一种全光纤型观测光波粒二象性的方法

提出一种结构简单、实验现象明显的光波粒二象性观测方案,本方案以波的相干叠加突出显示光的波动性,以粒子在50/50分束器的路径随机选择特性突出显示光的粒子性.以衰减强激光脉冲为光子源,在实验室获得的干涉对比度超过99%,单粒子特性超过90%.实验结果表明此方案有望在实际得到广泛应用.     

类钠Ni~(17+)离子双电子复合过程理论研究

使用基于相对论多组态方法的FAC程序,研究了类钠Ni17+(3s)离子通过双激发态Ni16+(3pnl,3dnl)(Δn=0激发)的双电子复合过程,得到了态选择的双电子复合截面和速率系数,并与文献中的实验和理论数据进行了对比.结果发现,计算通过3p3/210l和3p1/211l共振态的双电子复合积分截面在实验误差范围内与实验测量很好地符合,并好于全相对论的多体微扰理论计算结果.结合量子亏损理论,发现包含高里德伯态的共振双激发态的辐射跃迁和自电离速率具有较好的标度关系,利用该关系给出了近激发阈值的所有共振态的双电子复合积分截面和速率系数.比较3pnl和3dnl两个系列,发现在低温(大约小于100eV)等离子体情况下前者速率系数比后者大,更高的温度后者大.     

用低温电催化重整方法和CoZnAl催化剂进行低温生物油重整制氢

利用电化学催化重整方法和CoZnAl催化剂实现了高效的生物油重整制氢过程．研究了电流强度对氢气产率、碳转化率以及产物分布的影响．结果表明,通过催化剂的电流对氢气产量和碳转化率都有明显的促进作用,在500 oC低温重整条件下氢气产率和碳转化率分别达到大约70%和85%．此外,用XRD、XPS、TGA和BET研究了电流对催化剂的结构和性能的影响．结果表明,通电催化床中热电子对生物油中含氧有机物的重整反应起着重要的促进作用．     

丝光棉/天丝A混纺比的分光光度法测定

用65%硫酸溶解天丝A和丝光棉混合物,测定其溶液的吸光度值,根据Lasbeli定理计算其混纺比,分析结果与实际配比的偏差范围为-2.74%—1.80%,误差全部在标准FZ/T01053-2007的允差范围内,说明采用该方法来进行定量测定是可行的。     

Rare decays ^-Bs,d^0→e^＋e^- in a top quark two-Higgs-doublet model

In the framework of T2HDM, we calculated the new physics contributions involving neutral Higgs bosons to the branching ratios of ^-Bs,d^0→e^＋e^-（e= e,μ） decays. Comparing the theoretical predictions with the experimental upper-limits, we found that （a） The data of Br（^-Bs,d^0→e^＋e^-） give the upper bound on tanβ： tanβ≤22, while Br（^-Bs^0→e^＋e^-） give tanβ≤12 for fixed δ = 0^0, mH＋ = 350 CeV, mH^0 = 160 GeV, mh^0 = 115 GeV and mA^0 = 120 GeV; （b） A light neutral Higgs boson mass mho （mA^0） less than 50 GeV （120 GeV） is excluded by the data of branching ratios for ^-Bs,d^0→e^＋e^-（e = μ） decays with tanβ= 10; （c） The bounds on mh^0 and tanβ, or mA^0 and tanβ are strongly correlated： a smaller （larger） tanβ means a lighter （heavier） neutral Higgs boson.     

Density-functional investigation of 3d,4d,5d impurity doped Au6 clusters

The general features of the geometries and electronic properties for 3d,4d,and 5d transition-metal atom doped Au 6 clusters are systematically investigated by using relativistic all-electron density functional theory in the generalized gradient approximation(GGA).A number of structural isomers are considered to search the lowest-energy structures of M@Au 6 clusters(M=3d,4d and 5d transition-metal atoms),and the transition metal atom locating in the centre of an Au 6 ring is found to be in the ground state for all the M@Au 6 clusters.All doped clusters,expect for Pd@Au 6,show large relative binding energies compared with a pure Au 7 cluster,indicating that doping by 3d,4d,5d transition-metal atoms could stabilize the Au 6 ring and promote the formation of a new binary alloy cluster.     

基于羟基氧化铁/石墨烯复合材料构建生物传感器用于ATP的检测

采用FeOOH-rGO复合材料作为光敏材料,并将负载了大量葡萄糖分子的功能化介孔二氧化硅纳米颗粒(MSNs)作为识别探针和信号放大系统构建生物传感平台用于ATP的检测.在目标物存在的情况下,ATP与适配体进行特异性结合,使得MSNs的孔道被打开,葡萄糖分子被释放并作为电子供体参与光电转换过程,引起光电流的增加.随着ATP浓度的增大,释放的葡萄糖分子增加,光电流信号增强,通过监测光电流信号从而实现对目标物ATP浓度的检测.     

自由参数对基于双流体模型水锤计算精度影响的研究

本文采用气液两相双流体模型,分析探讨了该种计算模型对于计算带有液柱分离现象的水锤瞬变过程的准确性,同时研究了计算模型中自由参数对计算结果的影响,通过计算分析及实验验证,得到以下结论:1.采用气液两相双流体模型,考虑相间的质量分布,并采用类NND的高精度数值解法,可以较为准确的计算带有液柱分离现象弥合性水锤的瞬变过程。2.通过分析比对发现,双流体模型中的自由参数对于计算结果的影响中,气相波速改变对于计算结果精度的影响较大。     

Surface Carbonization of GaN and the Related Structure Evolution during the Annealing Process

To explain the stabilization mechanism of the carbon-ion-implanted GaN under the diamond growth environment,the luminescence characteristics and structure evolution correlative with sites' carbon atoms located for highfluence carbon-ion-implanted Ga N are discussed. GaN is implanted with carbon ion using fluence of 2×10~(17) cm~(-2) and energy of 45 keV. Then the implanted samples are annealed at 800℃ for 20 min and 1 h under the N_2 atmosphere. The luminescence characteristics of carbon-ion-implanted GaN are evaluated by photoluminescence spectrum at wavelength 325 nm. The lattice damage of Ga N is characterized by Raman spectrum and the corresponding vacancy-defect evolution before and after annealing is measured by slow positron annihilation. The results show that most of the carbon atoms will be located at the interstitial sites after carbon ion implantation due to the weak mobility. As the implanted samples are annealed, strong yellow luminescence is emitted and the vacancies for Ga(V_(Ga)) are reduced resulting from the migration of interstitial carbon(C_i) and formation of complexes(CGaand/or C_(Ga)-C_i) between them. As the annealing time is prolonged, the carbon ions accommodated by the vacancies are saturated, vacancy clusters with carbon atoms appear and the concentration of C_(Ga) diminishes, which will have an adverse effect on the diamond film nucleation and growth.     

三自旋体系长寿命核自旋单重态的制备

长寿命核自旋单重态的寿命（T_S）可以长于常规的纵向弛豫时间（T₁）,基于这个独特的优势,长寿命核自旋单重态具有较好的应用价值.本文对已有脉冲序列进行了改进,给出了适用于任意三自旋弱耦合体系长寿命核自旋单重态制备的参数计算方法,发现在同一个三自旋体系内核自旋单重态具有多种不同比例系数组合的形式,并以丙烯酸为例制备出了两种长寿命核自旋单重态,实验上观察到不同的核自旋单重态的寿命存在差异,另外我们还探究了温度对丙烯酸核自旋单重态寿命的影响.