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71.
A. Das D. Mukhopadhyay S. Adhikari M. Baer 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,65(3):373-381
In this article are presented the first ever derived single-valued
diabatic potentials for the reactive H2 + F system based on a
rigorous study of the conical intersection (ci) and
Born-Oppenheimer non-adiabatic coupling terms (BO NACTs). This study revealed the
existence of a Jahn-Teller (1, 2) ci located at a point on the collinear
axis and a Renner-Teller (2, 3) ci along this axis. The diabatic
potentials were calculated employing the rigorous adiabatic-to-diabatic transformation
(ADT) angles (also known as mixing angles) which possess integer Berry
phases along any closed contour at the region of interest in configuration space. The ADT
angles were calculated employing BO NACTs and line integrals. 相似文献
72.
Sharma VK Mitra S Kumar A Yusuf SM Juranyi F Mukhopadhyay R 《J Phys Condens Matter》2011,23(44):446002
Here we report the dynamical behaviour of water in Prussian blue analogue (PBA) Cu(0.75)Mn(0.75)[Fe(CN)(6)]·7H(2)O molecular magnet in the temperature range 260-360 K as studied using the quasielastic neutron scattering technique. While significant quasielastic broadening is observed in the hydrated sample, no broadening was observed in the dehydrated one. Data analysis showed that the observed quasielastic broadening in Cu(0.75)Mn(0.75)[Fe(CN)(6)]·7H(2)O corresponds to the dynamics of the non-coordinated water molecules at the 32f site and the coordinated water molecules at the 24e site, existing in the cavities created by the absence of Fe(CN)(6) units. The non-coordinated water molecules at 8c interstitial sites do not contribute to the broadening, suggesting that they are immobile at least within the time window of the spectrometer used. Behaviour of the elastic incoherent structure factor is consistent with the model where the water molecules undergo translational diffusion localized within the cavity of 5.1 ?. While all the non-coordinated water molecules at the 32f site are dynamic over the entire range of temperatures, the coordinated ones at the 24e site become progressively dynamic with temperature. The water molecules were found to undergo hindered (~1.16 × 10(-5) cm(2) s(-1) at 300 K) diffusion compared to bulk water and the diffusivity followed Arrhenius behaviour within the measured temperature range with an activation energy of 1.26 kcal mol(-1). 相似文献
73.
Partha Mukhopadhyay 《Annales Henri Poincare》2014,15(5):937-963
We rewrite the bosonic worldsheet theory in curved background in a language where it describes a single particle moving in an infinite-dimensional curved spacetime. This language is developed at a formal level without regularizing the infinite-dimensional traces. Then, we adopt DeWitt’s (Phys Rev 85:653, 1952) coordinate-independent formulation of quantum mechanics in the present context. This procedure enables us to define coordinate invariant quantum analogue of classical Virasoro generators, which we call DeWitt–Virasoro generators. This framework also enables us to calculate the invariant matrix elements of an arbitrary operator constructed out of the DeWitt–Virasoro generators between two arbitrary scalar states. Using these tools, we further calculate the DeWitt–Virasoro algebra in spin-zero representation. The result is given by the Witt algebra with additional anomalous terms that vanish for Ricci-flat backgrounds. Further analysis need to be performed to precisely relate this with the beta function computation of Friedan and others. Finally, we explain how this analysis improves the understanding of showing conformal invariance for certain pp-wave that has been recently discussed using hamiltonian framework. 相似文献
74.
Different all-optical logic operations, memory blocks etc. are developed using the inherent parallelism of optics. In any digital communication and computation system, the role of serial to parallel and parallel to serial data conversion are very much essential for making a data convenient for transition.Here in this paper, the authors propose a new scheme for developing an all-optical parallel to serial data conversion system by using optical J-K Flip-Flops and some logic gates based on optical non-linear switches. The uses of such switches are widely established in the area of optical parallel computation.This process can be extend for developing some all-optical digital devices like shift register, optical pulse counters etc. The proposed scheme deals with the best use of high parallelism of the optics, so the super-fast processing speed can be achieved. 相似文献
75.
76.
Goutam Mukhopadhyay Jasmina Khanam Arunabha Nanda Arindam Basu Sarkar 《Chromatographia》2010,71(7-8):699-702
A simple, sensitive and precise reverse phase liquid chromatographic method has been developed and validated for quantification of bovine serum albumin (BSA), α-lactalbumin (α-La) and β–lactoglobulin (β-Lg) that are removed from whey waste by foam fractionation method. The data is reproducible over a wide concentration range. This optimized method allowed analysis of BSA, α-La, β-Lg in a mixture within 5 min and could be applied to the analysis of a variety of commercial and laboratory whey products within a short time. 相似文献
77.
78.
79.
Prashant Dubey Devarajan Muthukumaran Subhashis Dash Rupa Mukhopadhyay Sabyasachi Sarkar 《Pramana》2005,65(4):681-697
Carbon nanotubes (CNT) has been synthesized by pyrolysing mustard oil using an oil lamp. It was made water-soluble (wsCNT)
through oxidative treatment by dilute nitric acid and was characterized by SEM, AFM, XRD, Raman and FTIR spectroscopy. The
synthesized wsCNT showed the presence of several junctions and defects in it. The presence of curved graphene structure (sp2) with frequent sp3 hybridized carbon is found to be responsible for the observed defects. These defects along with the presence of di- and tri-podal
junctions showed interesting magnetic properties of carbon radicals formed by spin frustration. This trapped carbon radical
showed ESR signal in aqueous solution and was very stable even under drastic treatment by strong oxidizing or reducing agents.
Oxidative acid treatment of CNT introduced several carboxylic acid group functionalities in wsCNT along with the nicking of
the CNT at different lengths with varied molecular weight. To evaluate molecular weights of these wsCNTs, an innovative method
like gel electrophoresis using high molecular weight DNA as marker was introduced. 相似文献
80.
This paper concerns with the investigation of laminar flow separation and its consequences in a tube over a smooth expansion under the axi-symmetric approximations. A co-ordinate stretching has been made to map the expanded tube into a straight tube. The two-dimensional unsteady Navier-Stokes equations are solved approximately by using primitive variables in staggered grid. A thorough quantitative analysis is performed through numerical simulations of the desired quantities such as wall shear stress, axial velocity, pressure distribution etc. These quantities are presented graphically and their consequences in the flow field are analysed in details. The dependence of the flow field on the physical parameter like expansion height d and on the Reynolds number has been investigated in details. It is interesting to note that the peak value of wall shear stress decreases with increasing height of expansion and also with the increasing Reynolds number. 相似文献