单分散性银纳米粒子的可控制备

以卤化银或氧化银作为前驱体,室温下以水为溶剂,在较高溶液浓度下,利用化学还原法制备了单分散性银纳米粒子,并通过改变前驱体的种类,实现了粒径可控制备。采取扫描电子显微镜（SEM）、紫外-可见光谱仪（UV-Vis）、X射线-粉末衍射仪（XRD）、X射线-光电子能谱仪（XPS）等对所制备的银纳米粒子的形貌及成分进行了表征。结果显示,所制备的银纳米粒子具有较高的单分散性,粒径在40~150 nm之间,具有面心立方多晶结构。该方法制备的银纳米粒子可用于喷墨打印RFID天线。     

银纳米粒子的合成及其在喷墨打印电路中的应用

银纳米粒子在光学、电磁学和生物相容性等方面所具有的独特优点,使其在一系列领域得到了广泛的应用。本文综述了银纳米粒子的合成方法,以及其作为喷墨打印材料在电路制备中的应用,并展望了其发展前景。     

液相脉冲激光烧蚀法制备高熔点的纳米金属粒子

采用液相脉冲激光烧蚀法成功地制备了高熔点的金属Pt、Ru与Ag纳米粒子. 采用SEM、TEM、ED和紫外-可见吸收光谱表征了纳米粒子的特征. 纳米粒子的粒径基本在数个到数十个纳米的大小范围内. 发现含适量PVP(poly(vinylpyrrolidone))的水溶液有利于纳米粒子的制备, 而且还能够提高纳米粒子悬浮液的稳定性. 该制备方法较简单, 在制备高熔点的纳米金属粒子方面有着其它方法所不能比拟的优势.     

聚合物/纳米碳酸钙复合材料的制备

提出了一种制备聚合物/碳酸钙复合材料的技术.即先将纳米碳酸钙粒子在温和条件下分散到水溶液中,再在较弱的外场作用下混合分散到聚合物熔体中,使用此方法制备的4种典型聚合物(聚乙烯、聚丙烯、聚碳酸酯和聚脂)的纳米复合材料,通过扫描电镜观察纳米粒子以纳米尺寸均匀分布于树脂基体中.聚碳酸酯复合材料的相对分子质量变化不大,而且复合材料的某些力学性能有所提高,证明此种方法可用于极性与非极性聚合物制备纳米复合材料.     

银纳米粒子簇的设计、 制备和表面增强拉曼光谱

通过匹配激光光斑直径与胶体微球的尺寸, 设计制备了银纳米粒子的表面增强拉曼散射(SERS)基底, 并将其用于研究单个银纳米粒子簇的表面增强拉曼光谱. 在制备纳米粒子的过程中, 考察了等离子体刻蚀时间与银沉积厚度对“单”银纳米粒子结构与形貌的影响. 将吡啶、 巯基苯和罗丹明R6G作为SERS探针分子, 研究了其SERS效应, 通过荧光共振能量转移(FRET)机理, 实现了染料分子在单银纳米粒子簇上的SERS效应. SERS光谱测试与相关计算结果表明, 单个银纳米粒子簇的拉曼增强因子能够达到约10⁶.     

TiO_2-SiO_2纳米粒子的合成及二级散射光谱法测定核糖核酸

采用溶胶-凝胶法制备了TiO2-SiO2纳米粒子.通过X-射线衍射谱、透射电子显微镜等对纳米粒子进行了表征.研究了TiO2-SiO2纳米粒子与核糖核酸(RNA)的相互作用,建立了基于纳米粒子与RNA吸附反应,二级散射光谱法测定痕量RNA的新方法.方法的线性范围是0.005～5 mg/L; 检出限为1.46 μg/L.方法用于RNA合成样品的测定,回收率为99.4%～103.9%;相对标准偏差为019%～0.24%.     

温和条件下制备形貌可控的羟基磷灰石

在温和条件下采用简单的实验方法成功制备出不同结构和形貌的羟基磷灰石(HAP)纳米粒子。采用沉淀-水解两步法,以PEG和PVP为表面活性剂,在沉淀步骤制备出前驱体CaHPO₄粒子,然后在100℃、常压条件下水解获得高结晶度的HAP纳米棒。采用PEG制备的纳米棒形貌均匀、纵横比高;采用PVP制备的纳米棒尺寸范围较宽且尺寸较小。直接采用一步沉淀法也能够成功制备出HAP纳米粒子。采用PEG制备出麦穗状的纳米粒子;采用PVP制备出尺寸小的纳米棒和纳米粒子混合物。HAP纳米晶的结构和形貌因制备条件不同发生很大变化,故而控制其合成,有望用于生物医药领域。     

银纳米粒子与氧化物纳米异质结构制备及应用

总结了近期银纳米粒子与氧化物纳米异质结构制备及应用研究进展情况,特别是银纳米粒子修饰的氧化钼纳米纤维异质结构、银纳米粒子修饰的钛酸盐纳米纤维异质结构、银纳米粒子@二氧化硅@银纳米粒子三明治异质结构的制备方法与性能表征.介绍了以上三种异质纳米复合结构的催化性能和银纳米粒子修饰的二氧化物纳米纤维异质结构的气体传感性能.     

金核银壳纳米粒子薄膜的制备及SERS活性研究

采用柠檬酸化学还原法制备金溶胶, 通过自组装技术在石英片表面制备金纳米粒子薄膜, 在银增强剂混合溶液中反应获得金核银壳纳米粒子薄膜. 用紫外-可见吸收光谱仪和原子力显微镜(AFM)研究了不同条件下制备的金核银壳纳米粒子薄膜的光谱特性和表面形貌, 并以结晶紫为探针分子测量了金核银壳纳米粒子薄膜的表面增强拉曼光谱(SERS). 结果表明, 金纳米粒子薄膜的分布、银增强剂反应时间的长短对金核银壳纳米粒子薄膜的形成均有重要影响. 制备过程中, 可以通过控制反应条件获得一定粒径的、具有良好表面增强拉曼散射活性的金核银壳纳米粒子薄膜.     

无机纳米粒子表面引发接枝聚合

无机纳米粒子表面引发聚合反应是无机纳米粒子—有机聚合物杂化复合材料制备的一种重要途径。分子自组装技术的发展使得各种类型的聚合反应都有转移至无机纳米粒子表面进行的可能。本文综述了表面引发聚合反应用于制备高键合密度的聚合物接技无机纳米粒子的研究进展。     

喷墨打印图案化高分子薄膜及其在有机电子器件加工中的应用

喷墨打印技术由于在图案化加工方面的高效、低成本、非接触形式及柔性的加工过程等特点而被应用于有机电子器件的加工中.通过打印功能性高分子溶液,喷墨打印实现了功能高分子薄膜的沉积和图案化,并实现了有机发光二极管、有机薄膜晶体管及其集成器件的加工.对喷墨打印在有机电子器件加工中取得的成果进行了总结,同时综述了高分子溶液喷墨打印过程中存在的基本科学问题和研究现状.     

喷墨打印技术制备聚合物太阳能电池的研究进展

聚合物太阳能电池具有成本低、质量轻、容易制备大尺寸器件等优势,是太阳能电池研究中最为活跃的领域之一。喷墨打印技术作为新的成膜技术,具有材料利用率高、快速、可柔性加工等优点,已被用于聚合物太阳能电池的制备,发展潜力巨大。综述了聚合物太阳能电池、喷墨打印技术和喷墨打印技术制备聚合物太阳能电池的研究进展,同时对聚合物太阳能电...     

Paper‐Based Inkjet‐Printed Microfluidic Analytical Devices

Rapid, precise, and reproducible deposition of a broad variety of functional materials, including analytical assay reagents and biomolecules, has made inkjet printing an effective tool for the fabrication of microanalytical devices. A ubiquitous office device as simple as a standard desktop printer with its multiple ink cartridges can be used for this purpose. This Review discusses the combination of inkjet printing technology with paper as a printing substrate for the fabrication of microfluidic paper‐based analytical devices (μPADs), which have developed into a fast‐growing new field in analytical chemistry. After introducing the fundamentals of μPADs and inkjet printing, it touches on topics such as the microfluidic patterning of paper, tailored arrangement of materials, and functionalities achievable exclusively by the inkjet deposition of analytical assay components, before concluding with an outlook on future perspectives.     

Fabrication of polymer microsphere particle standards containing trace explosives using an oil/water emulsion solvent extraction piezoelectric printing process

We present a methodology for fabricating polymer microspheres using inkjet printing of a biodegradable polymer containing either high explosives or high explosive simulant. Poly(dl-lactide/glycolide) 85:15 (PLGA) microsphere production is based on an oil/water emulsion solvent extraction process. The inkjet printing process allows for precise control of the microsphere diameter and the chemical composition. The microspheres can be used as calibrants or verification standards for explosives trace detection instruments. Gas chromatography/mass spectrometry analysis demonstrated that the composition of the microspheres was consistent with predicted concentrations based on the amount of analyte incorporated into the polymer solution and the inkjet operating parameters. We have demonstrated that the microspheres can be fabricated with a mass fraction of 70% of an analyte compound.     

喷墨打印聚合物薄膜均匀性调控研究进展

聚合物发光显示材料具有发光颜色在全可见光区可调、可溶液简单加工及适用于柔性大面积基底的特点,成为目前研究的热点。 在聚合物发光薄膜图案化技术中,喷墨打印因为具有加工过程简单高效、适用于溶液方式加工、柔性的加工过程等特点而被认为是最具有应用潜力的技术。 高质量聚合物薄膜的制备是高精度发光显示器件制作的关键,但喷墨打印液滴在干燥过程中通常伴随着“咖啡环”现象,造成薄膜不均匀沉积。 因此,消除“咖啡环”现象,实现聚合物薄膜的均匀沉积,是喷墨打印高性能器件的重要研究方向。 本文主要论述了“咖啡环”效应的产生机理,如何抑制喷墨打印聚合物薄膜加工过程中的“咖啡环”效应,最终实现聚合物薄膜均匀性调控。     

An attempt of improving polyester inkjet printing performance by surface modification using β‐cyclodextrin

To improve the sharpness and the color yield of polyester fabrics with water‐based pigment inkjet printing, surface modification was proceeded using β‐cyclodextrin and citric acid. Fabrics were modified in the solution of β‐cyclodextrin with the concentration 100g/L and citric acid 100g/L. The line width and image area of printed patterns, which could evaluate the printing performances, on the modified polyester fabric were decreased by 77% and 62% in comparison with that of the control, respectively. The color yield characterized by the K/S value was enhanced by 47%. Scanning electron microscope and atomic force microscope images confirmed that the capillary effect was decreased and the surface roughness was increased after the surface modification. The microscope images of the printed patterns clearly showed that the sharpness and the color yield were improved. Thereby, β‐cyclodextrin modification offered a potential way to polyester pretreatment for pigment inkjet printing. Copyright © 2012 John Wiley & Sons, Ltd.     

Green approach to prepare silver nanoink with potentially high conductivity for printed electronics

A new strategy was described for green preparation of silver nanoink with potentially high conductivity for printed electronics. Silver nanoparticles in the ink were characterized by visible ultraviolet spectrophotometer (UV‐vis), Transmission Electron Microscope (TEM), size distribution analysis (SDA), X‐Ray Diffractomer (XRD) and differential scanning calorimetry (DSC). Silver thin film was investigated by SEM and 4‐point probe. It can be found that silver nanoparticles are of small sizes about 2.1 ± 0.5 nm in diameter, with a low melting point of about 105°. It also can be concluded that continuous silver thin film has formed, and an integrated conductive track has been fabricated. Especially, when the solid content is up to 9 wt.% and the sintering condition is 200° for 30 minutes in air, the resistivity can decrease to 8.1 µΩ·cm, 4.9 times the bulk silver resistivity. In addition, the application of silver nanoink in conductive patterns on polyimide (PI) substrate was also studied by inkjet printing. Copyright © 2011 John Wiley & Sons, Ltd.     

印制电子用阻焊油墨及其发展趋势

本文介绍了PCB制造过程中所用阻焊油墨的研究现状及其发展趋势,重点介绍了可喷墨打印阻焊油墨、柔性电路板用阻焊油墨、水溶性碱显影感光阻焊油墨和LED封装用白色阻焊油墨的研究现状及趋势。     

Inkjet printed Prussian blue films for hydrogen peroxide detection

An inkjet printing method is described to fabricate hydrogen peroxide (H(2)O(2)) sensors. Insoluble Prussian blue (PB) nanoparticles were dispersed in aqueous solvent, and were printed on screen printed carbon electrodes with a piezoelectric inkjet printer for H(2)O(2) detection. The electrochemical behavior of the printed sensors was studied by using cyclic voltammetry and chronoamperometry. The printed sensors showed great electrocatalytic activity toward H(2)O(2) and can be used for amperometric detection of H(2)O(2). The calibration curves for H(2)O(2) determination showed a linear range from 0.02 to 0.7 mM with a sensitivity of 164.82 μA M(-1) cm(-2) for the printed PB film. The results showed the feasibility of applying inkjet printing technology on surface modification; the results also provide an alternative way for manufacturing electrochemical sensors.     

Numerical characterization of ultraviolet ink fluid agglomeration and the surfactant effect in nanoinkjet printing

Ultraviolet (UV) ink is a major ink type used in additive manufacturing via 3D inkjet printing. A major challenge in nanoinkjet printing is ink agglomeration. Among the UV ink components, oligomers have the highest tendency to agglomerate which can agitate the stability and quality of the printing fluid and possibly lead to nanoscale nozzle clogging. In this work, the first numerical study on the UV ink fluid, UV ink is modeled by using dissipative particle dynamics to study mesoscale agglomeration. The constituents of the ink model are composed of polystyrene and polyethylene glycol as photopolymers, BZP as a photoinitiator, and SDS as a surfactant. Styrene is a prevalent and established commercial photopolymer in present 3D inkjet applications, while ethylene glycol is a photopolymer known to improve ink viscosity. The morphological characteristics of the UV ink are studied here, where the results for different models from four cases considered here show how the kind of photopolymers and their constituent ratios affect the agglomeration morphology of the fluidic system. The existence of both oligomers and monomers results in mutual morphological benefits against agglomeration, while the photoinitiator occurs between photopolymers. In addition, we find that the surfactant can reduce the average size of agglomeration and improve the dispersion uniformity by increasing the number of agglomerates. These results highlight the important role additives can play to prevent, reduce, and control various forms of agglomeration to achieve enhanced nanoinkjet printing quality. Copyright © 2017 John Wiley & Sons, Ltd.