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991.
为了获取强激光驱动产生的X射线光源焦斑尺寸和空间分辨率,设计了刃边及双网格方法,其中刃边厚度为0.2μm,双网格分别为400目铜网格和394lp/cm的镍网,利用X射线CCD作为探测元件。Ti宝石激光在能量1J、脉宽40fs、频率10 Hz、激光功率密度约为4.4×1018 W/cm2的条件下,重复频率加载圆盘Cu靶。在中国工程物理研究院25TW激光装置上首次获得了X射线的焦斑及网格图像,并推算了该装置的X射线焦斑尺寸为43μm,而网格空间分辨力为34μm。结果表明该刃边及双网格方法适合强激光驱动产生的X射线焦斑尺寸测定。 相似文献
992.
曹柱荣 丁永坤 董建军 邓博 黎宇坤 穆宝忠 伊圣振 吴俊峰 陈韬 张继彦 杨志文 袁铮 李晋 胡昕 杨正华 缪文勇 蒋炜 袁永腾 黄天晅 陈伯伦 陈家斌 詹夏雨 张海鹰 康洞国 谷建法 叶文华 王占山 刘慎业 江少恩 张保汉 张维岩 《强激光与粒子束》2015,27(3):032013-122
在激光间接驱动惯性约束聚变(ICF)领域中,获得具有极高空间分辨率(优于5μm)的X射线辐射图像,是研究烧蚀不稳定性、内爆流线等关键物理过程的数据基础。基于掠入射反射式成像原理的Kirkpatrick-Baez(KB)显微成像系统作为一种具有高空间分辨率和集光效率的X射线显微诊断设备,目前已成为国际ICF装置的X射线关键诊断设备。在神光Ⅱ和神光Ⅲ原型装置条件上开展了KB诊断技术及设备的研究,在KB系统的光学设计、光学元件和物镜与系统装调技术等方面取得了许多重要进展,研制了大视场KB、多色KB等高分辨率X射线显微成像系统。这些系统已应用于我国的ICF内爆芯部发光和流线测量、流体不稳定增长测量等实验中,为关键物理量的测量提供了高空间分辨率的清晰图像。 相似文献
993.
Mu. Naushad Z. A. ALOthman Md. Rabiul Awual Mohammad Mezbaul Alam G. E. Eldesoky 《Ionics》2015,21(8):2237-2245
In the current study, Ti(IV) iodovanadate cation exchanger (TIV) was synthesized and applied for the removal of Pb2+ and Hg2+ metal ions from the aqueous medium. The adsorption studies were performed by the batch techniques and adsorption parameters viz. contact time, pH, initial metal ion concentration, and temperature were also investigated. The optimum adsorption of Pb2+ (95 %) and Hg2+ (65 %) were observed at pH 6. The pseudo-second order equation represented the adsorption kinetics with high correlation coefficient. Langmuir model showed the best fitting to the isotherm equilibrium data, with a maximum adsorption capacity of 18.8 mg g?1 for Pb2+ and 17.2 mg g?1 for Hg2+. Furthermore, thermodynamic factors, i.e., ΔG, ΔH, and ΔS, indicated that adsorption of Pb2+ and Hg2+ onto TIV were spontaneous, endothermic, and feasible in the temperature range of 293–323 K. 相似文献
994.
Ionics - Carbon/manganese dioxide (C/MnO2) hybrid nanotubes were prepared by the successive deposition of carbon and manganese dioxide using natural halloysite nanotubes as template. The... 相似文献
995.
Xiang Gao Bo Wu Wen‐Xue Huang Mu‐Wang Chen Yong‐Gui Zhou 《Angewandte Chemie (International ed. in English)》2015,54(41):11956-11960
A palladium‐catalyzed enantioselective C H functionalization of indoles was achieved with an axially chiral 2,2′‐bipyridine ligand, thus providing the desired indol‐3‐acetate derivatives with up to 98 % ee. Moreover, the reaction protocol was also effective for asymmetric O H insertion reaction of phenols using α‐aryl‐α‐diazoacetates. This represents the first successful application of bipyridine ligands with axial chirality in palladium‐catalyzed carbene migratory insertion reactions. 相似文献
996.
A new thiacalix[4]arene phenothiazine derivative(2) based on a thiacalix[4]crown with a 1,3-alternate conformation has been synthesized and characterized. In THF-water mixture, Compound 2 exhibits a strong fluorescence emission, with a large Stokes shift(λex/em = 357 nm/505 nm, Δλ = 148 nm), which helps to avoid interference in excitation and emission. For the metal ions tested, the fluorescence of Compound 2 was quenched only by Fe3+ and Cr3+ ions. Evidence for the hydrolysis reaction promoted by the metal ions is given by X-ray crystallography, mass spectra(MS), infrared(IR) spectra, and fluorescence spectroscopy data. 相似文献
997.
Synthesis and Photophysics of BF2‐Rigidified Partially Closed Chain Bromotetrapyrroles: Near Infrared Emitters and Photosensitizers
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En Dai Weidong Pang Prof. Dr. Xian‐Fu Zhang Xudong Yang Ting Jiang Ping Zhang Changjiang Yu Prof. Dr. Erhong Hao Yun Wei Xiaolong Mu Prof. Dr. Lijuan Jiao 《化学:亚洲杂志》2015,10(6):1327-1334
We report the synthesis, crystallographic, optical, and triplet and singlet oxygen generation properties of a series of BF2‐rigidified partially closed chain bromotetrapyrroles as near infrared emitters and photosensitizers. These novel dyes were efficiently synthesized from a nucleophilic substitution reaction between pyrroles and the 3,5‐bromo‐substituents on the tetra‐ and hexabromoBODIPYs and absorb in the near‐infrared region (681–754 nm) with high molar extinction coefficients. Their fluorescent emission (708–818 nm) and singlet oxygen generation properties are significantly affected by alkyl substitutions on the two uncoordinated pyrrole units of these dyes and the polarity of solvents. Among them, dyes 4 ca and 4 da show good singlet oxygen generation efficiency and good NIR fluorescence emission (fluorescence quantum yields of 0.14–0.43 in different solvents studied). 相似文献
998.
999.
Mu Gu Pan Gao Xiao‐Lin Liu Shi‐Ming Huang Bo Liu Chen Ni Rong‐Kun Xu Jia‐Min Ning 《Crystal Research and Technology》2010,45(4):365-370
The fundamental role of solubility and supersaturation of solute for crystal growth from solution has been widely realized. In order to optimize the process of CuI crystal growth by CuI·HI decomplexation in HI acid, the solubility and supersaturation curves of CuI in HI‐H2O mixed solvent were measured, and then a modified concentration programming scheme was designed, which could grow high quality CuI single crystals of 2.5 mm on edge successfully. In this scheme, the concentration distribution of CuI·HI complex and HI acid in silica gel along their diffused direction were measured with spectrophotometer, and the evolution of CuI·HI complex supersaturation ratio was analysed. It was found that the excess CuI·HI complex concentration would lead to the high supersaturation ratio and the formation CuI dendrites. The condition for regular CuI single crystal growth in silica gel was measured as follow: when the crystal nuclei appears, the CuI·HI complex concentration in HI‐H2O solvent should be kept in the range of 0.033–0.050 mol/L and its corresponding supersaturation ratio is 1.24–1.45, and then they should be respectively declined to a range of 0.025–0.033 mol/L and 1.14–1.26 at the stage of crystal growth. The results may provide a useful clue for further improvement of the experimental scheme. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
1000.
Gang Chen Ying Tang Qun-Zheng Zhang Ya Wu Shun-Zhen Mu 《Journal of chemical crystallography》2010,40(4):369-372