新型含偶氮聚合物薄膜表面微结构的刻写研究

基于偶氮苯聚合物的光致异构和光致取向特性,开展了双偶氮苯功能化聚合物薄膜表面微结构的"刻写"研究.利用两束相干光照射,在样品表面"刻写"出了亚微米量级的光栅结构;利用分步法在样品表面制作出了清晰的"三角格子"等花样微结构,证明了双偶氮苯功能化聚合物对于表面微结构的制作有较强的可操作性.通过对比单偶氮和双偶氮材料的实验结果,证明了双偶氮聚合物具有响应时间快、衍射效率高等特点,并由此讨论了偶氮苯聚合物薄膜表面微结构的形成机理及其偏振选择性.     

在聚合物表面刻写方格子的新方法及理论研究

为了提高制作偶氮苯微结构的实验技术,在偶氮苯聚合物的光致异构和光致取向特性的基础上,利用两激光束的新实验方案,运用比较简便的分步制作的方法,成功的在偶氮苯功能化聚合物薄膜表面“刻写”出二维的正方格子结构。提出了一个新的光异构取向场理论：在两束偏振方向互相垂直的偏振光照射下,偶氮苯聚合物表面光栅的形成是光异构取向场的干涉的结果,并对实验现象进行了解释。用计算机对实验结果进行了模拟,将模拟结果与实验结果进行了比较,结果表明计算机模拟将会更加有利于偶氮苯聚合物微结构的设计和制作。     

偶氮苯聚合物薄膜光致六角对称微结构

利用前向箭并四波混频光路,在偶氮苯聚合物薄膜表面制作出六角对称的晶体微结构,观察到多个相位共轭波,当三束入射光都处在p偏振态时,在样品表面可得到一维光栅,当三束入射光中有一束在p偏振态,另两束在s偏振态时,在样品表面上得到的是六角对称微结构,这一结果表明,光场强度周期性变化及光场偏振态对晶格微结构的形成非常重要。     

利用偏振全息记录可重复擦写的偶氮相位光栅

利用偏振全息技术在偶氮苯侧链聚合物薄膜上进行了记录全息相位光栅的研究.从理论和实验两方面分析了不同的偏振全息模式、偶氮高分子聚合物材料和全息曝光时间对相位光栅生成的影响.通过实验比较,确定了最佳的实验条件,在形成折射率相位光栅的同时,最大限度的避免了由于大分子运动而导致的表面起伏对相位光栅的破坏,并在此基础上,记录了可重复擦写的全息相位光栅.这种全息光栅制作比较方便,光栅系数可以方便的调整,在室温下非常稳定并且能用圆偏振光完全擦除后重复写入.     

Photo-induced Alignment Behavior of Azobenzene-containing Polymer Films with Different Cross-linking Degree

合成了带有不同取代基的偶氮苯基团和可交联丙烯酸基团的共聚物,并通过控制热聚合的反应条件获得一系列不同交联密度的聚合物薄膜. 红外光谱表征样品交联度是从0到32%. 不同交联密度的偶氮聚合物薄膜的光致取向行为的研究结果表明交联能够降低光致取向速率以及薄膜的最大透过率. 进一步的重复擦写实验还表明交联薄膜能够有效抑制在线偏光擦写过程中偶氮苯分子的趋光性质量迁移.     

新型掺偶氮苯聚合物的取向增强及全息存储

研究一种新型的并列式的高密度存储材料ADPA-PVK-PBA-TNF聚合物薄膜.在非吸收区用光抽运测试法研究了薄膜光致双折射,获得光致双折射变化值Δn=1.3×10^-3,分析了该聚合物薄膜光致取向增强的物理和化学机理.探讨了抽运光对光致双折射的增强和抑制效应.在此基础上初步实现了多重角度复用信息存储、获得了较为清晰的全息存储图像.并讨论了图象存储的增强/抑制效应,利用这种效应可对存储图像处理或删除. 关键词： 掺杂偶氮苯聚合物薄膜 光致双折射 光全息存储 光致取向增强     

光栅制备工艺的新进展

从全息光栅法出发 ,详细阐述了应用偶氮苯聚合物光致表面调制效应制备光栅的新工艺 ,说明使用偶氮苯聚合物薄膜制备光栅方法的特点 ,介绍了采用新工艺制备的光栅的独特性质———光栅可热擦除或光学擦除 ,同时提出应用新材料光栅制造方法所面临的问题。采用新工艺实验制备了薄膜光栅     

偶氮液晶聚合物中的非线性光致双折射

介绍了在偶氮液晶聚合物薄膜P-CN中发现的非线性光致双折射现象,给出了非线性光致双折射实验的具体结果.采用Z扫描技术验证了光致双折射的非线性过程本质,测量了P-CN介质薄膜的非线性吸收系数.讨论了光致双折射涉及的异构化微观机理,并在此基础上提出了非线性光光异构化实现光致双折射的方法 关键词： 液晶聚合物 光致双折射 光致异构化     

掺杂偶氮苯聚合物光致异构Z扫描测量及其理论解释

用He_Ne激光对掺有偶氮苯聚合物DR 13的PMMA薄膜样品进行Z扫描研究 ,发现其折射率改变量与光强的关系存在着饱和效应 ,且线偏振光引起的折射率改变明显大于圆偏振光引起的折射率改变 .对于这些现象 ,用光致异构的角烧孔机理进行解释     

新型极化聚合物薄膜电光调制器研究

用对硝基偶氮苯类为侧链的键合型聚合物，采用高温电晕极化的方法制作电光薄膜，设计并构造极化聚合物薄膜电光调制器。当通光方向和极化方向平行并且垂直于极化聚合物薄膜的表面时，利用法布里-帕罗（F-P）腔中多光束干涉，可以把通过的光由位相调制转化为强度调制，有利于电光调制器的小型化和高速封装。用这种聚合物薄膜电光调制器测量了锢锡氧化物共面波导上的电信号，并对系统的工作原理进行了分析。实验结果表明，薄膜调制器具有线性电光效应；当F-P腔的精细因子为20（为1.3μm的光），调制电场为1V/μm时，研制的极化聚合物电光调制器的调制深度可达到0.01%。     

电子显微镜散斑照相技术

提出了一种新颖的人工亚微米/纳米散斑制作技术.采用超声波分散亚微米/纳米颗粒,然后利用范德华力、静电力和毛细力将其吸附在试件表面.在特定分辨率的扫描电镜下,物体表面的亚微米/纳米颗粒可以看作是亚微米/纳米散斑.此外,发展了一种测量面内亚微米/纳米级变形的电子显微镜散斑照相技术.详细介绍了人工制作亚微米/纳米散斑和电子显微镜散斑照相技术,实验验证了技术的可行性     

The Transplant of Technology of Capacitive Displacement Transducer to Phase Modulation Grating-the Research of the Grating with nm Measuring Resolution

The method rising measuring resolution through reducing pitch of the transducer has brought forward from the basic structure, principle and the corresponding relationship among pitches of capacitive electrodes, period T and phase shift of o. But if the traditional technique of PCB made of the transducer is still used, it will meet with difficulties in lead wire. And so the technology transplant from the transducer to grating is presented, the basic principle of the phase modulation grating similar to the transducer is described and the experiments setup of transmitted and reflective grating are put out. Some practical schemes f the new grating with resolution to sub-micron, even nm is given.     

Photofabrication of periodic microstructures in azodye-doped polymers by interference of laser beams

Volume holographic gratings and two-dimensional periodic microstructures in azodye-doped polymethylmethacrylate were fabricated, respectively, by interference of two coherent beams of a femtosecond laser and by interference of three coherent beams of a nanosecond laser. The dependence of the first-order Bragg diffraction efficiency and the photoinduced refractive-index modulation of the gratings on the intensity of the writing light was investigated. The measurements of the absorption spectra before and after irradiation with the writing light suggest that the photoinduced gratings were refractive-index-modulated gratings, which arose from a photoinduced decomposition reaction of the azodye molecules through multiphoton absorption. In the experiments involving the interference of three beams, the period of the two-dimensional periodic microstructures was changed by adjusting the angle between the three writing beams. Received: 10 July 2002 / Revised version: 5 September 2002 / Published online: 20 December 2002 RID="*" ID="*"Corresponding author. Fax: +81-774/955206, E-mail: jhsi@photon.jst.go.jp     

光控光子晶体偏光片

提出了一种新颖的调节液晶光子晶体光子带隙的方法.光子晶体波导通过往二维三角形光子晶体的介质柱之间填充液晶得到，光诱导液晶取向以改变液晶的折射指数从而改变光子晶体的光子带隙.数值模拟结果表明：通过外界光场控制所填充的向列相液晶的方向可以对这种二维三角形介质柱光子晶体的禁带结构进行调节.与电场调制方法相比，该光控液晶取向技术具有响应速度快、结构简单的优点.这种可调光子晶体可用于制作新颖的光敏偏光片.     

A novel solution-based self-assembly approach to preparing ultralong titanyl phthalocyanine sub-micron wires

Ultralong titanyl phthalocyanine （TiOPc） sub-micron wires have been synthesized by a novel solution-based self- assembly method. By using different solvents, changing the mass concentration and the solvent vapor pressure, the length and the shape of the wires can be adjusted. The mixed-phase properties of the TiOPc sub-micron wires were investigated by the ultraviolet-visible （UV-vis） absorption spectrum and X-ray diffraction. Organic transistors based on these wires were studied, which show the typical p-channel characteristics.     

Femtosecond mid-IR pump-probe spectroscopy of photoinduced insulator to metal transition in dimer Mott insulator κ-(BEDT-TTF)2X

Ultrafast dynamics of the photoinduced insulator (I) to metal (M) transition were investigated using femtosecond mid-infrared pump-probe spectroscopy in two-dimensional organic Mott insulators [bis (ethylenedithio)]-tetrathiafulvalene (BEDT-TTF) salts κ-(BEDT-TTF)₂X (κ-(ET)₂X, where X denotes anion). In κ-(d-ET)₂Cu[N(CN)₂]Br, a metallic state was photogenerated using a phonon-mediated mechanism: the effective bandwidth increases through the photoinduced molecular rearrangement. The mechanism differs fundamentally from the previously reported photoinduced filling control in one-dimensional Mott insulators.     

Microstructure based model for sound absorption predictions of perforated closed-cell metallic foams

Closed-cell metallic foams are known for their rigidity, lightness, thermal conductivity as well as their low production cost compared to open-cell metallic foams. However, they are also poor sound absorbers. Similarly to a rigid solid, a method to enhance their sound absorption is to perforate them. This method has shown good preliminary results but has not yet been analyzed from a microstructure point of view. The objective of this work is to better understand how perforations interact with closed-cell foam microstructure and how it modifies the sound absorption of the foam. A simple two-dimensional microstructural model of the perforated closed-cell metallic foam is presented and numerically solved. A rough three-dimensional conversion of the two-dimensional results is proposed. The results obtained with the calculation method show that the perforated closed-cell foam behaves similarly to a perforated solid; however, its sound absorption is modulated by the foam microstructure, and most particularly by the diameters of both perforation and pore. A comparison with measurements demonstrates that the proposed calculation method yields realistic trends. Some design guides are also proposed.