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采用传统固相法制备Ba(Co1/3Nb2/3)O3微波介质陶瓷。研究了预烧温度对其物相组成、显微结构、烧结性能、微波介电性能的影响。结果表明:在不同预烧温度下制备的陶瓷样品主晶相为复合钙钛矿结构的Ba3CoNb2O9,900℃、1000℃有微量Ba3Nb5O15生成。最佳预烧温度为1100℃,在1380℃烧结4 h时,εr=31.8,Q×f=60164GHz,τf=-15×10-6/℃。合适的预烧温度能有效抑制第二相的生成,提升材料致密度,促使主晶相B位有序排列,进而降低介电损耗。 相似文献
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We calculate jet productions in p+Au collisions at the RHIC at next-to-leading order with perturbative QCD. Inclusive jet transverse energy spectrum, dijet invariant mass spectrum, dijet angular distribution, and corresponding nuclear modification factors for the three observables in p+Au collisions at √s=200 GeV are given, where the initial-state cold nuclear matter (CNM) effects are included by taking advantage of four parametrization sets of nuclear parton distribution functions (nPDFs) - EPS, nCTEQ, HKN and DS. We demonstrate that inclusive jet transverse energy (ET) spectrum, dijet invariant mass (MJJ) spectrum with all 4 nPDFs are increased at low ET or MJJ, whereas at high ET or MJJ large deviation of results with different nPDFs is observed. It is found that the dijet angular distributions in p+Au collisions do not vary relative to those in p+p collisions for all 4 nPDFs. 相似文献
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Effects of the structural order of canthaxanthin on the Raman scattering cross section in various solvents: A study by Raman spectroscopy and ab initio calculation 下载免费PDF全文
In this work,we measure the Raman scattering cross sections(RSCSs) of the carbon-carbon(CC) stretching vibrational modes of canthaxanthin in benzene,acetone,n-heptane,cyclohexane,and m-xylene.It is found that the absolute RSCS of CC stretching mode of canthaxanthin reaches a value of 10 24 cm 2 ·molecule 1 ·sr 1 at 8×10 5 M,which is 6 orders of magnitude larger than general RSCS(10 30 cm 2 ·molecule 1 ·sr 1),and the RSCSs of canthaxanthin in various solvents are very different due to the hydrogen bond.A theoretical interpretation of the magnetic experimental results is given,which is introduced in a qualitative nonlinear model of coherent weakly damped electron-lattice vibration in the structural order of polyene chains.In addition,the optimal structure and the bond length alternation(BLA) parameter of canthaxanthin are calculated using quantum chemistry calculation(at the b3lyp/6-31g(d,p) level of theory).The theoretical calculations are in good agreement with the experimental results.Furthermore,the combination of Raman spectroscopy and the quantum chemistry calculation study would be a quite suitable method of studying the structures and the properties of the π-conjugated systems. 相似文献
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The effect of an anti-hydrogen bond on Fermi resonance: A Raman spectroscopic study of the Fermi doublet v1-v12 of liquid pyridine 下载免费PDF全文
The effects of an anti-hydrogen bond on the v1 v12 Fermi resonance (FR) of pyridine are experimentally investigated by using Raman scattering spectroscopy. Three systems, pyridine/water, pyridine/formamide, and pyridine/carbon tetrachloride, provide varying degrees of strength for the diluent-pyridine anti-hydrogen bond complex. Water forms a stronger anti-hydrogen bond with pyridine than with formamide, and in the case of adding non-polar solvent carbon tetrachloride, which is neither a hydrogen bond donor nor an acceptor and incapable of forming a hydrogen bond with pyridine, the intermolecular distance of pyridine will increase and the interaction of pyridine molecules will reduce. The dilution studies are performed on the three systems. Comparing with the values of the Fermi coupling coefficient W of the ring breathing mode v1 and triangle mode v12 of pyridine at different volume concentrations, which are calculated according to the Bertran equations, in three systems, we find that the solution with the strongest anti-hydrogen bond, water, shows the fastest change in the v1-v12 Fermi coupling coefficient W with the volume concentration varying, followed by the formamide and carbon tetrachloride solutions. These results suggest that the stronger anti-hydrogen bond-forming effect will cause a greater reduction in the strength of the v1-v12 FR of pyridine. According to the mechanism of the formation of an anti-hydrogen bond in the complexes and the FR theory, a qualitative explanation for the anti-hydrogen bond effect in reducing the strength of the v1 - v12 FR of pyridine is given. 相似文献
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两株微藻的分离鉴定及Fe~(3+)对其生长和脂质积累的影响 总被引:4,自引:0,他引:4
自青岛汇泉湾海水样品中分离培养两株微藻HQW01和HQW02,经形态和系统发育分析,两株微藻分别鉴定为三角褐指藻(Phaeodactylum tricornutum)和球等鞭金藻(Isocrydid galbana).采用吸光度和尼罗红荧光染色法研究了Fe3+对这两株微藻生长和脂质积累的影响.结果表明,三角褐指藻在Fe3+浓度为1×10-4mol/L培养时,生长速度最快且脂质含量最高,达到47.3%,是不加Fe3+培养时的4.2倍;Fe3+浓度为1×10-5mol/L时,球等鞭金藻具有最大生长速率,同时脂质含量提高至41.9%,是不加Fe3+培养时的2.8倍.这两种高脂质含量的微藻有望作为生物柴油的生产原料. 相似文献
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