Quantitative temperature imaging in gas-phase turbulent thermal convection by laser-induced fluorescence of acetone

In this paper, an acetone planar laser-induced fluorescence (PLIF) technique for nonintrusive temperature imaging is demonstrated in gas-phase (Pr = 0.72) turbulent Rayleigh-Bénard convection at Rayleigh number Ra = 1.3᎒⁵. The PLIF technique provides quantitative spatially correlated temperature data without the flow intrusion or time lag associated with physical probes, and without the significant path averaging that plagues most optical heat-transfer diagnostic tools, such as the Mach-Zehnder interferometer, thus making PLIF an attractive choice for quantitative thermal imaging in easily perturbed, complex three-dimensional flow fields. The "instantaneous" (20-ns integration time) thermal images presented have a spatial resolution of 176쐀아 µm and a single-pulse temperature measurement precision of - 2.5 K, or 2.5% of the total temperature difference. These images represent a two-dimensional slice through a complex three-dimensional flow, allowing for thermal structure of the turbulence to be quantified. Statistics such as the horizontally averaged temperature profile, root-mean square (rms) temperature fluctuation, two-point spatial correlations, and conditionally averaged plume structures are computed from an ensemble of 100 temperature images. The profiles of the mean temperature and rms temperature fluctuation are in good agreement with previously published data, and the results obtained from the two-point spatial correlations and conditionally averaged temperature fields show the importance of large-scale coherent structures in this turbulent flow.     

Comparison of drag reduction, rheology, microstructure and stress-induced precipitation of dilute cationic surfactant solutions with odd and even alkyl chains

Cationic surfactant systems of different alkyl chain lengths with counterion, C_nTAC(5 mmol/l)/3-Cl-Benzoate(12.5 mmol/l) (n=15, 16, 17, 18), were investigated for drag reduction, rheological behaviors, microstructure, and stress-induced precipitation. These are the first measurements of these characteristics for odd chain length (C₁₅ and C₁₇) quaternary ammonium surfactants. The lower and upper effective drag reduction temperature limits, viscoelasticity, and stress-induced precipitation temperature increased with alkyl chain length. Krafft temperature, critical turbidity temperature, and lower drag reduction effectiveness temperature limit showed a zigzag odd-even effect, while the stress-induced precipitation temperature did not. Light microscopy and cryo-TEM showed that cooling the C₁₅ solution below 20 °C produced crystals, while above that temperature threadlike micelles were present. The same was true for the solutions of C₁₈ that had threadlike micellar network microstructures when clear and crystals formed upon cooling. Micellar solutions can remain in a homogenous metastable state at a temperature below the Krafft temperature and above the critical turbidity temperature for days without external disturbance. Imposition of flow stress causes the systems to overcome the energy barrier and precipitate.     

Linear viscoelasticity of thermoassociative chitosan-g-poly(N-isopropylacrylamide) copolymer

Chitosan-g-poly(N-isopropylacrylamide) (chitosan-g-PNIPAM) was synthesized and characterized rheologically in aqueous solutions. The copolymer solution exhibits a thermoassociative behavior in which its elastic response dramatically increases when temperature is above the critical temperature or the association temperature, T _assoc. The copolymer at low concentration shows typical solution property. When the temperature is increased up to the critical temperature, the copolymer exhibits a gel-like characteristic due to the formation of physical cross-links between chitosan backbones through the self-aggregation of PNIPAM side chains. At high concentration, the system exhibits a weak elastic response due to the entanglement of the copolymer at 25°C. As temperature is raised above T _assoc, the system shows a strong elastic behavior due to the formation of additional physical cross-links via the aggregation of PNIPAM side chains. Chitosan-g-PNIPAM offers an attractive associating behavior in aqueous solution at temperature close to the body temperature, thus providing potential applications in pharmaceutical and medical industries.     

Visualization of the impact of water drops on a hot surface: effect of drop velocity and surface inclination

The behaviour of one drop impinging on a hot surface by varying the surface temperature, the drop velocity and the position of the surface (horizontal and a inclined 45°) both at a temperature below and above the Leidenfrost temperature has been experimentally evaluated, estimating the temperature at which the drop rebounds. A large influence on the drop velocity has been evidenced. The inclination of the surface decreases the critical value of the temperature above which the surface is not rewetted.     

Combined two-dimensional velocity and temperature measurements of natural convection using a high-speed camera and temperature-sensitive particles

This paper proposes a combined method for two-dimensional temperature and velocity measurements in liquid and gas flows using temperature-sensitive particles (TSPs), a pulsed ultraviolet laser, and a high-speed camera. TSPs respond to temperature changes in the flow and can also serve as tracers for the velocity field. The luminescence from the TSPs was recorded at 15,000 frames per second as sequential images for a lifetime-based temperature analysis. These images were also used for the particle image velocimetry calculations. The temperature field was estimated using several images, based on the lifetime method. The decay curves for various temperature conditions fit well to exponential functions, and from these the decay constants at each temperature were obtained. The proposed technique was applied to measure the temperature and velocity fields in natural convection driven by a Marangoni force and buoyancy in a rectangular tank. The accuracy of the temperature measurement of the proposed technique was ±0.35–0.40°C.     

退火温度对氧化铬薄膜结构和高温摩擦学性能的影响

采用电弧离子镀技术在GH-4169高温合金基体上沉积氧化铬薄膜，并对薄膜进行了不同温度的退火处理，系统研究了不同退火温度(500、600、700和800 ℃)对薄膜形貌、薄膜结构、薄膜力学性能及薄膜摩擦学性能的影响. 结果表明:随退火温度升高，薄膜表面缺陷减少，氧化铬晶化趋于完善，薄膜硬度下降. 高温摩擦学性能方面薄膜经500和600 ℃退火后，在环境温度从室温到800 ℃宽温域范围内摩擦系数较退火前均有所增加；经800 ℃退火后的薄膜在环境温度为400~600 ℃时的摩擦系数均明显下降，但室温摩擦系数明显升高，宽温域内摩擦系数波动较大；700 ℃退火后薄膜宽温域内摩擦系数在0.21~0.33之间，波动较小.      

Thermomechanics of shape memory polymers: Uniaxial experiments and constitutive modeling

Shape memory polymers (SMPs) can retain a temporary shape after pre-deformation at an elevated temperature and subsequent cooling to a lower temperature. When reheated, the original shape can be recovered. Relatively little work in the literature has addressed the constitutive modeling of the unique thermomechanical coupling in SMPs. Constitutive models are critical for predicting the deformation and recovery of SMPs under a range of different constraints. In this study, the thermomechanics of shape storage and recovery of an epoxy resin is systematically investigated for small strains (within ±10%) in uniaxial tension and uniaxial compression. After initial pre-deformation at a high temperature, the strain is held constant for shape storage while the stress evolution is monitored. Three cases of heated recovery are selected: unconstrained free strain recovery, stress recovery under full constraint at the pre-deformation strain level (no low temperature unloading), and stress recovery under full constraint at a strain level fixed at a low temperature (low temperature unloading). The free strain recovery results indicate that the polymer can fully recover the original shape when reheated above its glass transition temperature (T_g). Due to the high stiffness in the glassy state (T < T_g), the evolution of the stress under strain constraint is strongly influenced by thermal expansion of the polymer. The relationship between the final recoverable stress and strain is governed by the stress–strain response of the polymer above T_g. Based on the experimental results and the molecular mechanism of shape memory, a three-dimensional small-strain internal state variable constitutive model is developed. The model quantifies the storage and release of the entropic deformation during thermomechanical processes. The fraction of the material freezing a temporary entropy state is a function of temperature, which can be determined by fitting the free strain recovery response. A free energy function for the model is formulated and thermodynamic consistency is ensured. The model can predict the stress evolution of the uniaxial experimental results. The model captures differences in the tensile and compressive recovery responses caused by thermal expansion. The model is used to explore strain and stress recovery responses under various flexible external constraints that would be encountered in applications of SMPs.     

Experimental and numerical analysis of spray-atomization characteristics of biodiesel fuel in various fuel and ambient temperatures conditions

The purpose of this work is to reveal the effects of fuel temperatures and ambient gas conditions on the spray-atomization behavior of soybean oil methyl ester (SME) fuel. The spray-atomization behavior was analyzed through spray parameters such as the axial distance from the nozzle tip, local and overall Sauter mean diameter (SMD). These parameters were obtained from a spray visualization system and a droplet measuring system. In addition, the experimental results were compared with the numerical results calculated by the KIVA-3V code. It was revealed that the increase of the fuel temperature (from 300 K to 360 K) little affects the spray liquid tip penetration. The increase of the ambient gas temperature (from 300 K to 450 K) caused a increase in the spray liquid tip penetration. Also, biodiesel fuel evaporation actively occurred due to the increase in the fuel temperature and the ambient gas temperature. Of special significance was that the highest vapor fuel mass concentration was observed at the center region of the spray axis. In the results of the microscopic characteristics, the detected local droplet size at the axial direction and overall droplet size at the axial and radial direction in a control volume increased when the fuel temperature increased. This is believed to be due to an increase in the number of small droplets that quickly evaporated. In addition, the increased fuel temperature caused the decrease of the number of droplets and the increase of the vapor fuel mass. The mean axial velocity of droplets decreased with increasing fuel temperature.     

The effective thermal conductivity of insulation materials reinforced with aluminium foil at low temperatures

The effective thermal conductivity (ETC) of multilayer thermal insulation materials was experimentally investigated as a function of temperature (0–25?°C). The materials consisted of binary/ternary glass wools or ternary expanded polystyrene foams reinforced with aluminium foil. The experimental measurements were performed using a guarded hot plate with temperature differences of 5, 10 and 15?°C. The results indicated that significant correlations exist between ETC and the characteristics of the materials with decreasing temperature. The ETC decreases with reinforcement with aluminium foil at the same temperature or with temperature differences of 5 and 15?°C. In addition, it was clearly observed that the ETC decreases sharply with decreased temperature. Consequently, reflective materials may reduce the ETC at low temperatures.     

Modeling of Turbulent Natural Gas and Biogas Flames of the Delft Jet-in-Hot-Coflow Burner: Effects of Coflow Temperature,Fuel Temperature and Fuel Composition on the Flame Lift-Off Height

The structure of a turbulent non-premixed flame of a biogas fuel in a hot and diluted coflow mimicking moderate and intense low dilution (MILD) combustion is studied numerically. Biogas fuel is obtained by dilution of Dutch natural gas (DNG) with CO₂. The results of biogas combustion are compared with those of DNG combustion in the Delft Jet-in-Hot-Coflow (DJHC) burner. New experimental measurements of lift-off height and of velocity and temperature statistics have been made to provide a database for evaluating the capability of numerical methods in predicting the flame structure. Compared to the lift-off height of the DNG flame, addition of 30 % carbon dioxide to the fuel increases the lift-off height by less than 15 %. Numerical simulations are conducted by solving the RANS equations using Reynolds stress model (RSM) as turbulence model in combination with EDC (Eddy Dissipation Concept) and transported probability density function (PDF) as turbulence-chemistry interaction models. The DRM19 reduced mechanism is used as chemical kinetics with the EDC model. A tabulated chemistry model based on the Flamelet Generated Manifold (FGM) is adopted in the PDF method. The table describes a non-adiabatic three stream mixing problem between fuel, coflow and ambient air based on igniting counterflow diffusion flamelets. The results show that the EDC/DRM19 and PDF/FGM models predict the experimentally observed decreasing trend of lift-off height with increase of the coflow temperature. Although more detailed chemistry is used with EDC, the temperature fluctuations at the coflow inlet (approximately 100K) cannot be included resulting in a significant overprediction of the flame temperature. Only the PDF modeling results with temperature fluctuations predict the correct mean temperature profiles of the biogas case and compare well with the experimental temperature distributions.     

Non-invasive measurement of void fraction and liquid temperature in microchannel flow boiling

Past thermometry research for two-phase microfluidic systems made much progress regarding wall temperature distributions, yet the direct measurement of fluid temperature has received little attention. This paper uses a non-invasive two-dye/two-color fluorescent technique to capture fluid temperature along with local liquid fraction in a two-phase microflow generated by injecting air into a heated microchannel. The fluorescent emission of Rhodamine 110 and Rhodamine B, measured with photodiodes, is used to obtain local liquid temperature (±3°C) and void fraction (±2% full-scale) over a temperature range from 45 to 100°C. Arrays of these sensors can significantly expand the set of measurable flow parameters to include bubble/slug frequency, size, velocity, and growth rates in addition to mapping the local liquid temperature and void fraction.     

Influence of Thermally Induced Chemorheological Changes on the Inflation of Spherical Elastomeric Membranes

When an elastomeric material is deformed and subjected to temperatures above some chemorheological value T _cr (near 100°C for natural rubber), its macromolecular structure undergoes time and temperature dependent chemical changes. The process continues until the temperature decreases below T _cr. Compared to the virgin material, the new material system has modified properties (often a reduced stiffness) and permanent set on removal of the applied load. A recently proposed constitutive theory is used to study the influence of chemorheological changes on the inflation of an initially isotropic spherical rubber membrane. The membrane is inflated while at a temperature below T _cr. We then look at the pressure response assuming the sphere's radius is held fixed while the temperature is increased above T _cr for a period of time and then returned to its original value. The inflation pressure during this process is expressed in terms of the temperature, representing entropic stiffening of the elastomer, and a time dependent property that represents the kinetics of the chemorheological change in the elastomer. When the membrane has been returned to its original temperature, it is shown to have a permanent set and a modified pressure-inflated radius relation. Their dependence on the initial inflated radius, material properties and kinetics of chemorheological change is studied when the underlying elastomeric networks are neo-Hookean or Mooney–Rivlin.     

Influence de la température sur la courbe de rétention d'eau de milieux poreuxInfluence of temperature on the water retention curve of porous media

This paper concerns the influence of temperature on the water retention curve of porous media. We present a model based on the differential of suction as a function of temperature, water content and void ratio. When adjusted for a given temperature, this model is able to predict the curve for any temperature. The model was validated by several tests on a ceramic (terra cotta) and a clayey silty sand at 20 and 60?°C. The application of the model to data found in the literature confirms its predictive power for a wide range of porous materials. To cite this article: S. Salager et al., C. R. Mecanique 334 (2006).     

Investigation of thermal convection in water columns using particle image velocimetry

Particle image velocity measurements were applied on thermally driven convection at low Rayleigh numbers. In a model experiment using a water column heated from bottom and cooled from above, the velocity field was studied at different vertical temperature gradients. In the testing facility with high aspect ratio (about 19) representing a 1-m-long column with 5?cm diameter, occurrence of free convection was verified for destabilizing temperature gradients of 0.1–2?K/m. The PIV results revealed that significant flow exists already at low vertical temperature gradients. The velocity of the stable large-scale circulations increased linearly with temperature gradient (<1?K/m) from 8?×?10^?5 to 1?×?10^?3?m/s. At higher temperature gradients (1–2?K/m), a transition from quasi-stationary into time-dependent flow was observed, where convection cells changed position, number, and form temporarily. The motivation of this research was to gain more insight into density-driven convection in boreholes and groundwater monitoring wells.     

On axisymmetrical problem of layer with temperature dependent properties

The paper deals with the axisymmetrical problem of thermoelastic layer with mechanical properties dependent on temperature. The boundary planes of the body are kept at constant but different temperatures. Moreover, the layer is assumed to be ideal fixed to a rigid foundation. The upper boundary plane is loaded by normal forces dependent on the radius. The considered stationary problem is solved according with the following scheme: (1⁰) firstly the distribution of temperature is found, (2⁰) secondly, assuming that the Young modulus is a power function of temperature and Poisson ratio is constant, the displacements and stress are calculated from adequate boundary value problem. The obtained results in the form of Hankel integrals are analysed numerically for the case of linear dependence of Young modulus on the temperature.     

Experimental and numerical study of the ignition of hydrogen-air mixtures by a localized stationary hot surface

The ignition of hydrogen-air mixtures by a stationary hot glow plug has been experimentally investigated using two-color pyrometry and interferometry. The ignition process was characterized by the surface temperature at ignition, as well as by the location where the initial flame kernel was formed. The experimental results indicate that: (i) the ignition temperature threshold is a function of equivalence ratio; (ii) the ignition location is a function of the rate at which the glow plug is heated because high heating rates favor non-uniform heating. As a result, ignition occurs on the side rather than near the top face of the glow plug. Comparison with two-dimensional numerical simulations exhibits discrepancies in terms of the temperature threshold value and dependence on equivalence ratio. Simulations performed imposing a non-uniform surface temperature show that a temperature difference between the side and the top of the glow plug as low as 12.5 to 25 K resulted in side ignition for hydrogen-air mixtures. The effect of surface chemistry was estimated numerically by imposing a boundary condition of zero species concentration for intermediate species, H and HO₂, at the hot surface, which increased the ignition threshold by up to 50 K for an initial H₂ concentration of 70%. The present study shows that surface temperature non-uniformity, heterogeneous chemistry and reaction model used, could influence the experimentally reported and numerically predicted ignition threshold as well as the location of ignition.     

Viscous dissipation of a power law fluid in axial flow between isothermal eccentric cylinders

We study the temperature distribution of a power law fluid in a pressure-driven axial flow between isothermal eccentric cylinders in bipolar cylindrical coordinates. We begin our analysis by writing the equation of energy in bipolar cylindrical coordinates. We then obtain a dimensionless algebraic analytic solution for temperature profiles under a steady, laminar, incompressible and fully developed flow [Eq. (64)]. We find that the dimensionless temperature profile depends upon the radius ratio of the inner to outer cylinders, the eccentricity, the angular position, and the power law exponent n. The temperature is a strong function of the gap between the cylinders. The temperature profiles are flat in the middle of the gap and then, near the wall, suddenly drop to the wall temperature.     

Gas temperature in the trace of water droplets streamlined by hot air flow

In order to obtain the knowledge necessary for developing new effective fire extinguishing technologies, we determined experimentally the gas temperature in the trace of water droplets streamlined by hot air flow. It was important to establish how much the temperature in the droplet trace decreases and how fast it recovery to the initial temperature field after the droplet evaporation. The following parameters were varied: droplet size from 1.3 mm to 1.7 mm, velocity from 1 m/s to 5 m/s, initial airflow temperature from 473 K to 773 K, number of droplets (one or two), and the arrangement of droplets relative to the hot inflow (serial or parallel). The study proves the theoretical hypothesis about a significant influence of evaporation on the temperature in the water droplet trace. When a temperature trace of water droplets is formed, irrespective of their arrangement, the role of the evaporation process strengthens with the gas flow temperature rising. Furthermore, the study specifies typical longitudinal dimensions of the aerodynamic and temperature traces of water droplets. It has been established that when droplets are located in series and in parallel, their combined impact on the temperature and velocity of the gas flow in the medium differs rather considerably.     

Combined phosphor and CARS thermometry at the wall–gas interface of impinging flame and jet systems

For the determination of surface normal temperature gradients, a generic system was built up consisting of two opposed, vertical nozzles impinging onto a flat, horizontal copper plate. From below, the plate was heated by non-reacting, turbulent air jets (Re = 5,000) and by a laminar flame (λ = 0.7, Re = 350), respectively. For well-defined boundary conditions, the plate was cooled by a turbulent cold jet from above in both cases. Wall temperature as well as gas temperature distributions within and outside of the thermal boundary layer of the hot side of the system were determined. The radial surface temperature profile of the plate was measured by coating it with thermographic phosphors (TP), materials whose phosphorescence decay time is dependent on their temperature. The TP was excited electronically by a frequency-tripled Nd:YAG laser (355 nm). The temporal decay of the phosphorescence intensity was measured pointwise by a photomultiplier tube. In this case, the 659 nm emission line of Mg₄FGeO₆:Mn was monitored. Non-intrusive point measurements of the gas temperature close to the surface were performed by rovibrational coherent anti-Stokes Raman spectroscopy (CARS) of diatomic nitrogen. Beams from a seeded, frequency-doubled Nd:YAG laser (532 nm) and from a modeless broadband dye laser (607 nm) were phase-matched into a surface-parallel, planar-boxcars configuration. The temperature data could be collected as close as 300 μm to the surface. Thermographic phosphors as well as CARS proved to be consistent for wall temperature and boundary layer measurements in all test cases. The results and challenges of this approach are discussed.     

PP/PA共混高聚物在高应变率下的热粘弹性本构关系和时温等效性

采用Instron1342电液伺服试验机和改进的SHPB技术对以113材料为例的PP/PA共混高聚物进行了应变率在10-4~103 s-1宽广范围,温度为25、40、60、80 ℃下的一维应力力学性能试验。结果表明,这类共混高聚物的力学响应对温度和应变率都是敏感的。以朱-王-唐非线性粘弹性本构方程来描述这类PP/PA共混高聚物的力学响应,并拟合得到了其热粘弹性本构参数,理论预言与试验结果在应变小于7%时吻合良好。对113材料20~80 ℃温度范围内不同应变率下的试验结果进行分析,证明PP/PA共混高聚物存在率温等效关系,提高温度和增加作用时间（减小应变率）的效果相当,反之,降低温度与减少作用时间（提高应变率）的效果相当。通过引入量纲一参量Z,使应变率d/dt、温度T这2个参量归结为统一的Z参量,从而得到了体现时温等效性的统一曲线。