碳遮光石英气凝胶传热机制与热性能数值模拟

建立了碳遮光石英气凝胶传热机制及热性能数值模拟方法,在交叉立方阵列导热模型、热辐射传输谱带模型、辐射导热耦合传热模型基础上,采用蒙特卡罗方法与有限体积法数值模拟了气凝胶内的热辐射传输及辐射导热耦合传热,并以表观导热系数描述气凝胶传热性能.以某石英气凝胶为例,定量模拟了热性能、各种传热方式的作用及温度依赖性,分析了应用Rosseland扩散近似引起的误差.     

基于空芯微结构光纤拉曼探针的实验研究

表面增强拉曼散射(SERS)技术可有效增强样品分子的拉曼信号,对生物分子检测具有较高的灵敏性,因此在生化方面有着许多潜在的应用.而将空芯微结构光纤与SERS技术相结合不仅能够远端实时、分布式地检测,同时还可以增加光场与待测物的有效作用面积,减少传统光纤探针无法避免的石英背景信号等问题.本文基于空芯微结构光纤进行SERS探针的制备及性能测试研究,利用真空物理溅射法在空芯光纤内镀纳米Ag膜,从而制备成SERS探针,通过实验检测不同浓度的罗丹明6G (R6G)酒精溶液的拉曼信号.结果表明,在探针的近端正面成功探测到了浓度低至10~(-9)mol/L的R6G拉曼信号,在探针的远端反面探测到的浓度可小于10~(-6)mol/L.该实验结果为研究高灵敏度的SERS探针提供了一种新的手段.     

应用于热中子的nTHGEM探测器性能研究

随着脉冲强流中子源的发展,对高性能中子探测器提出了更大的挑战,3He气体资源严重短缺和高计数率中子探测器的迫切需求,已开始制约着中子源应用技术的发展。中国科学院高能物理研究所针对中子的特殊性,专门研发了一种陶瓷基材的nTHGEM（neutron Thick Gaseous Electron Multiplier）探测器用于中子探测。基于nTHGEM的中子探测器具有高计数率、高位置与时间分辨能力、增益大、制作工艺简单,且便于大面积制作的特点,是目前国际上发展替代3He探测技术的重要方向之一。为了详细研究nTHGEM探测器的本身性能,本工作使用55Fe放射源研究了nTHGEM探测器的增益、计数率稳定性、能量分辨率等关键参数与nTHGEM膜间电压、收集场强、漂移场强之间的关系,优化了nTHGEM探测器在不同工作气体中的工作参数,为后续进一步优化nTHGEM探测器设计和工艺奠定了基础。实验结果表明,单层nTHGEM探测器在Ar（90%）+CO₂（10%）混合气体中增益能达到103,探测器计数率稳定性良好。另外,还在中国原子能科学研究院的CARR反应堆（China Advanced Research Reactor）上进行了中子束流实验,通过狭缝测量到探测器位置分辨率为（3.01±0.03）mm（FWHM）,已经接近高气压3He MWPC中子探测器水平。With the development of pulsed intense neutron source, the high-performance neutron detector poses more challenges. The severe shortage of 3He gas resources and the urgent need of neutron detector with high counting rate have begun to restrict the neutron source application technology development. In response to the particularity of neutrons, the Institute of High Energy Physics of CAS developed a nTHGEM(neutron Thick Gaseous Electron Multiplier)of ceramic substrate for neutron detection. The neutron detector based on nTHGEM is one of the most important directions for the development of alternative 3He detection technology in the world at present because of its high counting rate, high position and time resolution, large gain, simple fabrication process and large area production. In order to study the properties of nTHGEM detector in detail, this paper studied the relationship between nTHGEM detector's gain, counting rate stability, energy resolution and other key parameters and nTHGEM film voltage, collection field strength and drift field strength using 55Fe radioactive source, Optimized the working parameters of nTHGEM detector in different working gases, which laid the foundation for further optimization of nTHGEM detector design and process. The experimental results show that the single-layer nTHGEM detector has a gain of 103 in a Ar(90%)+CO₂(10%) mixed gas with good counting rate stability. In addition, a neutron beam experiment was performed on the China Advanced Research Reactor at the China Institute of Atomic Energy, and the position resolution of the detector was (3.01±0.03) mm (FWHM) measured by slits. Its performance is close to the high pressure 3He MWPC neutron detector level.     

Spin flip in single quantum ring with Rashba spin–orbit interation

We theoretically investigate spin transport in the elliptical ring and the circular ring with Rashba spin–orbit interaction.It is shown that when Rashba spin–orbit interaction is relatively weak, a single circular ring can not realize spin flip, however an elliptical ring may work as a spin-inverter at this time, and the influence of the defect of the geometry is not obvious.Howerver if a giant Rashba spin–orbit interaction strength has been obtained, a circular ring can work as a spin-inverter with a high stability.     

水饱和离子液体中脂肪酶催化萘普生甲酯对映选择性水解

 对比研究了水饱和异辛烷和水饱和离子液体1-正丁基-3甲基咪唑六氟磷酸盐([bmim]PF6)中脂肪酶催化萘普生甲酯不对称水解反应. 结果表明,由于离子液体[bmim]PF6同时具有极性和疏水性,因而成为萘普生甲酯不对称水解反应的理想介质. 与水饱和异辛烷相比,水饱和离子液体不仅明显降低了水解反应的平衡常数(K),增大了对映体比率(E),从而有效提高了水解反应的平衡转化率(ceq)和产物的对映体过量值(eep),而且由于离子液体对另一产物甲醇的溶解度高,还明显地提高了脂肪酶的操作稳定性.     

几个影响PVA为粘合剂的光敏热成像材料感光性能的因素研究

本文以水性聚乙烯醇(PVA)为粘合剂,原位法合成的AgBr作为光敏元,考察了组分四氯邻苯二甲酸、酞嗪以及三溴甲基砜类防灰雾剂在体系不同pH值时对PTG材料感光性能的影响.实验结果表明:防灰雾剂可以明显地降低灰雾和减小最大密度;体系pH在7.0-7.5之间时,感光度最大,而灰雾随着体系pH的升高而增大.     

Ca2+、Ba2+对光敏热成像材料照相性能和稳定性的影响

以常用的硬脂酸银为银源,异位AgBr为光敏元以及亲水型PVA为粘合剂,分别考察了Ca2+和Ba2+对光敏热成像(PTG)材料照相性能以及老化稳定性的影响.实验结果表明:涂布前乳液中加入Ca2+或Ba2+后,PTG材料的感光度和灰雾均出现不同程度的降低,并且随着加入量的增加,感光度下降更快.另外,含有Ca2+或Ba2+的PTG材料随着老化时间的增加,其感光度和灰雾的变化趋势并不相同.     

Impact of Sheath Boundary Conditions and Magnetic Flutter on Evolution and Distribution of Transient Particle and Heat Fluxes in the Edge-Localized Mode Burst by Experimental Advanced Superconducting Tokamak Simulation

To study the evolution and distribution of the transient particle and heat fluxes during the edge-localized modes(ELMs) burst on the experimental advanced superconducting tokamak(EAST), the BOUT++six-field two-fluid model with sheath boundary conditions(SBCs) and magnetic flutter terms in the parallel thermal conduction is used to simulate the evolution of the profiles and growing process of the fluxes at divertor targets. Although SBCs hardly play a role in the linear phase, in the nonlinear phase both SBCs and magnetic flutter can change the dominant toroidal mode. SBCs are able to broaden the frequency distribution of the turbulence. The magnetic flutter increases the ELM size from 2.8% to 8.4%, and it doubles the amplitudes of the radial heat and particle transport coefficients at outer midplane(OMP), at around 1.0 m~2 s~(-1). It is then able to increase the particle and heat flux at the divertor targets and to broaden the radial distribution of the parallel heat flux towards the targets.     

中国散裂中子源小角中子散射谱仪探测器研制

中子小角散射探测器是小角散射（SANS）谱仪的关键设备之一,探测器要求有足够大的探测面积、较高的探测效率及较好的空间分辨率,能够在真空腔中稳定地工作并可在腔体内前后移动。综合考虑,SANS探测器采用120只8 mm直径位置灵敏3He管,组成有效面积1 000 mm（X）×1 020 mm（Y）的二维探测器阵列。探测器阵列分为10个模块,每一个模块功能完全独立,包括12只3He管及其对应的读出电子学和数据获取系统。读出电子学位于探测器背面的回字形密闭腔体内,由CSNS电子学组自主研发。SANS探测器从设计、选型、样机、调试到安装历时三年,中子束流实验结果显示探测器探测效率大于50%（@2Å）,空间分辨率好于10 mm（FWHM）,完全达到设计要求,目前正在中国散裂中子源小角散射谱仪运行使用。     

从“精灵”到催化“多面手”的钴元素

钴因德语中“Kobold”一词而得名,从最早发现时的“精灵”到现在已成为催化“多面手”。回顾了钴元素的发现与得名过程以及钴元素在化学学科发展过程中的重要历史意义,介绍了钴元素作为催化剂的活性中心在清洁能源和绿色合成方面的相关应用。