回归正交试验设计在水飞蓟素提取工艺中的应用

本文针对水飞蓟素提取工艺利用二次回归正交设计 ,进行了五个变量的正交回归设计 ,获得了最佳的试验工艺参数值以及相应的数学模型     

Analyzing dynamic interaction of impulse-loaded strips

The paper considers the dynamic process of contact interaction of infinite impulse-loaded strips arranged with a gap. The behavior of the strips is described by linear elastic dynamics equations. The contact problem is solved by the collocation method. The process of impact of two and three strips is analyzed. The calculation results are compared with data obtained by using the finite-element method.     

反相高效液相色谱法测定棒柄花中反式-4-(1-丙烯基)苯酚-β-D-吡喃葡萄糖苷

用反相高效液相色谱法建立棒柄花中反式-4-(1-丙烯基)苯酚-β-D-吡喃葡萄糖苷的含量测定方法,并测定其含量。色谱柱Reliasil-C18(250 mm×4.6 mm,5μm),流动相乙腈-水(体积比22∶78),流速1.0mL/m in,检测波长257 nm。结果待测组分在0.080 4~0.281 4μg范围内与峰面积线性关系良好,相关系数为0.999 5,平均加标回收率为98%,RSD为1.8%(n=6)。本法简便、快速、重复性好、结果准确可靠。     

波长色散X射线荧光光谱法测定钴精矿中钴、铜和锰含量

采用高纯氧化物经四硼酸锂和偏硼酸锂熔融制备人工标准样品,以氧化镱为内标,制作校准曲线,建立了波长色散型X射线荧光光谱法测定钴精矿中钴、铜、锰元素的分析方法。重点研究了混合熔剂、试样稀释比、氧化剂和内标选择、方法检出限、方法准确度和精密度等,结果表明,各元素校准曲线线性范围宽,相关系数均大于0.999, 钴、铜、锰元素检出限分别达到0.002%、0.001%和0.001%,测试准确度和精密度可靠,方法满足行业检测需求。     

Experimental Solution of the Local Field Problem in Uniaxial Liquid Crystals†

A method of experimental determination of the Lorentz-factor tensor in uniaxial liquid crystals is suggested. The specific features of the local field tensor of the light wave in a nematic liquid crystal with low optical anisotropy have been investigated experimentally. Anisotropy of the local field and Lorentz-factor tensors has been found to decrease with the decreasing optical and molecular-optical anisotropies. These results appear to contradict the existing polarization theories of liquid crystals. The local field problem in cholesteric liquid crystals has been considered. A new approach to the local field problem in uniaxial liquid crystals with arbitrary optical anisotropy is developed and the experimental results are explained.     

Synthesis and Crystal Structure of Isosteviol Derivatives

Isosteviol (ent-16-ketobeyeran-19-oic acid, I) is a tetracyclic diterpenoid with a beyerane skeleton obtained by acid hydrolysis of stevioside.1 Several tetracyclic diterpenoids, specially the kaurenes, have important biological activities. Recent studies on the microbial transformation of isosteviol have revealed that it is metabolized by Cunninghamella bainieri, Actinoplanes sp., Mucor recurvatus, and Cunninghamella blackesleeana to yield five new metabolites.2 The hydroxylation pattern of these bioactive compounds may influence their binding on to the receptors, as was proposed for the Rabdosia diterpenoids. Therefore, the introduction of hydroxyl groups or unsaturated bonds in saturated and non-hydroxylated diterpenoids, like isosteviol, may enhance existing properties or lead to new biological activities. Although some beyeranes have been subjected to biotransformations by fungi,4 there are few report in the literature related the chemical transformation of Isosteviol. In the present study, we try to develop the chemical transformation of isosteviol and other beyeranes in order to obtaining some bioactive compounds with beyerane skeleton. Seven isosteviol derivatives, Ⅱ-Ⅷ, were therefore synthesized and characterized. The X-ray crystal strcture of H(R = H) was also determined.     

不同基底对TiO2和SiO2薄膜的光学性能的影响

采用溶胶-凝胶法分别在K9玻璃、单晶硅和石英玻璃基底上制备了纳米TiO₂和SiO₂薄膜。利用SEM、UV-Vis及反射式椭圆偏振光谱仪对薄膜的微观结构及光学特性进行了表征和分析。结果表明:3种基底中, 单晶硅基底上TiO₂和SiO₂薄膜折射率最大;在非晶态K9玻璃和石英玻璃基底上TiO₂薄膜折射率和透光率差异较大;SiO₂薄膜在非晶态基底上折射率、透光率相近;3种基底上薄膜的折射率和消光系数都有随波长增大而减小的趋势, 同时Cauchy模型能较好的描述单晶硅基底上两种薄膜在400~800 nm波段的光学性能。     

一种分析自由电子激光场的新量子方法

将固体理论中的LLP变换用于研究自由电子激光场的量了态,并求得了小信号增益,这种新方法简捷且有助于深入地探讨自由电子激光场的量子特性. 关键词：     

蛙峡核的视野区域对应投射和双眼反应

本文用玻璃微电极从黑斑蛙(Rana nigromaculata)左峡核细胞外记录了125个单位的视觉反应,并用钴染色法标记出101个电极尖端位置,以便重建峡核内的视野图。在所记录的单位中,80％对静止光点显示给光(ON)-撤光(OFF)反应,许多单位对通过其感受域的黑、白目标的运动有方向选择性。所有钴标记点都在核内,表明峡核本身是蛙视觉系统的一个局限部分。在峡核内有一个视野投射圈。整个对侧半视野和同侧半视野的鼻侧40°呈区域对应地投射到峡核上。核内的无细胞带是对侧半视野与同侧半视野的分界线,它的背侧是对侧视野代表区。上视野投射到核的嘴半部、尾半部的中央和内腹部分。下视野的代表在尾半部的背部和外侧部。在峡核里观察到15个双眼单位,其中13个主要被对侧眼兴奋,2个几乎同等地被两只单眼兴奋。标记成功的14个双眼单位主要位于峡核嘴半部的髓质内。     

Preconcentration of microamounts of elements in natural waters with 8-mercaptoquinoline and bis(8-quinolyl) disulphide for their atomic-absorption determination

A method has been developed for the group concentration of microamounts of metals (Fe, Co, Ni, Mn, Cu, Zn, Cd, Hg, Pb, Bi, Sb, Mo, W, V, Cr, Ga, In, Sn, Ag, Au, Pd, Pt) in the form of their 8-mercaptoquinolinates co-precipitated on bis(8-quinolyl) disulphide as collector, the latter being an oxidation product of 8-mercaptoquinoline. The collector is formed during the co-precipitation process, which is the reason for its high co-precipitating power. The elements thus concentrated are determined by atomic-absorption spectrometry after dissolution of the precipitate in dilute nitric acid.