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1.
用聚乙二醇—硫酸铵—铝试剂体系萃取分离铁(Ⅲ)铝(Ⅲ),铜(Ⅱ)钴(Ⅱ)… 总被引:9,自引:1,他引:9
研究了在聚乙二醇-硫酸铵-铝试剂体系中Fe(Ⅲ),Al(Ⅲ)、Cu(Ⅱ)、CoⅡ)Cd(Ⅱ)Mn(Ⅱ)、Ni(Ⅱ)的萃取分离行为。结果表明,在PH5.0-6.5HAc-NaAc缓冲溶液中,Fe(Ⅲ)、Al(Ⅲ)可被PEG相几乎完全萃取,而Cu(Ⅱ)、Co(Ⅱ)Cd(Ⅱ)Mn(Ⅱ)基本上不被萃取,从而实现了Fe(Ⅱ)与Cu(Ⅱ)Co(Ⅱ)Cd(Ⅱ)Mn(Ⅱ)及Al(Ⅲ)与Fe(Ⅲ)Co(Ⅱ)、Cu( 相似文献
2.
用聚乙二醇—硫酸铵—铬黑T体系从铁(Ⅲ),钴(Ⅱ),镍(Ⅱ),铜(Ⅱ)中萃取… 总被引:8,自引:0,他引:8
本研究了聚乙二醇(PEG)-(NH4)2SO4-铬黑T(EBT)体系对Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Cd(Ⅱ)的非有机溶剂萃取行为。结果表明,在pH7 ̄11的NH3·HNHCl缓冲溶液中,Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)可被聚乙二醇(PEG)相萃取,而Cd(Ⅱ)基本上不被萃取,从而获得了Cd(Ⅱ)与Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)混合离子的定量分离。 相似文献
3.
聚乙二醇—硫酸铵—亚硝基R盐体系中钴(Ⅱ)的分离及其存在形态 总被引:2,自引:0,他引:2
在pH4.0~6.0的HAc-NaAc缓冲溶液中,Co(Ⅱ),Fe(Ⅲ),Ni(Ⅱ),Cu(Ⅱ)等金属离子与亚硝基R盐可形成稳定络合物,加入HCl适当提高溶液酸度(HCl浓度在0.3~0.6mol/L)用聚乙二醇2000(PEG)-硫酸铵-亚硝基R盐体系萃取,Co(Ⅱ)可被PEG相几乎完全萃取,而Fe(Ⅲ),Ni(Ⅱ),Cu(Ⅱ)基本上不被萃取,实现了Co(Ⅱ),Fe(Ⅲ),Ni(Ⅱ),Cu(Ⅱ) 相似文献
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聚乙二醇-硫酸铵-亚硝基R盐体系中钴(Ⅱ)的分离及其存在形态 总被引:2,自引:0,他引:2
在 pH 4.0~6.0的 HAc-NaAc缓冲溶液中,Co(Ⅱ)、Fe(Ⅲ)、Ni(Ⅱ)、Cu(Ⅱ)等金属离子与亚硝基R盐可形成稳定络合物。加入HCI适当提高溶液酸度(HCI浓度在0.3~0.6mol/L),用聚乙二醇2000(PEG)-硫酸铵-亚硝基R盐体系萃取,Co(Ⅱ)可被PEG相几乎完全萃取,而Fe(Ⅲ)、Ni(Ⅱ)、Cu(Ⅱ)基本上不被萃取。实现了Co(Ⅱ)、Fe(Ⅲ)、Ni(Ⅱ)、Cu(Ⅱ)混合离子合成样品和硅酸盐岩矿实际样品中Co(Ⅱ)的分离与测定。同时吸收光谱、摩尔比、连续浓度变换、加入表面活性剂等实验表明,在萃取相Co(Ⅱ)与亚硝基R盐是1:3络阴离子形式存在的。 相似文献
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中位—四(4—N—氰甲基吡啶)卟啉—铜(Ⅱ)络合物及其与脱氧核糖核酸… 总被引:4,自引:1,他引:4
本文在银胶活性基质上获得了Cu(Ⅱ)的中位-四(4-N-氰甲基吡啶)卟啉络合物Cu(Ⅱ)NACN的表面增强喇曼光谱光谱,并与其RRS光谱作了比较,讨论了PH值和Cu(Ⅱ)NACN的复合物的SERS光谱的影响,研究了小牛胸腺双链DNA及其变性DNA与Cu(Ⅱ)NACN的复合物的SERS光谱,指出Cu(Ⅱ)NACN是通过吡啶氮和卟啉核共同与银胶作用的,Cu(Ⅱ)NACN是斜向吸附在银表面上的,最佳PH 相似文献
7.
氧化铈在非贵金属氧化物催化剂中的作用:Ⅵ.Cu—Fe—Ce—O催化剂的结 … 总被引:3,自引:1,他引:2
采用XRD,顺磁共振(ESR),Mossbauer和或温还原(TPR)技术对负截型Cu-Fe-O(Ⅰ),Cu-Fe-Co-O(Ⅱ)催化剂的固相结构及热稳定性进行了研究。结果发现,(Ⅰ)中主要存在Fe2CuO4,CuO和颗粒度小于13nm的Fe2O3相。随着焙烧温度的升高,CuO晶相逐渐消失,Fe2CuO4的晶相长大。(Ⅱ)中Ce的存在,能提高Cu^2+的浓度,抑制CuO和Fe2CuO4晶相的生成, 相似文献
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研究了N2H4在间-四(邻-硝基苯基)四苯并卟啉铁(Ⅲ)、钴(Ⅱ)、锌(Ⅱ)和镍(Ⅱ)配合物[MTP(о-NO2)TBP,简称MTBP]修饰石墨电极上的催化电氧化反应,测得该系列金属四苯并卟啉的催化活性的顺序为Co(Ⅱ)TBP>ClFe(Ⅲ)TBP>Ni(Ⅱ)TBP>Zn(Ⅱ)TBP≈石墨,考察了Co(Ⅱ)TBP和ClFe(Ⅲ)TBP催化联氨电氧化反应的动力学过程。结果表明,OH^-和N2H4在C 相似文献
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V. A. Shlyapochnikov G. I. Oleneva N. O. Cherskaya O. A. Luk'yanov V. P. Gorelik O. V. Anikin V. A. Tartakovsky 《Russian Chemical Bulletin》1995,44(8):1449-1453
The vibrational and electronic spectra of dinitramide salts MN(NO2)2 (M=K, Na, Li, NH4, Fe, Ag, Mn, Mg, Rb, C(NH2)3) have been studied. The IR and Raman spectra of solutions and melts of the salts have been satisfactorily interpreted on the basis of the anion model withC
2v
symmetry. The complication of the spectra in the crystalline phase has been explained by restructurization of the anion that reduces its symmetry and makes the nitro groups nonequivalent.For part 6, seeIzv. Akad. Nauk, Ser. Khim., 1995, 113 [Russ. Chem. Bull.,44, 108 (Engl. Transl.)].Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1508–1512, August, 1995. 相似文献
13.
Syntheses, absorption and fluorescence properties for a series of new enzyme substrates are described, which are derived from 7-hydroxycoumarins possessing electron-withdrawing substituents in position 3. The new substrates are advantageous over existing ones in that they exhibit longwave absorption and fluorescence maxima as well as largeStokes' shifts. In addition, theirpK
a
values, which are usually between 6.0 and 7.0, allow the direct and continuous kinetic assay of hydrolases such as esterases, phosphatases, and sulfatases.
Synthesen und spektrale Eigenschaften langwellig absorbierender und fluoreszierender Substrate für die direkte und kontinuierliche kinetische Bestimmung von Carboxylesterasen, Phosphatasen und Sulfatasen
Zusammenfassung Die Synthesen und Absorptions- sowie Fluoreszenzspektren einer Reihe neuer Enzymsubstrate werden beschrieben, welche von 7-Hydroxycumarinen mit elektronenziehenden Substituenten in 3-Stellung abgeleitet sind. Die neuen Substrate bieten gegenüber bisherigen den Vorteil langwelliger Absorptions- und Fluoreszenzmaxima sowie großerStokes-Verschiebungen. Die niedrigenpK s -Werte, welche zwischen 6 und 7 liegen, erlauben weiters eine direkte und kontinuierliche kinetische Bestimmung von Hydrolasen vom Typ der Esterasen, Phosphatasen und Sulfatasen.相似文献
14.
Diffuse reflection FTIR spectral database of dyes and pigments 总被引:1,自引:0,他引:1
Silva CE Silva LP Edwards HG de Oliveira LF 《Analytical and bioanalytical chemistry》2006,386(7-8):2183-2191
24 pigments commonly used in art have been characterized by diffuse reflection infrared spectroscopy (DR). All of the compounds
have also been characterized by means of infrared absorption spectroscopy to demonstrate the reliability of the DR technique.
This is the first record of the use of this technique as an analytical tool in conservation science, and the results appear
to be promising for the identification of unknown pigments used on historical and artwork artifacts. Although the DR technique
used here is not nondestructive, it can still be usefully applied to the analysis of artwork since it requires only a very
small quantity of sample for analysis. 相似文献
15.
Complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 3-(2-pyridyl)-1-(2-hydroxy phenyl)-2-propen-1-one (PHPO), 3-(1-naphthyl)-1-(2-hydroxy
phenyl)-2-propen-1-one (NHPO) and 3-(3,4-dimethoxy phenyl)-1-(2-hydroxy phenyl)-2-propen-1-one (DMPHPO) have been synthesized
and characterized by analytical, conductivity, thermal, magnetic, infrared, electronic and electron spin resonance data. Based
on analytical data the stoichiometry of the complexes has been found to be 1 : 2. The conductivity data show that all these
complexes are non-electrolytes. The infrared spectral data indicate that the ligand PHPO acts as uninegative tridentately
towards Co(II) and Ni(II) and bidentately with Cu(II), Zn(II) and Cd(II). Ligands like NHPO and DMPHPO act as uninegative
bidentately with all the metal ions. The electronic spectral data suggest that all the Co(II) complexes and Ni(II) of PHPO
complex are octahedral and all the Cu(II) and Ni(II) of NHPO and DMPHPO complex are square-planar. The complex of Zn(II) and
Cd(II) are tetrahedral. ESR parameters of Cu(II) complexes have been calculated and relevant conclusions have been drawn with
respect to the nature of bonds present in them. 相似文献
16.
Norbornene reacts with trichlorosilane to generate norbornyltrichlorosilane in high yield. The slow hydrolysis of norbornyltrichlorosilane in acetone yields incompletely condensed norbornyl-silasesquioxanes. The compound C42H70O11Si6 can be isolated from this reaction. On the basis of elemental analyses, 1H, 13C and 29Si NMR, mass spectroscopy, infrared spectroscopy, and crystallographic analysis, C42H70O11Si6 is formulated as [(C7H11)6Si6O7(OH)4], with the Si6O7 framework being composed of two perpendicular Si4O4 planes sharing an edge. [(C7H11)6Si6O7(OH)4] is a putative model of vicinal [Si(OH)]2 sites on the surface of partially dehydroxylated silica. 相似文献
17.
四(对-硝基苯基)卟啉配合物的红外和拉曼光谱 总被引:3,自引:0,他引:3
本文研究了四(对-硝基苯基)卟啉及其Cr(Ⅲ)、Mn(Ⅲ)、Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)配合物的3500~220cm~(-1)的红外光谱和1700~100cm~(-1)的拉曼光谱.谱带归属表明,~250cm~(-1)谱带是M—N伸缩振动和卟啉环变形振动的复合振动.金属敏感带出现在~1600、~1582、~1547、~1284、~1190、~355和~245cm~(-1)处,其中二价金属配合物金属敏感带频率按Ni>Co>Cu>Zn顺序递减.用金属半径和d_x~2 y~2电子排斥作用解释了金属敏感带变化规律. 相似文献
18.
A. B. A. El-Gazzar H. A. R. Hussein A. S. Aly 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2771-2784
We prepared a thieno[2,3-d]pyrimidine compound fused with a thiazolo ring to produce biologicaly active compounds. In a one-step reaction, 2-arylmethylene derivative (3) was prepared via the reaction of a ternary mixture of 2-thioxo-1,2,3,4-tetrahydrocyclohepteno[4,5]thieno[2,3-d]pyrimi-dine-4-one (2), cloroacetic acid, and a proper aldehyde. The reaction of 2 with 3-chloropent-2,4-dione in ethanolic potassium hydroxide yielded the S-acetylacetone derivative 4e. The latter compound reacted with hydrazine hydrate and phenyl hydrazine to give 2-pyrazolthio derivatives 8a,b, respectively. Compound 4e also underwent cyclization on boiling with acetic anhydride/pyridine solution to form 2-acetyl-3-methyl thiazolo[3,2-a]cyclohepteno[4,5]thieno[2,3-d] pyrimidine-5-one (9). To support the structure 9, it gave a characteristic reaction for the 2-acetyl group. The 2-methylthio derivatives 4a underwent further alkylation at N3 to give 6a,b. The purpose of the synthesis of thienopyrimidine derivatives is due to high biological activities. The 4-oxo-thienopyrimidine derivatives acted as inhibitors of adenosine kinase, platelet aggregation, antilukemia, and anticancer activities. 相似文献
19.
合成了未见报道的L-谷氨酸桥连的卟啉二联体配体及其铜的金属配合物, 并用红外光谱, 电子吸收光谱, 核磁氢谱, 元素分析和质谱等对化合物的结构加以确认, 研究了配体和金属配合物的CD, 拉曼光谱和荧光光谱的变化. 结果显示在配体中没有出现劈裂的Cotton效应, 而铜配合物中出现了劈裂的正负Cotton效应, 配体的荧光强度强于铜配合物的荧光强度, 在拉曼光谱中, 由于卟啉分子平面的对称性由D2h变为D4h群及其铜离子d轨道的电子效应, 在卟啉配体和铜配合物之间的拉曼光谱有很大差别. 相似文献
20.
The absorption and fluorescence properties of the plant phenol ellagic acid have been studied in alcohol and aqueous solutions. Fluorescence is weak in all kinds of solvents, but is greatly enhanced by addition of borax. The resulting complex emits much more intensely in methanol than in water solution. UV and fluorescence data reveal that the complex formed in methanol is different from the complex formed in aqueous solution. The enormous fluorescence enhancement of ellagic acid by borax offers a simple method for the visualization and quantification of the potent anti-mutagen ellagic acid as well as a fluorimetric method for the determination of boron.The IUPAC name for ellagic acid is 2,3,7,8-tetra-hydroxy[1]benzopyrano[5,4,3—c,d,e][1]-benzopyran-5,10-dione. 相似文献