A digital transmission system for high intensity pulsed radial detection

A digital transmission system with 900 MHz bandwidth and over 40 dB linear dynamic range for high intensity pulsed radial detection is designed. The transient signals (with a subnanoseconds rising edge) from the detectors can be transmitted to diagnosing systems kilometers away with high fidelity. It can adapt to interference and a hostile detecting environment by using the intelligent functions of this system. The feasibility and reliability of this system is verified by system evaluation tests.     

南充市表层土壤中多环芳烃的源解析研究

运用同分异构体比率、聚类分析法和主成分因子载荷法对南充市表层土壤多环芳烃(PAHs)污染源进行了定性和定量分析。研究表明:同分异构体比率分析揭示表层土壤中PAHs污染来源以燃烧源为主;聚类分析将土壤中13种PAHs组分分成3个主群,3个主群分别指示为交通类PAHs污染、煤燃烧类PAHs污染和混合类PAHs污染。主成分因子/多元线性回归分析显示,PAHs主要来源于3大污染源,并定量计算了3种源的贡献量,其中交通燃油污染的贡献率最大(占42.4%),而燃煤燃烧排放、混合污染所占比例分别为32.4%和25.2%。     

3-硝基-2-氨基苯甲酸的合成

以邻苯二甲酸酐为起始原料,经硝化、脱水、酰胺化、霍夫曼重排4步反应合成了3-硝基-2-氨基苯甲酸,总收率19%,其结构经1H NMR, IR和元素分析表征.探讨了酰胺化和霍夫曼重排反应条件对产率的影响.结果表明, n(脲素) ∶ n(3-硝基邻苯二甲酸酐)=2.0 ∶ 1.0,于50 ℃～60 ℃反应5 h～6 h,酰胺化反应收率85%～91%.n(NaClO) ∶ n(3-硝基-2-甲酰胺基苯甲酸)=1.2 ∶ 1.0,于60 ℃反应3 h,重排反应收率94%.     

THRESHOLD RESULT FOR SEMILINEAR PARABOLIC EQUATIONS WITH INDEFINITE NON-HOMOGENEOUS TERM

In this paper,we study the threshold result for the initial boundary value problem of non-homogeneous semilinear parabolic equations ut u=g(u)+λf(x),(x,t)×(0,T),u=0,(x,t)∈×[0,T),u(x,0)=u0(x)≥0,x ∈.(P) By combining a priori estimate of global solution with property of stationary solution set of problem(P),we prove that the minimal stationary solution Uλ(x)of problem(P)is stable,whereas,any other stationary solution is an initial datum threshold for the existence and nonexistence of global solution to problem(P).     

Beam stability analysis of high power laser system based on relay imaging

The model of a beam propagating in a high power laser system is built based on relay imaging. The displacement sensitivity of the lens to beam positioning error is obtained using this model, which is then compared with the traditional method. Two real systems, the pre-amplifier and four-pass amplifier in SGII-U, are presented to further discuss the differences between the two methods. The limitation and application range are summarized in the end. The findings can be used to provide guidance in similar systems.     

混沌量子克隆优化求解认知无线网络决策引擎

通过分析认知无线网络引擎决策, 给出了其数学模型, 并将其转化为一个多目标优化问题, 进而提出一种基于混沌量子克隆的优化求解算法, 并证明了该算法以概率1收敛. 算法采用量子编码, 利用Logistic映射初始化抗体种群, 设计了一种基于混沌扰动的量子变异方案. 最后, 在多载波环境下对算法进行了仿真实验. 结果表明, 与QGA-CE(基于量子遗传算法的认知引擎)算法相比, 本文算法收敛速度较快, 具有较高的目标函数值, 可以对无线参数优化调整, 满足认知引擎的实时性要求.     

新型Ni(Ⅱ)催化剂催化聚合乙烯电中性机理的量子化学研究

Ni(Ⅱ)与含氮氧配位原子的大配体形成的催化剂,可以不用助催化剂即有较高的烯烃聚合催化活性.不用助催化剂的催化机理不是阳离子催化反应机理,而是电中性催化机理.应用密度泛函理论方法,在B3LYP/LANL2MB水平上,研究了Ni(Ⅱ)催化剂催化乙烯聚合的电中性反应机理.计算结果表明,电中性催化机理类似于阳离子催化机理.电中性催化机理中,初始带空位的中性四面体络合物能量较低,是避免使用助催化剂的必要条件;由于Ni原子带正电荷较小,乙烯与催化剂共平面的的结构不是平衡几何构型,而是过渡态.在B3LYP/LANL2MB在水平上优化得到一个乙烯与催化剂共平面的二级鞍点结构.     

具有非线性光学性质的杯[4]芳烃的合成

通过杯芳烃醛和异佛尔酮衍生物缩合合成了一系列新的具有NLO性貭的杯芳烃衍生物。在这些化合物中，杯芳烃上缘的环锁三烯用作D-π-A单元的共轭桥和电子受体，杯芳烃下缘的正辛氧基用于固定锥式构象。核磁共振研究证实它们以锥式构象存在，非共轭的D-p-A单元能近似同向排列。     

硅壳纳米颗粒对COS-7细胞的生物效应

从硅壳纳米颗粒对细胞存活率、细胞周期及细胞生长曲线的影响等方面系统地考察了包裹RuBpy染料的硅壳荧光纳米颗粒(FSiNPs)对美洲绿猴肾细胞(COS-7)的生物效应. 结果表明, FSiNPs对COS-7细胞的影响是浓度依赖性的, 低浓度(<0.2 μg/μL)的FSiNPs对细胞的存活率、细胞周期及整个生长过程均无负面影响, 但随着与COS-7细胞作用的FSiNPs浓度的增大, FSiNPs对COS-7细胞的毒性也逐渐增大, 尤其是对细胞周期及细胞生长曲线的影响更为敏感. 同时, 利用FSiNPs的荧光信号同步指示作用, 考察了COS-7细胞对FSiNPs的吞噬作用, 发现 FSiNPs通过细胞膜的吞噬作用随机地进入到细胞内, 一部分FSiNPs被细胞当成异物外排到细胞培养基中, 另一部分则进入到下一代细胞中. 随着细胞传代次数的增多和新生胞质的产生, FSiNPs在细胞内的含量逐渐减少, 最后消失. 在这一过程中, 细胞的形态和生长状况依然良好. 上述研究结果有望为FSiNPs在细胞生物学的研究和应用提供一定的安全标准, 并为开展基于新型纳米颗粒的纳米颗粒器件的研究与应用打下了基础.     

Synthesis and Nonlinear Optical Properties of Chromophores with 1,8-Dimethoxy-9,10-dihydroanthracene and Ring-locked Triene

The new chromophore molecules with nonlinear optical （NLO） properties were prepared by Knoevenagel condensation from 1,8-dimethoxy-4,5-diformyl-9,10-dihydroanthracene and isophorone derivative in the presence of piperidine and acetic acid. In these chromophore, the ring-locked trienes were employed as the conjugation bridge and electron acceptor in D-π-A units. The key intermediate dialdehyde was conveniently prepared via a three step reaction, in which 1,8-dimethoxyanthraquinone was reduced with zinc/acetic acid and sodium/ethanol successively, followed by formylation with 1,1-dichlorodimethyl ether in the presence of TiCI4. The solvatochromism and UV spectra indicate that they have higher second-order nonlinear hyperpolarizability μβ values than the corresponding reference compound, without red shift of the charge transfer band.