The Gibbs-Thompson relation within the gradient theory of phase transitions

This paper discusses the asymptotic behavior as 0+ of the chemical potentials associated with solutions of variational problems within the Van der Waals-Cahn-Hilliard theory of phase transitions in a fluid with free energy, per unit volume, given by ²¦¦²+ W(), where is the density. The main result is that is asymptotically equal to E/d+o(), with E the interfacial energy, per unit surface area, of the interface between phases, the (constant) sum of principal curvatures of the interface, and d the density jump across the interface. This result is in agreement with a formula conjectured by M. Gurtin and corresponds to the Gibbs-Thompson relation for surface tension, proved by G. Caginalp within the context of the phase field model of free boundaries arising from phase transitions.     

Interpolation formulas for maxwell viscosity of certain metals as a function of shear-strain intensity and temperature

The purpose of this study is the construction of interpolation formulas for the dependence of Maxwell viscosity, a quantity which is the reciprocal of shear-strain relaxation time , on shear-strain intensity and temperature for several metals: iron, aluminum, copper, and lead. This function was interpolated in various temperature and deformation velocity ranges in accordance with available experimental data for iron (0 10⁷ sec^–1, 200 ° T 1500 °); aluminum (0 10⁷ sec^–1, 300 ° T 900 °); copper (0 10⁵ sec^–1, 300 ° T 1300 °); lead (0 10⁶ sec^–1, 90 ° T 400 °); temperatures in °K.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 4, pp. 114–118, July–August, 1974.     

Positively invariant regions for a problem in phase transitions

Positively invariant regions for the system v _t + p(W) _x = V _xx , W _t –V _x = W _xx are constructed where p < 0, w < , w > , p(w) = 0, w , > 0. Such a choice of p is motivated by the Maxwell construction for a van der Waals fluid. The method of an analysis is a modification of earlier ideas of Chueh, Conley, & Smoller [1]. The results given here provide independent L bounds on the solution (w, v).Dedicated to Professor James Serrin on the occasion of his sixtieth birthday     

Emergence of taylor vortices between rotating eccentric cylinders

In a linear setting we examine the stability of the flow of a viscous incompressible liquid between eccentric cylinders, the inner cylinder rotating and the outer cylinder fixed. We consider the case of a narrow gap between the cylinders, which is characteristic for problems in lubrication theory. The main flow, perturbations, and the critical Reynolds number are found in the form of expansions in powers of the eccentricity to within O (³). The results obtained agree with the known experimental data for 0 0.5 and confirm the stabilizing influence of the eccentricity.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 3, pp. 101–106, May–June, 1973.The author wish to thank N. P. Artemenko, A. D. Myshkis, and R. Di Prima for a useful discussion of the problem.     

Generation of vortices in a partially filled,rapidly rotating cylinder

We describe a system in which vortices are shed from a cylindrical free surface approximately centered in a rotating flow. Shedding is controlled by the parameter =2 g/ ² d, where g, , d denote gravity, rotation rate and the diameter of the free surface. We find vortex shedding for >0.162 and no vortex shedding for < 0.0847. The range depends on the aspect ratio L/d, where L is the column length, in a nonmonotonic fashion. These results are independent of viscosity and surface tension for small values of these parameters.Now at Martin Marietta, Orlando Aerospace, PO Box 5837, Mail Point 150, Orlando, FL 32855, USA     

Combined effect of external turbulence and strong acceleration on boundary layer transition in a nozzle

The effect of external turbulence on the boundary layer flow in a convergent-divergent nozzle with a high expansion ratio has been studied numerically. The external turbulence was simulated by the turbulent viscosity _e, for which we used the partial differential equation that serves to close the system of boundary layer equations [1–4]. It was found that there exists a critical value _cr such that for all _e< _cr the flow regime in the nozzle remains perfectly laminar, whereas for _ecr a laminar-turbulent transition takes place and the boundary layer in the supersonic part of the nozzle becomes turbulent. For postcritical values of _e the heat fluxes and friction losses are approximately an order greater than for precritical values. With increase in the Reynolds number, determined from the parameters in the nozzle throat, the value of _cr decreases; as the coordinate of the onset of boundary layer formation is displaced in the direction of flow the value of _cr increases.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 34–37, January–February, 1906.The authors are grateful to L. V. Gogish for participating in the discussion of the results.     

Solution of regular beam equations in arbitrary emission conditions on a curvilinear surface

The regular beam equations are solved analytically for the case of emission from an arbitrary surface in conditions of total space charge (-mode) and in a given external magnetic field H (§2) for temperature-limited emission (T-mode), in an external magnetic field H (§3); and for emission with nonzero initial velocity (§4). The emitter is taken as the coordinate surface x¹=0 in an orthogonal system x¹ (i = =1,2,3), while the current density J and field on it are given functions j(x², x³), (x², x³. The solution is written as series in (x¹) with coefficients dependent on x², x³, determined from recurrence relations. For emission in the -mode and H 0, =1/3; for temperature-limited emission, =1/2; with nonzero initial velocity, =1. The results are extended to the case of a beam in the presence of a moving background of uniform density (5).     

Investigation of the flow past wings of infinite span with a blunt leading edge in the vorticity interaction regime

An asymptotic analysis of the Navier-Stokes equations is carried out for the case of hypersonic flow past wings of infinite span with a blunt leading edge when 0, Re , and M . Analytic solutions are obtained for an inviscid shock layer and inviscid boundary layer. The results of a numerical solution of the problems of vorticity interaction at the blunt edge and on the lateral surface of the wing are presented. These solutions are compared with the solution of the equations of a thin viscous shock layer and on the basis of this comparison the boundaries of the asymptotic regions are estimated.deceasedTranslated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 120–127, November–December, 1987.     

Viscoelastic swirling flow with free surface in cylindrical chambers

The flow of a viscoelastic liquid driven by the steadily rotating bottom cover of a cylindrical cup is investigated. The flow field and the shape of the free surface are determined at the lowest significant orders of the regular domain perturbation in terms of the angular velocity of the bottom cap. The meridional field superposed on a primary azimuthal field shows a structure of multiple cells. The velocity field and the shape of the free surface are strongly effected by the cylinder aspect ratio and the elasticity of the liquid. The use of this flow configuration as a free surface rheometer to determine the first two Rivlin-Ericksen constants is shown to be promising.Nomenclature R, ,Z Coordinates in the physical domain D - , , Coordinates in the rest stateD ₀ - r, ,z Dimensionless coordinates in the rest stateD ₀ - Angular velocity - Zero shear viscosity - Surface tension coefficient - Density - Dimensionless surface tension parameter - ₁, ₂ The first two Rivlin-Ericksen constants - Stream function - Dimensionless second order meridional stream function - ^* Dimensionless second normal stress function - 2 Dimensionless sum of the first and second normal stress functions - N ₁,N ₂ The first and second normal stress functions - n Unit normal vector - D Stretching tensor - A _n nth order Rivlin-Ericksen tensor - S Extra-stress - u Velocity field - U Dimensionless second order meridional velocity field - V Dimensionless first order azimuthal velocity field - p Pressure - Modified pressure field - P Dimensionless second order pressure field - J Mean curvature - a Cylinder radius - d Liquid depth at rest - D Dimensionless liquid depth at rest - h Free surface height - H Dimensionless free surface height at the second order     

Invariant Manifolds for Nonautonomous Systems with Application to One-Step Methods

In this paper we study the existence of invariant manifolds for a special type of nonautonomous systems which arise in the study of discretization methods. According to [10], a one-step scheme of step-size for an autonomous system can be interpreted as the -flow of a perturbed nonautonomous system. The perturbation is rapidly forced in the sense that it is periodic with respect to time with period . Assuming a saddle node for the autonomous system, we prove that these rapidly forced perturbations have center manifolds which exist in a uniform neighborhood and which converge to a center manifold of the autonomous system as tends to zero. Our results are applied to obtain a smooth continuation as well as estimates of the well known center manifolds for one-step schemes. They also form the basis for studying saddle-node homoclinic orbits under discretization.     

Transport in ordered and disordered porous media III: Closure and comparison between theory and experiment

In this paper we examine the closure problem associated with the volume averaged form of the Stokes equations presented in Part II. For both ordered and disordered porous media, we make use of a spatially periodic model of a porous medium. Under these circumstances the closure problem, in terms of theclosure variables, is independent of the weighting functions used in the spatial smoothing process. Comparison between theory and experiment suggests that the geometrical characteristics of the unit cell dominate the calculated value of the Darcy's law permeability tensor, whereas the periodic conditions required for thelocal form of the closure problem play only a minor role.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface associated with the local closure problem, m² - A _p surface area of a particle, m² - b vector used to represent the pressure deviation, m^–1 - B ⁰ B+I, a second order tensor that maps v _m ontov - B second-order tensor used to represent the velocity deviation - d _p 6V _p/A_p, effective particle diameter, m - d a vector related to the pressure, m - D a second-order tensor related to the velocity, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor calculated on the basis of a spatially periodic model, m² - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p characteristic length for the volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - characteristic length (pore scale) for the-phase - _i i=1, 2, 3 lattice vectors, m - weighting function - m(-y) , convolution product weighting function - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - n unit normal vector pointing from the-phase toward the -phase - p pressure in the-phase, N/m² - p _m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p – p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function - r position vector, m - r position vector locating points in the-phase, m. - V averaging volume, m³ - B volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v _m superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - v traditional superficial volume averaged velocity, m/s - v – v _m , spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the -phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * , weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

Asymptotic Nusselt numbers for Newtonian flow through a parallel-plate channel with recycle

General expressions for evaluating the asymptotic Nusselt number for a Newtonian flow through a parallel-plate channel with recycle at the ends have been derived. Numerical results with the ratio of thicknesses as a parameter for various recycle ratios are obtained. A regression analysis shows that the results can be expressed by log Nur^0.83=0.3589 (log)² -0.2925 (log) + 0.3348 forR 3, 0.1 0.9; logNu=0.5982(log)² +0.3755 × 10^–2 (log) +0.8342 forR 10^–2, 0.1 0.9.

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Asymptotische Nusselt-Zahlen für die Newtonsche Strömung durch einen Kanal aus parallelen Platten mit Rückführung

Zusammenfassung In dieser Untersuchung wurden allgemeine Ausdrücke hergeleitet um die asymptotische Nusselt-Zahl für eine Newtonsche Strömung durch einen Kanal aus parallelen Platten mit Rückführung an den Enden berechnen zu können. Es wurden numerische Ergebnisse mit den Dicken-Verhältnissen, als Parameter für verschiedene Rückführungs-verhältnisse, erhalten. Eine Regressionsanalyse zeigt, daß die Ergebnisse wie folgt ausgedrückt werden können: log Nur^0,83=0,3589 (log)² -0,2925 (log) + 0,3348 fürR 3, 0,1 0,9; logNu=0,5982(log)² +0,3755 × 10^–2 (log) + 0,8342 fürR 10^–2, 0,1 0,9.

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Nomenclature A₁ shooting value,d(0)/d - A₂ shooting value,d(1)/d - B channel width - Gz Graetz number, U_bW²/L - h _m logarithmic average convective heat transfer coefficient - h _x average local convective heat transfer coefficient - k thermal conductivity - L channel length - Nu average local Nusselt number, 2 h_xW/k - Nu _m logarithmic average Nusselt number, 2h_mW/k - R recycle ratio, reverse volume flow rate divided by input volume flow rate - T temperature of fluid - T _m bulk temperature, Eq. (8) - T ₀ temperature of feed stream - T _s wall temperature - U velocity distribution - U _b reference velocity,V/BW - V input volume flow rate - v dimensionless velocity distribution, U/U_b - W channel thickness - x longitudinal coordinate - y transversal coordinate - Z₁-z₆ functions defined in Eq. (A1) - thermal diffusivity - least squares error, Eq. (A7) - weight, Eqs. (A8), (A9) - dimensionless coordinate,y/W - dimensionless coordinate,x/GzL - function, Eq. (7)     

Über den Einfluß von Querkrümmung und Dichte bei inhomogenen turbulenten Freistrahlen

Zusammenfassung Zur Berechnung turbulenter Strömungen wird das k--Modell im Ansatz für die turbulente Scheinzähigkeit erweitert, so daß es den Querkrümmungs- und Dichteeinfluß auf den turbulenten Transportaustausch erfaßt. Die dabei zu bestimmenden Konstanten werden derart festgelegt, daß die bestmögliche Übereinstimmung zwischen Berechnung und Messung erzielt wird. Die numerische Integration der Grenzschichtgleichungen erfolgt unter Verwendung einer Transformation mit dem Differenzenverfahren vom Hermiteschen Typ. Das erweiterte Modell wird auf rotationssymmetrische Freistrahlen veränderlicher Dichte angewendet und zeigt Übereinstimmung zwischen Rechnung und Experiment.

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On the influence of transvers-curvature and density in inhomogeneous turbulent free jets

The prediction of turbulent flows based on the k- model is extended to include the influence of transverse-curvature and density on the turbulent transport mechanisms. The empirical constants involved are adjusted such that the best agreement between predictions and experimental results is obtained. Using a transformation the boundary layer equations are solved numerically by means of a finite difference method of Hermitian type. The extended model is applied to predict the axisymmetric jet with variable density. The results of the calculations are in agreement with measurements.

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Bezeichnungen Wirbelabsorptionskoeffizient - c_i Massenkonzentration der Komponente i - c_D, c_L, c, c₁, c₂ Konstanten des Turbulenzmodells - d Düsendurchmesser - E bezogene Dissipationsrate - f bezogene Stromfunktion - f Korrekturfunktion für die turbulente Scheinzähigkeit - j turbulenter Diffusionsstrom - k Turbulenzenergie - k_i Schrittweite in -Richtung - K dimensionslose Turbulenzenergie - L turbulentes Längenmaß - M_i Molmasse der Komponente i - p Druck - allgemeine Gaskonstante - r Querkoordinate - r_0,5 Halbwertsbreite der Geschwindigkeit - r_0,5c Halbwertsbreite der Konzentration - T Temperatur - u Geschwindigkeitskomponente in x-Richtung - v Geschwindigkeitskomponente in r-Richtung - x Längskoordinate - y allgemeine Funktion - Y_i diskreter Wert der Funktion y - Relaxationsfaktor für Iteration - turbulente Dissipationsrate - transformierte r-Koordinate - kinematische Zähigkeit - Exponent - transformierte x-Koordinate - Dichte - _k, Konstanten des Turbulenzmodells - Schubspannung - allgemeine Variable - Stromfunktion - Turbulente Transportgröße Indizes 0 Strahlanfang - m auf der Achse - r mit Berücksichtigung der Krümmung - t turbulent - mit Berücksichtigung der Dichte - im Unendlichen - Schwankungswert oder Ableitung einer Funktion - – Mittelwert Herrn Professor Dr.-Ing. R. Günther zum 70. Geburtstag gewidmet     

Asymptotic analysis of equilibrium states for rotating turbulent flows

The equilibrium states of homogeneous turbulence simultaneously subjected to a mean velocity gradient and a rotation are examined by using asymptotic analysis. The present work is concerned with the asymptotic behavior of quantities such as the turbulent kinetic energy and its dissipation rate associated with the fixed point (/kS)=0, whereS is the shear rate. The classical form of the model transport equation for (Hanjalic and Launder, 1972) is used. The present analysis shows that, asymptotically, the turbulent kinetic energy (a) undergoes a power-law decay with time for (P/)<1, (b) is independent of time for (P/)=1, (c) undergoes a power-law growth with time for 1<(P/)<(C ₂–1), and (d) is represented by an exponential law versus time for (P/)=(C ₂–1)/(C ₁–1) and (/kS)>0 whereP is the production rate. For the commonly used second-order models the equilibrium solutions forP/,II, andIII (whereII andIII are respectively the second and third invariants of the anisotropy tensor) depend on the rotation number when (P/kS)=(/kS)=0. The variation of (P/kS) andII versusR given by the second-order model of Yakhot and Orzag are compared with results of Rapid Distortion Theory corrected for decay (Townsend, 1970).     

Der Spannungs- und Verschiebungszustand drehsymmetrischer Membrane mit beliebig gekrümmter Meridiankurve

Zusammenfassung Die Einführung von Zylinderkoordinaten (x, r, ) in die Gleichgewichtsbedingungen der Schnittkräfte bzw. in die Beziehungen zwischen Verzerrung und Verschiebungen am differentialen Schalenabschnitt ermöglicht die Berechnung des Spannungs- und Verschiebungszustandes von drehsymmetrischen Membranen mit beliebig gekrümmter Meridiankurve auf die Integration einer einfachen, linearen partiellen Differentialgleichung zweiter Ordnung für eine charakteristische FunktionF bzw. zurückzuführen. Eine geschlossene Lösung und damit eine Darstellung der Schnittkräfte und Verschiebungen durch explizite Formeln ist bei harmonischer Belastung cosn für zwei Funktionsgruppen=x ² und=x ^–3 möglich. Im Sonderfall der drehsymmetrischen und der antimetrischen Belastung mitn=0 undn=1 gelten die Gleichungen der Schnitt- und Verschiebungsgrößen für eine beliebige Meridianfunktion=(). Die Betrachtungen der Randbedingungen offener Schalen bei harmonischer Belastung geben über die infinitesimalen Deformationen einer drehsymmetrischen Membran mit überall negativer Krümmung Aufschluß.     

An example of a quasiconvex function that is not polyconvex in two dimensions

We study the different notions of convexity for the function f () = ||² (||² – 2 det ) where ^2×2, introduced by Dacorogna & Marcellini. We show that f is convex, polyconvex, quasiconvex, rank-one convex, if and only if ¦¦ 2/3 2, 1, 1+ (for some >0), 2/3, respectively.     

Die Temperaturabhängigkeit der Oberflächenspannung von reinen Kältemitteln vom Tripelpunkt bis zum kritischen Punkt

Zusammenfassung Die Oberflächenspannung von sechs reinen Substanzen — SF₆, CCl₃F, CCl₂F₂, CClF₃, CBrF₃ und CHClF₂ — wurde mit Hilfe einer modifizierten Kapillarmethode gemessen. Die zur Berechnung der Oberflächenspannung erforderlichen Sättigungsdichten und wurden teils aus vorhandenen Zustandsgleichungen, teils aus ebenfalls gemessenen Brechungsindizes bestimmt. Die Temperaturabhängigkeit der Oberflächenspannung läßt sich durch einen erweiterten Ansatz nach van der Waals =_O (T_c-T)(1+...) darstellen, wobei bei einfachen Stoffen ein eingliedriger, bei polaren und assoziierenden Stoffen ein zweigliedriger Ansatz notwendig und ausreichend ist. Für den kritischen Exponenten der Oberflächenspannung wurde ein von der molekularen Substanz weitgehend unabhängiger Wert von =1.284±0.005 gefunden.

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Temperature dependence of surface tension of pure refrigerants from triple point up to the critical point

The surface tension of six fluids (SF₆, CCl₃F, CCl₂F₂, CClF₃, CBrF₃, CHClF₂) have been measured by means of a modified capillary rise method. The liquid vapor densities, which are needed to calculate the surface tension, have partly been determined by means of refractive indices simultaneously measured in the same apparatus. The temperature dependence of the surface tension is described by an extended van der Waals power law =_O(T_c-T)(1+...). For simple fluids one term and for polar and associating fluids two terms are necessary and sufficient. The critical exponent is found to be 1.284 ± 0.005 and nearly independent of the molecular structure.

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Formelzeichen a² Laplace-Koeffizient - a Parameter - B_O, B_on Koeffizient der Koexistenzkurve - g Erdbeschleunigung - H Höhe, kapillare Steighöhe - LL Lorentz-Lorenz-Funktion oder Refraktionskonstante - M molare Masse - M Zahl der Meßwerte - N Zahl der unbekannten Parameter - n Brechungsindex - p Druck - R,r Radius - s Entropie - SD Standardabweichung - T, t Temperatur - u innere Energie Griechische Formelzeichen Exponent des Laplace-Koeffizienten - Exponent der Koexistenzkurve - 2. Exponent der Oberflächenspannung - Wellenlänge des Lichts - Exponent der Oberflächenspannung - _D Dipolmoment - , Dichte der Flüssigkeit bzw. des Dampfes - Oberflächenspannung - reduzierte Temperatur (1-T/T_c) - ² gewichtete Varianz Indizes c kritischer Zustand - D Differenz - m Mittelwert - T Isotherme - t Zustand am Tripelpunkt - S Zustand am Schmelzpunkt - bezogen auf Oberfläche     

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

Zum Impuls-, Wärme- und Stoffaustausch in turbulenten Strömungen reagierender Binärgemische

Zusammenfassung Die in Teil I vorgestellten Reynolds 'schen Gleichungen und Transportgleichungen werden für Strömungen mit Grenzschichtcharakter angegeben. Weiter werden Integralbedingungen mitgeteilt. Nach einer Diskussion über die Schließung des Gleichungssystems werden Lösungsverfahren besprochen. Dabei wird speziell auf Integralverfahren eingegangen.

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About the transfer of momentum, heat and mass in turbulent flows of binary mixturesPart II: Thin shear flow layers

The Reynolds equations and transport equations given in part I are presented for thin shear flow layers. Integral relations are given. After a discussion of the closure problem methods of solution are described. Specially integral methods are discussed.

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Formelzeichen c Massenkonzentration der Komponente - c_t charakteristische Konzentrationsschwankung - c_o Bezugskonzentration - c spezifische Wärme bei konstantem Druck - c_f Reibungsbeiwert - c_D Dissipationsintegral - c_E Entrainment-Funktion - c Schubspannungsintegral - D binsrer Diffusionskoeffizient - H Formparameter - H₁₂ Formparameter - H₃₂ Formparameter - j Kassendiffusionsstrom - L Bezugslänge - p Druck - p_t charakteristische Druckschwankung - p_o Bezugsdruck - Pr Prandtl-Zahl - q Wärmestrom - q²/2 kinetische Energie der Schwankungsbewegung - Re_L mit L gebildete Reynolds-Zahl - Re mit gebildete Reynolds-Zahl - Re₂ mit ₂ gebildete Reynolds-Zahl - Sc Schmidt-Zahl - T absolute Temperatur - T_t charakteristische TemperaturSchwankung - T_o Bezugstemperatur - u,v,w Geschwindigkeitskomponenten - u_t charakteristische Geschwindigkeitsschwankung - u_o Bezugsgeschwindigkeit - U=/ü dimensionslose. x-Komponente der Geschwindigkeit - x,y,z Komponenten des Ortsvektors Griechische Symbole Grenzschichtdicke - ₁ Verdrängungsdicke - ₂ Impulsverlustdicke - ₃ Energieverlustdicke - _T Enthalpieverlustdicke - _c Konzentrationsverlustdicke - =d/dx Parameter für die Grenzschichtabsch:atzung - turbulente Impulsaustauschgröße - _D turbulente Stoffaustauschgröße - _q turbulente Energieaustauschgröße - Dissipationsfunktion - Wärmeleitfähigkeit - dynamische Viskosität - v=/ kinematische Viskosität - Dichte - Produktionsdichte - Schubspannung Indizes mol molekularer Anteil - tur turbulenter Anteil - res resultierender Anteil - Außenrand der Grenzschicht - w Wand     

Radial diffusion in the poiseuille flow of a gas mixture

In a number of experiments (see [1], in which experimental papers are listed), diffusion has been observed in the radial direction in the process of flow of a mixture along tubes at low pressures. The heavier molecules accumulate near the tube axis. The attempt made in [1] to explain this phenomenon by the influence of the Burnett contribution to the diffusion did not lead to success, and the Burnett terms in the radial diffusion velocity indicate a motion of heavy molecules away from the tube axis. In the present paper, a complete analysis is given of this phenomenon. We consider the problem of the flow of a mixture along a cylindrical tube of finite length for given pressure difference p between its ends. On the basis of the hydrodynamic equations of the Burnett and super-Burnett approximations, a consistent asymptotic (with respect to the small parameter ) solution is given; = (p/p)R/L is the relative change in the pressure along the tube at a distance of order R (R and L are the radii and length of the tube). Radial diffusion occurs in the quadratic approximation in . It is shown that the radial diffusion velocity contains new terms not present in [1]; these are due to the inhomogeneity of the temperature and the pressure over the tube section, the expansion of the gas, and the super-Burnett correction to the diffusion velocity. The most important is the thermodiffusion term, which is determined by the hydrodynamic equations of the Navier-Stokes approximation. The remaining terms have order relative to it of Kn² (Kn = 1 /R is the Knudsen number, and 1 is the mean free path of the molecules). The expression obtained for the diffusion velocity agrees in sign with the experiment.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 91–96, September–October, 1979.I am grateful to G. E. Skvortsov, who drew my attention to this problem, and Yu. N. Grigor'ev for discussing the results.