希夫碱过渡金属配合物的合成及其荧光性能

合成了3,5-二氯水杨醛缩邻苯二胺配体(H2L);H2L与M(NO3)2(M=Cu,Ni,Zn)反应,合成了3种希夫碱过渡金属配合物ML。UV,1HNMR,IR和元素分析研究表明ML为四配位。用荧光激发光谱和发射光谱研究了H2L和ML的光物理性能,结果表明,H2L具有较强的荧光;ZnL具有较强的荧光和良好的热稳定性(分解温度达424.2℃)。     

新型单取代苯磺酰内脲衍生物的合成及表征

以2-氯-5-氯甲基吡啶和不同取代基的苯磺酰氯为原料, 合成了7个新型的苯磺酰内脲类衍生物, 并用FT-IR, 1H NMR, 13C NMR, 元素分析对其结构进行了表征, 同时对合成目标化合物的反应条件进行了探究.     

Relationship between the Biodegradability and Structure of Polycyclic Aromatic Hydrocarbons

21 Physicochemical and quantum chemical parameters of 17 kinds of polycyclic aromatic hydrocarbons were calculated by using semi-empirical MOPAC AM1 method. By means of Partial Least Squares （PLS）, quantitative structure-biodegradation relationship （QSBR） study was performed with the logarithm of specific biodegradation rates （logKb）. The optimal model was obtained, and the result showed that the first-order molecular connectivity index （^1X）, the energy of the lowest unoccupied molecular orbital （Elumo）, logarithm of n-octyl alcohol/water partition coefficient （logP） and torsion energy （Et） are the dominant factors governing the biodegradability of polyeyelie aromatic hydrocarbons, and the effect of second-order valence molecular connectivity index （^2X^V）, the third-order valence molecular connectivity index （^3X^V） and molar refractivity （Rm） should not be ignored.     

MCM-41分子筛固载腈钯配合物的合成及其催化Heck偶联反应的性能

合成了MCM-41分子筛固载腈钯(0,Ⅱ)配合物催化剂,并利用XPS、FT-Raman等技术对催化剂进行了表征.研究表明,MCM-41分子筛载体上的-CN基可通过叁键上的π电子对与Pd发生弱配位.MCM-(CH2)3CN·Pd(O)具有良好的催化性能和稳定性,在反应温度70℃、DMF-Et3N的存在下,对催化各种碘代芳烃与共轭烯烃的Heck偶联反应均较有效,高产率且高立体选择地生成了一系列取代的反式产物,产物分离收率达到84%以上.     

Characteristics of a Novel Water Plasma Torch

Relying on heat generated by plasma arc heating liquid water into steam as a swirl gas, a water plasma torch has the distinctive steam generation structure, which has various applications such as in the treatment of organic waste and hydrogen production for fuel cells in future vehicles. The operational features of the water plasma torch and water phase change process in the discharge chamber are investigated based on the temporal evolution of the voltage and current. The optical emission spectrum measurement shows that the water molecule in the plasma is decomposed into 14, OH and O radicals. As the electrodes do not require water-cooling, the thermal efficiency of the torch is very high, which is confirmed by analytical calculation and experimental measurement.     

Research on the response model of microbolometer

There are certain limitations in the application of uncooled focal plane array (FPA) detector due to the lack of an effective response model which reliably transforms the target temperature to analog output voltage. This paper establishes the response model of microbolometer through researching the detection theory of microbolometer and the heat balance equation under the condition of the pulsed voltage bias. In the establishing process, we simplified the heat balance equation to acquire a simple answer. The experimental data show that, in the temperature dynamic range of 30 K, the biggest tolerance between the model data and the experiment data is 0.2 K; while in the temperature dynamic range of 100 K, it is 1 K. This model can reflect the real response of the microbolometer with only small differences which are acceptable in engineering applications.     

峰值/谷值电流型控制开关DC-DC变换器的对称动力学现象分析

峰值电流和谷值电流控制开关DC-DC变换器在较宽的电路参数范围内具有对称动力学现象.文中建立了峰值电流和谷值电流控制buck,boost,及buck-boost变换器的统一离散迭代映射模型,并导出了统一的分段光滑迭代映射方程及特征值方程,通过数值仿真得到了占空比变化时的正、逆分岔图和Lyapunov指数谱.研究结果表明,峰值/谷值电流型控制开关变换器的分岔图和Lyapunov指数具有关于点或轴对称的现象.时域仿真结果验证了数值仿真结果,并进一步表明,随着占空比的变化,峰值/谷值电流型控制开关变换器具有对称动力学现象、对称动力学现象和非对称动力学现象共存、非对称动力学现象.     

Er~(3+)∶YVO_4的频率上转换动力学分析

测量并分析了980nm抽运下Er3+∶YVO4晶体的上转换荧光,建立了描述Er3+离子跃迁的速率方程。通过求解速率方程并拟合1550nm,980nm和550nm的荧光衰减实验曲线,得到了4I13/2+4I13/2→4I15/2+4I9/2,4I11/2+4I11/2→4I15/2+4F7/2的频率上转换系数C22=9.221×10-17cm3s-1,C33=7.545×10-17cm3s-1。通过测量980nm抽运下的550nm荧光衰减谱,得到了4S3/2能级的主要上转换机制是以激发态吸收为主。     

需求不确定性对闭环供应链系统决策的影响分析

在由一个制造商与一个销售商组成的闭环供应链系统中,构建了市场需求不确定环境下废旧产品回收率为外生变量和零售商决策变量两种情形的闭环供应链系统决策模型,并通过数值仿真得到了各模型供应链成员的最优定价和订货策略以及最终利润,进一步分析了两种情形下市场需求不确定性对零售商、制造商决策行为及利润的影响,最后对两种情形进行了对比分析.     

基于运动补偿的红外图像噪音时域IIR滤波算法

从模式识别的角度出发将图像分为运动区域和非运动区域,采用基于噪音分布模型的运动检测技术与基于概率松弛法的运动区域标号技术相结合对这两种区域进行具体划分,对分类后的图像采用时域IIR滤波,不同区域采用不同的影响因子,以期达到最终的运动补偿.仿真结果表明该方法有效抑制了噪音,同时并未引起明显的运动模糊,图像的视觉效果得到了极大改善.