Highly Selective Salicylate Membrane Electrode Based on N,N′-(Aminoethyl)ethylenediamide Bis(2-salicylideneimine)Binuclear Copper(Ⅱ) Complex as Neutral Carrier

A new ion selective electrode for salicylate based on N,N'-(aminoethyl)ethylenediamide bis(2-salicylideneimine)binuclear copper(Ⅱ)complex[Cu(Ⅱ)_2-AEBS]as an ionophore was developed.The electrode has a linear range from1.0×10~(-1) to 5.0×10~(-7) mol·L~(-1) with a near-Nernstian slope of(-55±1)mV/decade and a detection limit of 2.0×10~(-7) mol·L~(-1) in phosphorate buffer solution of pH 5.0 at 25℃.It shows good selectivity for Sal~- and displaysanti-Hofmeister selectivity seoquence:Sal~->SCN~->ClO_4~->I~->NO_2~->Br~->NO_3~->CI~->SO_3~(2-)>SO_4~(2-)The proposed sensor based on binuclear copper(Ⅱ)complex has a fast response time of 5-10 s and can be used forat least 2 months without any major deviation.The response mechanism is discussed in view of the alternating cur-rent(AC) impedance technique and the UV-vis spectroscopy technique.The effect of the electrode membranecompositions and the experimental conditions were studied.The electrode has been successfully used for the deter-mination of salicylate ion in drug pharmaceutical preparations.     

Parallel signaling-based fast restoration scheme in distributed optical networks

The fast parallel restoration （FPR） scheme is proposed to achieve the fast setup of restoration label switched path （LSP） in the distributed optical networks. The scheme is derived by dividing the whole restoration LSP into several segments of sub-LSP and triggering each sub-LSP along the new route to finish the signaling procedure concurrently, and subsequently merging all sub-LSPs into a whole LSP. The theoretical analysis and simulation results show that the FPR scheme outperforms the other two typical restoration schemes in terms of connection setup time.     

第二届全国高校计算机辅助化学教学软件交流会

来自全国41所高等院校的79名代表,云集在苏州大学化学楼内的微机旁,紧张而又认真地审阅着各校最新推出的五十多面微机辅教软件,会内会外他们都在坦率而又真诚地交流着编制软件的经验,散会时他们还在忙着相互复制一些软件(初稿)以便进一步的切磋。     

自我检查题

(一)初中部分(100分钟作完) 1、下列十条结论,你如果认为正确,就在后面的( )内打一“√”;如果不正确,就打个“×”,再在下面说明理由。或者加以更正。 (1)任何有理数的平方都是正数。( ) (2)任何实数的绝对值都大于0。( ) (3)((1-a)~2)~(1/2)=1-a ( )     

盐酸胍诱导的猪血红蛋白分子解离过程中各亚基的分布

以内源荧光光谱、荧光相图、高效凝胶排阻色谱和相对释氧曲线等方法,研究了盐酸胍诱导的猪血红蛋白分子解离过程中各亚基的分布状况.实验发现,当溶液中盐酸胍浓度小于3.5 mol/L时,猪血红蛋白分子仅仅以四聚体形式存在;而当溶液中盐酸胍浓度达到和超过3.5 mol/L时,部分猪血红蛋白分子开始从四聚体解离成二聚体和单体,并且...     

覆冰输电塔线体系风载荷影响因素分析

输电塔线体系属于强非线性耦联系统,具有高柔度、大跨度、风敏感等特点,对其在风载荷作用下的非线性静态响应分析研究在结构设计和实际线路中具有重要的理论和工程价值.建立了以猫头直线塔为基础的"三线两塔"输电塔线体系耦合有限元模型,考虑结构自重载荷、覆冰载荷、导线张力和风载荷的组合作用下对输电塔线体系进行非线性静力学分析,重点研究了风向角、覆冰风攻角和风速对输电塔线体系静态承载能力的影响,归纳总结了相应的影响规律.     

Preliminary Frequency Comparison of Two 40^Ca^＋ Optical Frequency Standards

Frequency comparison is one of the most efficient ways to evaluate the performance of a frequency standard. Based on the pre-existing 40^Ca＋ optical frequency standard, we set up the second 40^Ca^＋ optical frequency standard, which has been improved in the materials and structure of ion traps for better control of the magnetic field. After the compensation, the residual magnetic field at the position of the ion is adjusted to be～500nT with a long time jitter of～10nT, which is better than the pre-existing 40^Ca^＋ optical frequency standard. We realize the ＇4-point-closed-loop locking＇ on the second 40^Ca＋ optical frequency standard after a series of preparatory works. Through half an hour of measurement time, the two frequency standards exhibited a stability of 2.1 × 10^-13.τ^1/2 and a relative frequency difference of 1.5 （2.9）Hz.     

枯草杆菌α-淀粉酶在一些色谱体系中的热力学和超热力学研究

通过测定不同温度范围的热力学平衡常数、焓变、熵变、自由能变和补偿温度,研究了枯草杆菌α-淀粉酶在几种色谱介质上的热力学和超热力学。结果表明,在RP-C18反相介质、Zn2+螯合的Sepharose fast-flow亲和介质和WCX-1阳离子交换介质上,当温度分别在13-30和30-50℃范围时,它们的lnKSL分别随绝对温度的倒数线性变化;而在PEG-400和修饰的PEG-400疏水色谱介质上,当温度分别在13-40和13-30℃范围时,它们的lnKSL分别随绝对温度的倒数线性减小,但当温度分别高于40℃和30℃时,它们则随绝对温度的倒数剧烈减小。通过研究不同温度范围的焓变、熵变、自由能变和α-淀粉酶构象变化之间的关系,发现在RP-C18反相和Zn2+螯合的Sepharose fast-flow亲和介质上在30- 50 ℃温度范围内,在WCX-1阳离子交换介质上在13-30 ℃温度范围内,α-淀粉酶的吸附过程由焓变和熵变共同所支配,而在Zn2+螯合的Sepharose fast-flow亲和介质上在13- 30 ℃温度范围内,在WCX-1阳离子交换介质上在30-50 ℃温度范围和在PEG-400 和修饰的PEG-400疏水色谱介质上在13-65 ℃温度范围时,α-淀粉酶的吸附过程仅仅由熵变所控制。最后,通过α-淀粉酶在这些色谱体系中的补偿温度进一步发现,它们的焓变仅仅只能通过它们构象变化所引起的熵变所补偿。     

A STOICHIOMETRIC DISPLACEMENT MODEL FOR RETENTION OF SOLUTE IN LIQUID CHROMATOGRAPHY WITH MULTI-COMPONENT SYSTEM

Considering all the kinds of interactions between solute and solvent, solute and stationary phase, solvent and stationary phase molecules as well as the competitional adsorption among various kinds of solvent molecules on the stationary phase, we present a stoichiometric displacement model of solute retention with four sets of parameters in liquid chromatography. This model was tested with data from both literature and experiments done by ourselves. These results show that this model may fit the experimental data for a liquid chromatography system with various kinds of mobile phases consisting of a complete range of multi-components and with different types of stationary phases.     

汞及其化合物的原子吸收分析近况

汞化合物可分为两大类,既有机汞和无机汞。它们的用途很广,但均有不同的毒性。测定汞的方法很多,本文仅将原子吸收法测定汞的有关问题作以概述。