, 1899.03, and 1191.37 s−1, with the overpotential (η) values of 0.62, 0.58, 0.71, 0.67, 0.60, and 0.56 V, respectively. The result of electrochemical studies indicates that all complexes can be used as efficient molecular eletrocatalysts for the reduction of protons to hydrogen in the presence of TFA in MeCN. 相似文献
22.
The chiral phosphine-containing palladacycle, synthesized easily from H-MOP, showed its high catalytic activity as well as asymmetric induction ability in ring-opening reaction of oxabicyclic alkenes with arylboronic acids, providing corresponding products in high yields and high ee. 相似文献
23.
Weifeng Yang Dong-Liang Peng Huolin Huang Zhengyun Wu 《Applied Surface Science》2009,255(11):5669-5673
Transparent conductive Al-doped zinc oxide (AZO) films with highly (0 0 2)-preferred orientation were deposited on quartz substrates at room temperature by RF magnetron sputtering. Optimization of deposition parameters was based on RF power, Ar pressure in the vacuum chamber, and distance between the target and substrate. The structural, electrical, and optical properties of the AZO thin films were investigated by X-ray diffraction, Hall measurement, and optical transmission spectroscopy. The 250 nm thickness AZO films with an electrical resistivity as low as 4.62 × 10−4 Ω cm and an average optical transmission of 93.7% in the visible range were obtained at RF power of 300 W, Ar flow rate of 30 sccm, and target distance of 7 cm. The optical bandgap depends on the deposition condition, and was in the range of 3.75-3.86 eV. These results make the possibility for light emitting diodes (LEDs) and solar cells with AZO films as transparent electrodes, especially using lift-off process to achieve the transparent electrode pattern transfer. 相似文献
24.
25.
中蜂囊状幼虫病毒结构蛋白预测与鉴定 总被引:2,自引:0,他引:2
摘要 本文采用RT-PCR方法和质谱分析对中蜂囊状幼虫病毒辽宁株(CSBV-LN)全基因组进行分子克隆、序列测定、分子生物学特性分析及其结构蛋白预测和鉴定。结果获得CSBV-LN全基因组序列长为8863个核苷酸,编码一个大的开放阅读框,其中包括178nt的5'非编码区的前导序列和142nt的3'非编码区,后面跟着一个poly(A)的尾巴。通过软件分析表明,CSBV-LN蛋白序列,类似于哺乳动物的小RNA病毒蛋白序列,预计存在VP1,VP2, VP3和VP4四个小的结构蛋白,系统分析进化分析表明CSBV,SBV和 DWV起源相同,推测CSBV有着类似DWV的结构蛋白序列5’-VP2 VP4 VP1 VP3-3。基于此,根据PAGE蛋白条带的大小,利用NetPicoRNA软件预测结构蛋白的裂解位点。在此基础上,对纯化后的CSBV进行SDS-PAGE,经SDS-PAGE分离到的4个蛋白进行质谱分析,结果鉴定出VP1、VP3和VP0三个蛋白。 相似文献
26.
In the present work, a series of [Fe80Ni20–O/SiO2]n multilayer thin films is fabricated using a reactive magnetron sputtering equipment. The thickness of SiO2 interlayer is fixed at 3 nm, while the thickness values of Fe80Ni20–O magnetic films range from 10 nm to 30 nm. All films present obvious in-plane uniaxial magnetic anisotropy. With increasing the Fe80Ni20–O layer thickness, the saturation magnetization increases slightly and the coercivity becomes larger due to the enlarged grain size, which could weaken the soft magnetic property. The results of high frequency magnetic permeability characterization show that films with thin magnetic layer are more suitable for practical applications. When the thickness of Fe80Ni20–O layer is 10 nm, the multilayer film exhibits the most comprehensive high-frequency magnetic property with a real permeability of 300 in gigahertz range. 相似文献
27.
Patil AS Mo DL Wang HY Mueller DS Anderson LL 《Angewandte Chemie (International ed. in English)》2012,51(31):7799-7803
Two in two: Dioxygenation of alkenyl boronic acids has been achieved with N-hydroxyphthalimide. The two-step process involves etherification of an alkenyl boronic acid with N-hydroxyphthalimide followed by a [3,3] rearrangement. The dioxygenated product can then be hydrolyzed to form either the corresponding α-hydroxy ketone or the α-benzoyloxy ketone. 相似文献
28.
29.
针对目前各油田聚合物驱转为水驱后,一般出现含水上升快,产油量大幅度下降的情况,以及油层内残余的大量聚合物未得到利用,而目前开发的残余聚合物再利用技术存在一些缺点,未得到推广应用,研制出新型复合处理剂JY-8。新型复合处理剂JY-8可与聚合物形成强度较高的凝胶体,将地层内残余聚合物有效地固定和絮凝,是很好的固定剂和絮凝剂,实现了“二剂合一”,达到对地层进行深部调剖、驱油的目的;同时,通过调整复合处理剂JY-8的加量等可调节成胶时间和凝胶强度。室内评价和现场应用表明,与以前的技术相比,复合处理剂JY-8可使油层内的残余聚合物利用率从原来的8%提高到15.65%,使聚合物驱后续水驱的采收率增加值从原来的10.33%提高到18.1%,在油井上起到了很好的增油、控水效果。 相似文献
30.
利用水热合成法制备了一种新型硅酸锡微孔化合物(Microporous stannosilicates), 通过XRD, SEM, 29Si MAS NMR, 119Sn MAS NMR, IR和TG等测试手段对该硅酸锡微孔化合物进行了表征. 结果表明, 该硅酸锡微孔化合物中的Sn物种为六配位形式, 而此化合物与硅锆矿石(Litvinskite)具有相同的拓扑结构. 相似文献