A new POM-templated metal–organic complex based on the flexible bis-pyridyl-bis-amide ligand

A new POM-templated metal?Corganic complex [Cu₄(L)₇(H₂O)₁₂(SiMo₁₂O₄₀)₂]·7H₂O [L?=?N,N??-bis(3-pyridinecarboxamide)-1,6-hexane], has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction analysis. The results reveal that the complex is a 2D metal?Corganic coordination framework of [Cu₄(L)₇(H₂O)₁₂] _n ⁸ⁿ⁺ cations containing decanuclear cycles with dimensions of ca. 17.55?×?57.42 ?, in which the SiMo₁₂O₄₀ ^4? anions act as non-coordinated anionic templates. The electrochemical properties of a bulk-modified carbon paste electrode of the complex have been investigated, and the results indicate that the complex-modified CPE has good electrocatalytic activity toward the reduction of nitrite in aqueous 1?M H₂SO₄ solution.     

Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide

Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.     

R&D of an LLRF control system for a 162.5 MHz radio frequency system

This paper describes a low level radio frequency control system that was developed by the Institute of Modern Physics Chinese Academy of Sciences, and will be used in Injector of the China-ADS project. The LLRF control system consists of an RF modulated front end, fast analog-to-digital converter (ADC) modules, and a digital signal processing board based on a field programmable gate array. The system has been tested on a room temperature cavity with 12-hr, and the results illustrate that the stability of amplitude and phase achieved ±0.32% and ±0.35 degrees, respectively.     

Analytical expressions for the correlation function of a hard sphere dimer fluid

A closed form expression is given for the correlation function of a hard sphere dimer fluid. A set of integral equations is obtained from Wertheim's multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation. Applying the Laplace transformation method to the integral equations and then solving the resulting equations algebraically, the Laplace transforms of the individual correlation functions are obtained. By the inverse Laplace transformation, the radial distribution function (RDF) is obtained in closed form out to 3D (D is the segment diameter). The analytical expression for the RDF of the hard dimer should be useful in developing the perturbation theory of dimer fluids.     

高压下稳态六方Ge2Sb2Te5结构、电子和光学性质的第一性原理研究

采用基于密度泛函理论的广义梯度近似方法研究了稳态六方petrov原子序列结构Ge2Sb2Te5的结构、电子和光学性质.计算所得的平衡态晶格参数与实验数据和先前的理论结果吻合很好.基态的能带结构和态密度表明了稳态六方petrov原子序列结构的Ge2Sb2Te5持有金属性.从压强影响下体积的变化趋势发现稳态六方Ge2Sb2Te5在17 GPa和34 GPa出现不稳定,暗示在此压强下的相变发生,这与2009年Krbal等人的实验结果相吻合.同时,还系统地研究了稳态六方petrov原子序列结构的Ge2Sb2Te5高压下的光学性质,得到了高压下介电函数、吸收率、光反射率、折射率、消光系数和电子能量损失谱在20 eV内的变化情况.     

有应急车辆影响的多车道交通流元胞自动机模型

在分析应急车辆对城市道路交通流影响的基础上, 引入让行状态参数、警笛影响区域和强制换道安全距离等特征变量, 修改换道规则, 建立了多车道元胞自动机模型, 并进行数值模拟. 结果表明, 车道数量和混合车辆比例系数在低密度范围内影响车辆速度及换道次数, 警笛影响区域参数改变了一定范围内车辆的换道次数, 应急车辆强制换道安全距离参数主要影响应急车辆的速度及换道次数.研究发现, 应急车辆对低密度交通流的扰动现象明显, 其与社会车辆相互作用参数的设置使得交通流元胞自动机模型更接近应急条件下实际交通运行. 关键词： 交通流 元胞自动机 应急车辆     

带有乘积型多目标权函数的调度谈判问题

在供应链环境下的生产活动中,各成员对所辖资源具有独立的支配权,因此需要合理的机制使得协同调度方案得以实施,以提高供应链整体的效率.研究由具备不同讨价还价能力的成员所组成的供应链,建立了以纳什讨价还价公理体系为基础的调度谈判模型.在装配系统中,讨论两供应商关于交付顺序的协商.为求取纳什谈判解,提出了一类新的以多目标乘积项作为目标函数的调度问题.对于单机型供应商,新问题的计算复杂性尚未确定,设计了一种多项式时间的启发式算法以求得近优解,并通过数值算例进行验证.该谈判模型为供应链中各成员提供了一种合理的调度协调机制.     

Heston随机波动率模型下的动态投资组合

应用随机最优控制方法对Heston随机波动率模型下的动态投资组合问题进行了研究,得到了幂效用和指数效用下最优投资策略的显示解,并给出一些数值计算结果分析了市场参数对最优投资策略的影响.     

完全3- 一致超图的一类填充问题和覆盖问题

设Γ 是一些单t- 一致超图的集合. 填充设计P_λ(t, Γ, v) (或覆盖设计C_λ(t, Γ, v)) 是一个二元有序组(X, B), 其中X 是完全t- 一致超图λK_v^(t) 的顶点集, B 是λK_v^(t) 的一些子超图的集合, 要求每个子超图都同构于Γ 中的某一个超图, 每个子超图称为是一个区组, 并且满足λK_v^(t) 中的每一条边至多(或至少) 含在B 的λ 个区组中. 给定参数t, v, λ, Γ, 填充设计P_λ(t, Γ, v) 的最大可能的区组数称为填充数, 记为d_λ(t, Γ, v); 覆盖设计C_λ(t, Γ, v) 的最小可能的区组数称为覆盖数, 记为C_λ(t, Γ, v). 本文将确定Γ 中仅含超图K₄⁽³⁾ + e 时的d_λ(t, Γ, v) 和C_λ(t, Γ, v) 的精确值.     

金属铜的晶体结构与热力学性质的第一性原理计算

基于第一性原理,利用密度泛函理论(DFT)和密度泛函的微扰理论(DFPT),以及广义梯度近似(GGA),研究了过渡金属Cu的晶体结构、能量、电子能带和态密度、声子的能带结构和态密度,以及其在298.15 K下的热容,体积模量,格林艾森参数和体胀系数等热力学函数并与实验值作了对比.通过分析Cu的晶格几何与能量之间的关系,讨论了金属Cu的固-液相变与晶格声子振动能量之间可能的内在联系,首次提出直接得到Cu熔化温度T_m的静力学方法,研究了熔化温度与压强的关系.计算结果与实验值符合较好,明显优于分子动力学模拟的结果.