A New 1-D Chain ofγ-Hg3S2Br2Constructed from Hg4S4Squares:Solid-state Synthesis,Structure and Optical Properties

A new metal chalcogenide,γ-Hg₃S₂Br₂(1),has been prepared by moderate-temperature solid-state reaction,and its crystal structure was determined by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in space group Cmmm of orthorhombic system with a=9.1923(18),b=18.2262(5),c=4.6251(7)?,V=774.9(3)?³and Z=4.In the structure,two Hg(1),two Hg(2)and four S(1)atoms form a near square Hg₄S₄,and such squares are linked by Hg(3)atoms nearly linearly coordinated to two S1 atoms of two parallel Hg₄S₄squares to form one-dimensional infinite Hg₆S₄chains along c direction.Optical absorption spectra reveal the presence of sharp optical gap of 2.80 eV for 1.IR spectrum,TGA and electric resistivity have been investigated.     

聚甲基丙烯酸甲酯和聚碳酸酯各向异性光学性质理论研究

作为重要的光学薄膜材料,聚甲基丙烯酸甲酯(PMMA)和聚碳酸酯(PC)在诸多工业领域已得到广泛应用.本文利用密度泛函理论结合分子动力学方法深入系统地研究了这两种聚合物的各向异性光学性质,并对比分析了不同分子链长度和微观结构对其各向异性光学性质的影响.计算结果表明PMMA和PC都具有较高的本征双折射率,且分子链长度对本征折射率的影响显著.在可见光范围内,单体单元PMMA本征双折射率在10%以上,而三单元结构本征折射率则不到4%.对于体相结构多聚体,从立方结构拉伸到厚度仅有6?的过程中,PC不同方向折射率最大差异高达6%,而同样情况下PMMA不同方向折射率差异仅有1.3%.此项研究有助于理解PMMA和PC聚合物各向异性光学特征产生的原因和影响因素,从而进一步指导和促进其在更多领域的发展与应用.     

串联战斗部不同介质组合的隔爆能力

为了有效提升串联切割战斗部隔爆结构衰减爆炸冲击波的性能,解决前级聚能装药结构与后级随进弹的匹配及隔爆问题,在前级切割器和后级随进弹之间加装隔爆结构,使用有限元分析软件ANSYS/LS-DYNA建立模型,进行不同组合结构隔爆性能的数值模拟,比较隔爆能力。模拟结果表明:前级装药起爆后,爆炸冲击波首先向后级随进弹头靠里区域汇聚,而不是向弹头尖端区域汇聚,因此可以适当减薄外层金属隔爆介质头部尖端区域;将外层金属由硬质钢改成铝时,后端壳体应力峰值的变化很小,故确定外层金属介质为铝;铝-聚脲的隔爆能力优于铝-泡沫铝结构,最终确定"软"隔爆介质为聚脲。通过调整铝和聚脲层的厚度,确定了最佳隔爆参数,能够满足实际应用。     

Microscopic study of 7Li-nucleus potential

A microscopic approach is employed to study the optical potential for the 7Li-nucleus interaction system without any free parameters.It is obtained by folding the microscopic optical potentials of the constituent nucleons of 7Li over their density distributions.We employ an isospin-dependent nucleon microscopic optical potential,which is based on the Skyrme nucleon-nucleon effective interaction and derived using the Green's function method,as the nucleon optical potential.The harmonic oscillator shell model is used to describe the internal wave function of 7Li and obtain the nucleon density distribution.The 7Li microscopic optical potential is used to predict the reaction cross-sections and elastic scattering angular distributions for the target range from 27Al to 208Pb and energy range below 450 MeV.Generally,the results can reproduce the measured data reasonably well.In addition,the microscopic optical potential is comparable to a global phenomenological optical potential by fitting the presently existing measured data.     

Near-field manipulation of terahertz surface waves by metasurfaces [Invited]

Surface waves(SWs) are a special form of electromagnetic waves that travel along the boundary between a metal and a dielectric. The special optical properties of SWs render them very attractive in applications, such as subdiffractional lithography, novel biochemical sensors, and ultrafast integrated circuitries. Herein, we present a review of our recent progress in excitation and manipulation of terahertz SWs due to interference or coupling between a pair of slit resonators in metasurfaces, showing the ability to devise ultrathin and compact plasmonic components.     

马丁内兹型啁啾脉冲放大系统高阶色散的混合补偿

采用光线追迹法对含有马丁内兹型展宽器的CPA系统的各阶色散进行了系统的理论研究，提出了引入适当负三阶色散量以补偿五阶色散的总体色散的混合补偿方法.该方法能够获得比采用仅补偿二、三阶色散的逐阶色散补偿法更接近傅里叶变换极限的超短脉冲. 关键词： 啁啾脉冲放大 马丁内兹型展宽器 色散补偿     

利用喇曼光谱测量氧碘激光器氧发生器的O2（a1Δ）产率

 利用自发喇曼成像技术实时监测氧碘激光器O₂(¹Δ)发生器流场组分，得到了发生器气流中O₂(¹Δ)和 O₂(X³Σ)以及N₂的自发喇曼散射光谱，由此得到了不同条件下的O₂(¹Δ)产率，测量误差不超过8%。     

ZnO粉末中无序激射现象时间分辨的研究

采用抽运-探测时间分辨方法实验研究了半导体材料ZnO纳米颗粒粉末中的无序激射现象.在2 67nm激光的抽运下，通过精确控制抽运光的能量和样品表面的抽运面积，获得了宽度小于1n m的单模无序激射光谱和多峰的多模无序激射光谱.时间分辨的抽运-探测结果显示，此时样 品的上能级寿命仅为几个皮秒，证明了ZnO粉末的单模无序光谱是受激辐射的结果. 关键词： 高散射介质 多重散射 抽运-探测 无序激射     

飞秒互相关时间选通技术用于光学层析成像的实验研究

利用飞秒互相关二次谐波信号时间选通技术。实现了对埋藏在高度散射介质中物体的透射成像和反射以析成像。互相关选通门有效地选出携带物体信息的弹道光子和蛇行光子，排除了给成像带来背景噪声的温射光子，分别获得了散射介质中物体的二次谐波一维和二维图像。     

SC32，SC64多群核参数的研制与检验

为适应中子物理基准实验的细致计算分析，研制了中子光子耦合计算用SC32、SC64两套多群核参数，中子能量上限为14．5MeV，低能端延伸到热能区25keV。配套的光子参数采用20群结构。核素种类涉及总体计算程序用到的五六十种，见表l。