共查询到19条相似文献,搜索用时 104 毫秒
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利用磷酸三丁酯形成的反胶束在常温常压下制备出一种超浓盐酸,其酸水摩尔比(nHCl/nH2O)在0.50~1.50之间,高于常温常压下饱和浓盐酸的酸水摩尔比(0.28)。红外光谱的研究结果表明超浓盐酸中部分氯化氢未发生电离,而是以分子形式存在。同时HCl参与了体系内氢键网络的形成。超浓盐酸体系提供了一个特殊的物理化学环境,使得溶于其中的铜离子呈红棕色。采用FTIR及UV-Vis对含铜离子的超浓酸体系进行了表征。结果表明,超浓酸中,铜离子的d—d跃迁和电荷迁移跃迁谱带都发生了明显的变化。铜离子的加入对超浓盐酸体系中未电离的HCl分子的氢键体系产生明显影响。 相似文献
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不少作者对常用工质绘制过(火用)焓图。本文利用Oguchi等人提出的状态方程,算出并绘制了R 22(火用)焓图(SI制),并给出两种不同环境温度时使用本图的(火用)修正曲线。 一、R22(火用)焓图的编制 R 22(火用)焓图以稳定流动系统工质比焓(火用)e为纵坐标,以比焓h为横坐标。焓(火用)e的定义式为 相似文献
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中心遮拦干涉图的处理 总被引:4,自引:1,他引:3
介绍了一种用于中心遮拦的大口径干涉仪的干水条纹处理软件,该软件通过对干涉数据进行采集,处理而得出被检波面的波差分布和像差,由于对干涉图数据拟合过程中所使用的泽尼特(Zernike)多项式进行了修正,因此得到的结果的准确度也有了较大的提高。 相似文献
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利用低相干光纤动态光散射法测量浓悬浮液中多分散颗粒粒径分布 总被引:1,自引:0,他引:1
本文针对高浓度散射介质,用低相干光纤动态光散射技术测量浓悬浮液中多分散颗粒系的粒径及其粒径分布。利用迭代CONTIN算法对实验数据进行反演运算,得到多分散颗粒系的粒径分布结果。结果表明,浓悬浮液中多分散颗粒系的峰值粒径测量值与给定的两种标准粒径值相吻合,其误差在4%之内,粒径分布曲线中各散射颗粒所反映的散射体光强分布与根据Mie散射计算得到的理论值相吻合。实验结果证明低相干光纤动态光散射实验系统能准确测量浓悬浮液中多分散颗粒粒径及粒径分布。 相似文献
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We calculate the ground state phase diagrams of a mixed Ising model on a square lattice where spins S (± 3/2, ± 1/2) in one sublattice are in alternating sites with spins Q (± 5/2, ± 3/2, ± 1/2), located on the other sublattice. The Hamiltonian of the model includes first neighbor interactions between the S and Q spins, next-nearest-neighbor interactions between the S spins, and between the Q spins, and crystal field. The topologies of the phase diagrams depend on the values of the parameters in the Hamiltonian. The diagrams show some key features: coexistence between regions, points where two, three, four, five and six states can coexist. Besides being very useful as a way to check the low temperature limit of the finite-temperature phase diagram, often obtained by mean-field theories, the richness of the ground state diagrams for certain combinations of parameters can be used as a guide to explore interesting regions of the finite-temperature phase diagram of the model. 相似文献
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应用卡诺循环的Bucher图形象地表示出三热源循环,并由图中的相似三角形直接导出三热源循环的能量守恒方程、熵守恒方程和性能系数. 相似文献
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The isotropic liquid (I) ⊥ nematic (N) ⊥ smectic A(A) phase diagrams of homologous series of liquid crystals obtained experimentally may be divided into at least 4 types (Fig. la-d) according to the characteristic behavior of TNI. 相似文献
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界面有序单分子层膜结构的红外和拉曼光谱表征 总被引:2,自引:0,他引:2
本文综述了近十几年来红外和拉曼光谱方法用于表征空气/水界面单分子层(Langmiur膜)、油/水界面和空气/固界面单分子层(LB膜)分子结构的最新进展。 相似文献
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We calculate the dynamic phase transition (DPT) temperatures and present the dynamic phase diagrams in the kinetic mixed spin-1/2 and spin-5/2 Ising model under the presence of a time-dependent oscillating external magnetic field. We employ the Glauber transition rates to construct the set of mean-field dynamic equations. The time variation of the average magnetizations and the thermal behavior of the dynamic magnetizations are investigated, extensively. The nature (continuous or discontinuous) of the transitions is characterized by studying the thermal behaviors of the dynamic magnetizations. The DPT points are obtained and the phase diagrams are presented in two different planes. Phase diagrams contain four fundamental phases and three coexistence or mixed phases, which strongly depend on interaction parameters. The phase diagrams are discussed and a comparison is made with the results of the other mixed spin Ising systems. 相似文献
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The critical behaviors of the trilayer Bethe lattice in the form of spin-(1/2,3/2,1/2) with the exterior two layers consisting of spin-1/2 and the interior one having only spin-3/2 Ising spins are studied in terms of the recursion relations with either ferromagnetic or antiferromagnetic bilinear exchange interactions between the nearest-neighbor spins. The ground-state phase diagrams are calculated and it is found that the model presents six different ground state phase configurations. The thermal variations of the order-parameter and free energy are investigated, therefore, topologically different phase diagrams of the model are obtained. It is found that the model exhibits second- and first-order phase transitions, tricritical and bicritical points for the values of the coordination numbers q=3, 4 and 6 and, the reentrant behavior for q=4 and 6, respectively. 相似文献
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J. Alejandre 《Molecular physics》2013,111(23-24):3029-3033
The surface properties and phase diagrams are examined for a number of modified water models. In the ‘bent’ family of models where the bond angle is decreased and the network structure is lost the surface tension is lower than in SPC/E water and the critical temperature is lower. In the ‘hybrid’ family of models which are hybrids between SPC/E water and a Lennard–Jones liquid the surface tension and the critical temperature are higher that in SPC/E water. These properties correlate well with the varying ability of the liquids to dissolve hard spheres. The surface potential, on the other hand, is slightly smaller in magnitude in the hybrid models than in SPC/E water because there is slightly less alignment of the dipoles in the surface layer. The degree of molecular alignment in the surface and the consequent surface potential drop is much lower in magnitude in the bent models than in SPC/E water. 相似文献
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J. Kplé S. Massou F. Hontinfinde E. Albayrak 《Chinese Journal of Physics (Taipei)》2018,56(3):1252-1261
A bilayer spin-1/2 Ising model consisting of two superposed Bethe lattices with antiferromagnetic/ferromagnetic interactions is studied by the use of exact recursion relations in a pairwise approach in the presence of an external staggered magnetic field. Besides the ground state phase diagrams calculated in different possible planes of the model parameters space, the thermal variations of the order-parameters and the free energy are investigated to obtain the temperature-dependent phase diagrams of the model for different values of the coordination numbers q. Our calculations reveal that depending on the strength of the model parameters, the model exhibits a variety of interesting phase transitions and therefore phase diagrams. 相似文献