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Aqueous solutions of seven cationic triarylmethane dyestuffs can be titrated with sodium tetraphenylborate using as indicator electrode an aluminium wire coated with a PVC membrane plasticized with 2-nitrophenyl 2-ethylhexyl ether or tricresylphosphate. Titrations are possible in unbuffered and buffered media within the pH range 4–10. Characteristic titration data are given for determinations of malachite green B, seto- glaucin 0, brilliant green, fuchsine, methyl violet, crystal violet, and Victoria blue B. 相似文献
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The electrochemical properties of two basic violets(methyl violet and ethyl violet) at the MWNTs/Nafion modified glassy carbon electrode were investigated.The redox of the basic violets is two-electron and two-proton process,and methyl violet presents stronger electron transfer capacity than ethyl violet.Meanwhile,the inclusion constants of the two basic violets with five CDs were determined by differential pulse voltammetry(DPV).The two basic violets and CDs can form 1:1 complexes. The inclusion capacit... 相似文献
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Pier Luigi Buldini 《Analytica chimica acta》1976,82(1):187-201
An extensive bibliography on the determination of boron by means of tetrafluoroborate-dye complexes is given. The stability constants of the fluoroborate—dye complexes are calculated from potentiometric measurements with an Orion fluoroborate ion-selective electrode, for the following nineteen dyes: methylene blue, methylene green, new methylene blue N, thionine, toluidine blue O, malachite green, brilliant green, crystal violet, fuchsine, methyl green, methyl violet, Victoria blue B, brilliant cresyl blue, Nile blue A, rhodamine B, rhodamine 6G, pyronine Y, safranine T and Janus green B. The solubilities of these dyes have been determined by spectrophotometry. 相似文献
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A new enzyme coated electrode for the determination of urea in blood samples has been developed. It is based on the encapsulation of urease enzyme in the porous silicate matrix by the sol-gel technique on a glass electrode for the purpose of sensing urea in blood samples. Various parameters like the effect of pH, selection of a suitable buffer of appropriate concentration and interference of common substances in blood samples have been evaluated to optimize the conditions for the determination of urea. The electrode can be used for the determination of urea in the concentration range 0.03-30.0 mM in a solution. The detection limit of the present enzyme-coated electrode is found to be 52 μg/ml of urea. The relative standard deviation for the electrode-to-electrode reproducibility is found to be 2.4% for the determination of 0.1 mM of urea (six replicate electrodes). Sol-gel matrix containing immobilized enzyme was stable for about 25 days at ∼4 °C with 80% urease activity. Urea content in various clinical blood samples has been estimated using this electrode and the results are found to be in good agreement with the standard clinical methods as reported in the literature. 相似文献
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碳纳米管/高分子复合材料已经被广泛研究, 但长期以来存在一个共同而关键的挑战, 即碳纳米管无规聚集, 结构难以调控, 性能无法满足应用需要. 本工作提出了制备取向碳纳米管/高分子复合材料的一种新方法, 获得块状、膜状、纤维状复合材料, 制备的关键步骤是通过化学气相沉积法合成可纺的高质量碳纳米管阵列. 该方法简单易行, 具有较好的普适性. 由于碳纳米管取向排列, 复合材料具有优异的物理性能, 如碳纳米管取向后复合材料的机械强度和导电率可分别提高一个和三个数量级. 在此基础上, 进一步探讨取向碳纳米管/高分子复合材料作为新型电极在有机太阳能电池中的应用. 相似文献
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Removal of methyl violet from aqueous solution by perlite 总被引:2,自引:0,他引:2
The use of perlite for the removal of methyl violet from aqueous solutions at different concentration, pH, and temperature has been investigated. Adsorption equilibrium is reached within 1 h. The capacity of perlite samples for the adsorption of methyl violet was found to increase with increasing pH and temperature and decrease with expansion and increasing acid-activation. The adsorption isotherms are described by means of the Langmuir and Freundlich isotherms. The adsorption isotherm was measured experimentally at different conditions and the experimental data were correlated reasonably well by the adsorption isotherm of Langmuir. The order of heat of adsorption corresponds to a physical reaction. It is concluded that the methyl violet is physically adsorbed onto the perlite. The removal efficiency (P) and dimensionless separation factor (R) have shown that perlite can be used for removal of methyl violet from aqueous solutions, but unexpanded perlite is more effective. 相似文献
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