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吸附聚丙烯酸对纳米碳管表面特征影响的研究 总被引:3,自引:0,他引:3
利用低温氮气吸附法系统研究了吸附聚丙烯酸 (PAA)的量对纳米碳管表面特征的影响 .分析结果表明 :当PAA吸附量增加到 2 68 98mg·g-1时 ,纳米碳管的比表面积下降了 46 97% ;虽然吸附PAA后的纳米碳管在 1 8nm以上的孔径分布特征基本上与原样一致 ,但孔容减少 ,这部分孔对比表面的贡献明显降低 ,同时出现 1 8nm以下的孔 ;通过氮气吸附等温线利用热力学方法计算的纳米碳管的表面分维值 (surfacefractaldimension)dSF由原样的 2 5 4下降至吸附后的 2 48,表明吸附PAA分子能够降低纳米碳管的粗糙度 .这些说明堵孔效应和屏蔽效应是纳米碳管表面特征改变的主要因素 ,这一研究对纳米碳管在吸附、催化等方面的应用有着非常重要的意义 . 相似文献
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超临界甲烷在高表面活性炭上的吸附测量及其理论分析 总被引:22,自引:0,他引:22
实验测定了0~10
MPa,233~333 K (20 K间隔)范围内超临界甲烷在高表面活性炭上的吸/脱附等温线,确定了此物理吸附过程的可逆性,并从实验数据计算出吸附热为16.5
kJ/mol. 建立了描述具有最大点的吸附等温线模型,其总体偏差为±2%. 模型保持了特征吸附能恒定的性质,方程指数亦反映了吸附剂的微孔分布特征,模型参数给出了超临界甲烷的吸附相密度. 将超临界吸附极限态引入等温线模型中,经典的吸附理论亦可解释超临界吸附现象. 相似文献
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采用基于三维Ono-Kondo方程的格子密度函数理论(LDFT)模型模拟了氢气在A和X型微孔沸石上的超临界吸附等温线. 根据沸石孔的尺寸和形状, LDFT模型将氢分子在孔中的吸附位分布近似为简单立方、面心立方和体心立方的团簇结构. 模拟结果表明, LDFT模型可有效地用于描述氢气在A和X型沸石上的单层或多层超临界吸附行为. 模拟所得的吸附等温线与实验测定结果吻合. 特别是, LDFT模型中的氢-沸石作用势能参数的准确性得到了Lennard-Jones(12-6)势能方法的有效验证. 因此, LDFT模型被用于预测了更宽温度和压力范围内氢气在X沸石上的超临界吸附. 相似文献
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在273-373 K、0-10 MPa范围内测量了甲烷在纳米活性炭表面的吸附等温线和等量吸附热. 结果发现, 在实验涉及的温度范围内, 吸附平衡特性在低压下能够很好地遵循Dubinin-Astakhov (DA)微孔填充模型, 但是当压力超过特定范围时, 吸附等温线及等量吸附热测量数据都与DA模型计算结果发生了偏离, 吸附行为更接近单层定位吸附.文中参照Cerofolini对亚单层吸附提出的Freundlich-Dubinin-Radushkevich (FDR)混合模型, 对纳米活性炭在较高压力条件下的吸附使用通用Freundlich (GF)模型进行了修正, 从而提出了一种分段模型GFDA. 根据GFDA模型对甲烷在广泛的压力范围内在纳米活性炭表面的吸附机理进行了完整的解释, 并对纳米活性炭表面的能量非均匀性进行了分析. 相似文献
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应用基于Ono-Kondo格子理论得到的通用吸附等温方程, 通过分析氢在不同温度下, 在沸石NaX、CaA、NaA和ZSM-5上的吸附数据, 确定了氢的最大单层吸附容量. 并引入维里吸附方程, 由第二维里吸附系数和圆柱孔的Lennard-Jones(12-6)势模型计算了氢与沸石微孔壁面的作用势. 结果表明, 通用吸附等温方程可较好地描述氢在沸石上的超临界吸附行为, 拟合所得的氢在沸石上的最大单层吸附容量与吸附剂相关, 而与吸附温度无关. 圆柱孔作用势模型计算所得的氢分子在沸石上的吸附作用势与吸附热相近. 氢分子间的作用力表现为吸引力. 相似文献
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采用巨正则系统MonteCarlo方法研究了甲烷在单壁碳纳米管(Singlewallcarbonnanotube,SWNT)中于低温74.05K下的吸附等温线及吸附机理,发现在两个较小的孔径(1.225nm和1.632nm)下单壁碳纳米管中甲烷的吸附有着明显的微孔所独有的“填充效应”,而在2.04nm以上的孔的吸附中会出现毛细凝聚现象。通过模拟知道发生毛细凝聚的必要条件是孔内能至少容纳下两层粒子,此外还导出在恒定温度下毛细凝聚吸附量与SWNT孔径关系。本文还模拟了常温300K下甲烷在SWNT内的吸附,对比了2.04nm和4.077nm两种孔径的SWNT吸附甲烷的等温线,推荐在4.077nm孔中的适宜吸附存储压力为5.0~6.0MPa,吸附质量分数可达16%~19%. 相似文献
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Both H2 and CH4 are clean energy sources. Adsorption was considered a measure to enhance their storage, and many efforts have been dedicated to creating novel materials including carbon nanotubes as efficient carriers for them. In order to understand the uptake mechanism and the viability of practical application, eight adsorption isotherms of H2 on a sample of multiwall carbon nanotubes were collected. The heat of adsorption was determined and an isotherm model was presented. Isotherms of CH4 on the same sample were also collected. While the adsorption on dry samples behaves similarly to that of H2, the sorption behavior of CH4 in the water-loaded sample is quite different and five times higher uptake capacity was observed in the wet sample due to the formation of methane hydrates. However, carbon nanotubes are unlikely to be used as an energy carrier due to its limited surface area and pore volume. 相似文献
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Adsorption of H2 on multiwalled carbon nanotubes was measured at 77 K by a volumetric method. Adsorption and desorption isotherms are largely reversible. The adsorption capacity increased remarkably after receiving heat treatment at 400 °C and being pressed into pellets. The isotherms show typical feature of supercritical adsorption and were satisfactorily modeled by the model that applied for usual supercritical adsorption. The maximal adsorption capacity of hydrogen under the condition tested is less than 0.5 wt%. 相似文献
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ZHENG Hong WANG Shaoqing & CHENG Huiming Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang China 《中国科学B辑(英文版)》2004,47(3):222-227
Hydrogen is a kind of clean, sustainable and renewable energy carrier. Of the problems to be solved for the utilization of hydrogen energy, how to store and transport hydrogen has been given high priority on the research agenda. Recently, carbon nanotubes (CNTs) were reported to be very promising candidates for hydrogen uptake[1], which may have possibility to satisfy the benchmark set by the US Department of Energy (DOE) Hydrogen Plan for fuel cell powered vehicles: a gravimetric density … 相似文献
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Gas adsorption process in activated carbon over a wide temperature range above the critical point. Part 1: modified Dubinin-Astakhov model 总被引:1,自引:1,他引:0
Simulations of the thermal effects during adsorption cycles are valuable tools for the design of efficient adsorption-based
systems such as gas storage, gas separation and adsorption-based heat pumps. An analytical representation of the measured
adsorption data over the wide operating pressure and temperature swing of the system is necessary for the calculation of complete
mass and energy conservation equations. In Part 1, the Dubinin-Astakhov (D-A) model is adapted to model hydrogen, nitrogen,
and methane adsorption isotherms on activated carbon at high pressures and supercritical temperatures assuming a constant
microporous adsorption volume. The five parameter D-A type adsorption model is shown to fit the experimental data for hydrogen
(30 to 293 K, up to 6 MPa), nitrogen (93 to 298 K, up to 6 MPa), and for methane (243 to 333 K, up to 9 MPa). The quality
of the fit of the multiple experimental adsorption isotherms is excellent over the large temperature and pressure ranges involved.
The model’s parameters could be determined as well from only the 77 K and 298 K hydrogen isotherms without much reducing the
quality of the fit. 相似文献
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Fadi Khaddour Auriane Knorst-Fouran Frédéric Plantier Manuel M. Piñeiro Bruno Mendiboure Christelle Miqueu 《Adsorption》2014,20(4):649-656
The adsorption of pure methane in activated carbon Ecosorb was studied by combining grand canonical ensemble Monte Carlo molecular simulations and an experimental approach based on a gravimetric device. Experimental and calculated adsorption isotherms of methane were determined in supercritical conditions at 303.15 and 353.15 K and pressures up to 10 MPa. The comparison between both experimental and estimated data proves the consistency of the methodology used in this work, starting from the characterization of the porous media in terms of pore size distribution, the determination of the experimental adsorption isotherms, and the final estimation of computational results through estimated isotherms determination. Moreover, additional differential enthalpy of adsorption calculations were compared with experimental values obtained by means of a manometric/calorimetric technique. The good agreement shows the strength and the originality of this paper by combining experimental and computational homemade results allowing a complete characterization of the activated carbon substrate and its methane storage capacity. 相似文献
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Kowalczyk P Tanaka H Kaneko K Terzyk AP Do DD 《Langmuir : the ACS journal of surfaces and colloids》2005,21(12):5639-5646
Grand canonical Monte Carlo (GCMC) simulation was used for the systematic investigation of the supercritical methane adsorption at 273 K on an open graphite surface and in slit-like micropores of different sizes. For both considered adsorption systems the calculated excess adsorption isotherms exhibit a maximum. The effect of the pore size on the maximum surface excess and isosteric enthalpy of adsorption for methane storage at 273 K is discussed. The microscopic detailed picture of methane densification near the homogeneous graphite wall and in slit-like pores at 273 K is presented with selected local density profiles and snapshots. Finally, the reliable pore size distributions, obtained in the range of the microporosity, for two pitch-based microporous activated carbon fibers are calculated from the local excess adsorption isotherms obtained via the GCMC simulation. The current systematic study of supercritical methane adsorption both on an open graphite surface and in slit-like micropores performed by the GCMC summarizes recent investigations performed at slightly different temperatures and usually a lower pressure range by advanced methods based on the statistical thermodynamics. 相似文献
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Fitzgerald JE Robinson RL Gasem KA 《Langmuir : the ACS journal of surfaces and colloids》2006,22(23):9610-9618
The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO2 sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO2 on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO2 on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties. 相似文献
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Optimum conditions for adsorptive storage 总被引:1,自引:0,他引:1
The storage of gases in porous adsorbents, such as activated carbon and carbon nanotubes, is examined here thermodynamically from a systems viewpoint, considering the entire adsorption-desorption cycle. The results provide concrete objective criteria to guide the search for the "Holy Grail" adsorbent, for which the adsorptive delivery is maximized. It is shown that, for ambient temperature storage of hydrogen and delivery between 30 and 1.5 bar pressure, for the optimum adsorbent the adsorption enthalpy change is 15.1 kJ/mol. For carbons, for which the average enthalpy change is typically 5.8 kJ/mol, an optimum operating temperature of about 115 K is predicted. For methane, an optimum enthalpy change of 18.8 kJ/mol is found, with the optimum temperature for carbons being 254 K. It is also demonstrated that for maximum delivery of the gas the optimum adsorbent must be homogeneous, and that introduction of heterogeneity, such as by ball milling, irradiation, and other means, can only provide small increases in physisorption-related delivery for hydrogen. For methane, heterogeneity is always detrimental, at any value of average adsorption enthalpy change. These results are confirmed with the help of experimental data from the literature, as well as extensive Monte Carlo simulations conducted here using slit pore models of activated carbons as well as atomistic models of carbon nanotubes. The simulations also demonstrate that carbon nanotubes offer little or no advantage over activated carbons in terms of enhanced delivery, when used as storage media for either hydrogen or methane. 相似文献
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为研究影响碳基吸附剂吸附超临界温度气体的主要因素,选择石墨化热解碳黑BP280和Ajax活性炭,分析超临界温度高压甲烷在其上的吸附平衡。应用容积法,在压力0~20.5 MPa、温度253 K~313 K测定甲烷的吸附平衡数据,并由等量吸附线标绘和亨利定律常数确定等量吸附热。引入通用吸附等温方程,再由方程的Langmuir标绘确定最大吸附容量,进而通过方程的线性化计算吸附平衡态中甲烷分子的作用能。结果表明,甲烷在两种吸附剂上的最大吸附容量均随温度而变化,并都小于液态甲烷的密度;甲烷在碳黑和活性炭上的等量吸附热分别为11.9 kJ/mol~12.5 kJ/mol和17.5 kJ/mol~22.5 kJ/mol,体现了两种吸附剂不同的表面能量分布;甲烷分子间作用能随吸附量的变化特点反映了超临界温度甲烷以类似于压缩气体状态聚集的特点和吸附剂结构上的差异。碳基吸附剂的比表面积和微孔容积是影响其储存甲烷容量的重要因素。 相似文献
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There is considerable interest in hydrogen adsorption on carbon nanotubes and porous carbons as a method of storage for transport and related energy applications. This investigation has involved a systematic investigation of the role of functional groups and porous structure characteristics in determining the hydrogen adsorption characteristics of porous carbons. Suites of carbons were prepared with a wide range of nitrogen and oxygen contents and types of functional groups to investigate their effect on hydrogen adsorption. The porous structures of the carbons were characterized by nitrogen (77 K) and carbon dioxide (273 K) adsorption methods. Hydrogen adsorption isotherms were studied at 77 K and pressure up to 100 kPa. All the isotherms were Type I in the IUPAC classification scheme. Hydrogen isobars indicated that the adsorption of hydrogen is very temperature dependent with little or no hydrogen adsorption above 195 K. The isosteric enthalpies of adsorption at zero surface coverage were obtained using a virial equation, while the values at various surface coverages were obtained from the van't Hoff isochore. The values were in the range 3.9-5.2 kJ mol(-1) for the carbons studied. The thermodynamics of the adsorption process are discussed in relation to temperature limitations for hydrogen storage applications. The maximum amounts of hydrogen adsorbed correlated with the micropore volume obtained from extrapolation of the Dubinin-Radushkevich equation for carbon dioxide adsorption. Functional groups have a small detrimental effect on hydrogen adsorption, and this is related to decreased adsorbate-adsorbent and increased adsorbate-adsorbate interactions. 相似文献